ºÝºÝߣshows by User: RobertTreharne / http://www.slideshare.net/images/logo.gif ºÝºÝߣshows by User: RobertTreharne / Wed, 27 Nov 2019 08:16:29 GMT ºÝºÝߣShare feed for ºÝºÝߣshows by User: RobertTreharne Getting Sh*t Done with MS Teams /slideshow/getting-sht-done-with-ms-teams/198309028 gettingsh-tdonewithmsteams-191127081629
A 2 hour fun and interactive workshop for students at the University of Liverpool that introduces the use of Microsoft Teams as a professional tool for collaborative working.]]>

A 2 hour fun and interactive workshop for students at the University of Liverpool that introduces the use of Microsoft Teams as a professional tool for collaborative working.]]>
Wed, 27 Nov 2019 08:16:29 GMT /slideshow/getting-sht-done-with-ms-teams/198309028 RobertTreharne@slideshare.net(RobertTreharne) Getting Sh*t Done with MS Teams RobertTreharne A 2 hour fun and interactive workshop for students at the University of Liverpool that introduces the use of Microsoft Teams as a professional tool for collaborative working. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/gettingsh-tdonewithmsteams-191127081629-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> A 2 hour fun and interactive workshop for students at the University of Liverpool that introduces the use of Microsoft Teams as a professional tool for collaborative working.
Getting Sh*t Done with MS Teams from University of Liverpool
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Science on the read/write web /slideshow/science-on-the-readwrite-web-132531547/132531547 scienceontheread2fwriteweb1-190220104728
A Fun, interactive session for LIFE710 students]]>

A Fun, interactive session for LIFE710 students]]>
Wed, 20 Feb 2019 10:47:28 GMT /slideshow/science-on-the-readwrite-web-132531547/132531547 RobertTreharne@slideshare.net(RobertTreharne) Science on the read/write web RobertTreharne A Fun, interactive session for LIFE710 students <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/scienceontheread2fwriteweb1-190220104728-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> A Fun, interactive session for LIFE710 students
Science on the read/write web from University of Liverpool
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Solar Challenge Briefing | University of Liverpool /slideshow/solar-challenge-briefing-university-of-liverpool/58684392 solarchallengebriefing1-160224225619
Briefing for the RSA International Solar Challenge. Delivered by Rob Treharne on Thurs 25 Feb 2016 @ 11am, Stephenson Institute for Renewable Energy, University of Liverpool]]>

Briefing for the RSA International Solar Challenge. Delivered by Rob Treharne on Thurs 25 Feb 2016 @ 11am, Stephenson Institute for Renewable Energy, University of Liverpool]]>
Wed, 24 Feb 2016 22:56:19 GMT /slideshow/solar-challenge-briefing-university-of-liverpool/58684392 RobertTreharne@slideshare.net(RobertTreharne) Solar Challenge Briefing | University of Liverpool RobertTreharne Briefing for the RSA International Solar Challenge. Delivered by Rob Treharne on Thurs 25 Feb 2016 @ 11am, Stephenson Institute for Renewable Energy, University of Liverpool <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/solarchallengebriefing1-160224225619-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Briefing for the RSA International Solar Challenge. Delivered by Rob Treharne on Thurs 25 Feb 2016 @ 11am, Stephenson Institute for Renewable Energy, University of Liverpool
Solar Challenge Briefing | University of Liverpool from University of Liverpool
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Optical Characterization of Inorganic Semiconductors /slideshow/optical-characterization-of-inorganic-semiconductors/54819291 opticalpropertiescdtlec72015-151106121922-lva1-app6891
Delivered by T. Veal for CDT-PV Liverpool training module, 5 Nov 2015]]>

Delivered by T. Veal for CDT-PV Liverpool training module, 5 Nov 2015]]>
Fri, 06 Nov 2015 12:19:22 GMT /slideshow/optical-characterization-of-inorganic-semiconductors/54819291 RobertTreharne@slideshare.net(RobertTreharne) Optical Characterization of Inorganic Semiconductors RobertTreharne Delivered by T. Veal for CDT-PV Liverpool training module, 5 Nov 2015 <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/opticalpropertiescdtlec72015-151106121922-lva1-app6891-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Delivered by T. Veal for CDT-PV Liverpool training module, 5 Nov 2015
Optical Characterization of Inorganic Semiconductors from University of Liverpool
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Solar cells /slideshow/solar-cells-50055747/50055747 solarcells-150701152405-lva1-app6891
5 min presentation by Nick, Tom and Thea]]>

5 min presentation by Nick, Tom and Thea]]>
Wed, 01 Jul 2015 15:24:05 GMT /slideshow/solar-cells-50055747/50055747 RobertTreharne@slideshare.net(RobertTreharne) Solar cells RobertTreharne 5 min presentation by Nick, Tom and Thea <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/solarcells-150701152405-lva1-app6891-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> 5 min presentation by Nick, Tom and Thea
Solar cells from University of Liverpool
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Solar Cells /slideshow/measuring-solar-cells/50055656 measuringsolarcells-150701152133-lva1-app6892
5 min presentation from and Jake and Kiran]]>

5 min presentation from and Jake and Kiran]]>
Wed, 01 Jul 2015 15:21:33 GMT /slideshow/measuring-solar-cells/50055656 RobertTreharne@slideshare.net(RobertTreharne) Solar Cells RobertTreharne 5 min presentation from and Jake and Kiran <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/measuringsolarcells-150701152133-lva1-app6892-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> 5 min presentation from and Jake and Kiran
Solar Cells from University of Liverpool
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Measuring the power output of a solar cell /RobertTreharne/measuring-the-power-output-of-a-solar-cell measuringthepoweroutputofasolarcell-150701152004-lva1-app6891
5 min presentation by Matthew and Aref]]>

5 min presentation by Matthew and Aref]]>
Wed, 01 Jul 2015 15:20:04 GMT /RobertTreharne/measuring-the-power-output-of-a-solar-cell RobertTreharne@slideshare.net(RobertTreharne) Measuring the power output of a solar cell RobertTreharne 5 min presentation by Matthew and Aref <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/measuringthepoweroutputofasolarcell-150701152004-lva1-app6891-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> 5 min presentation by Matthew and Aref
Measuring the power output of a solar cell from University of Liverpool
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Transparent conducting oxides for thin film PV /RobertTreharne/tco-workshop-fundamentals-of-tcos tcoscdt-141112022456-conversion-gate02
Talk delivered by Dr. T. Veal, University of Liverpool on Nov 12 2014 as part of the CDT-PV TCO Masterclass]]>

Talk delivered by Dr. T. Veal, University of Liverpool on Nov 12 2014 as part of the CDT-PV TCO Masterclass]]>
Wed, 12 Nov 2014 02:24:56 GMT /RobertTreharne/tco-workshop-fundamentals-of-tcos RobertTreharne@slideshare.net(RobertTreharne) Transparent conducting oxides for thin film PV RobertTreharne Talk delivered by Dr. T. Veal, University of Liverpool on Nov 12 2014 as part of the CDT-PV TCO Masterclass <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/tcoscdt-141112022456-conversion-gate02-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Talk delivered by Dr. T. Veal, University of Liverpool on Nov 12 2014 as part of the CDT-PV TCO Masterclass
Transparent conducting oxides for thin film PV from University of Liverpool
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Lecture 10: Solar Cell Technologies /slideshow/lecture-10-solar-cell-technologies/41257983 lecture-solarcelltechnologies-141107082037-conversion-gate01
Lecture 10 of "Fundamentals of Photovoltaics" course, delivered by Prof. Ken Durose, Nov 7 2014]]>

Lecture 10 of "Fundamentals of Photovoltaics" course, delivered by Prof. Ken Durose, Nov 7 2014]]>
Fri, 07 Nov 2014 08:20:37 GMT /slideshow/lecture-10-solar-cell-technologies/41257983 RobertTreharne@slideshare.net(RobertTreharne) Lecture 10: Solar Cell Technologies RobertTreharne Lecture 10 of "Fundamentals of Photovoltaics" course, delivered by Prof. Ken Durose, Nov 7 2014 <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/lecture-solarcelltechnologies-141107082037-conversion-gate01-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Lecture 10 of &quot;Fundamentals of Photovoltaics&quot; course, delivered by Prof. Ken Durose, Nov 7 2014
Lecture 10: Solar Cell Technologies from University of Liverpool
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Lecture 8: Phase Diagrams /slideshow/lecture-8-phase-diagrams/41249513 cdtlecture-phasediagrams-141107043936-conversion-gate02
Lecture 8 of "Fundamentals of Photovoltaics" course, delivered by Prof. Ken Durose, Nov 7 2014]]>

Lecture 8 of "Fundamentals of Photovoltaics" course, delivered by Prof. Ken Durose, Nov 7 2014]]>
Fri, 07 Nov 2014 04:39:35 GMT /slideshow/lecture-8-phase-diagrams/41249513 RobertTreharne@slideshare.net(RobertTreharne) Lecture 8: Phase Diagrams RobertTreharne Lecture 8 of "Fundamentals of Photovoltaics" course, delivered by Prof. Ken Durose, Nov 7 2014 <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/cdtlecture-phasediagrams-141107043936-conversion-gate02-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Lecture 8 of &quot;Fundamentals of Photovoltaics&quot; course, delivered by Prof. Ken Durose, Nov 7 2014
Lecture 8: Phase Diagrams from University of Liverpool
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Lecture 6: Junction Characterisation /slideshow/lecture-6-junction-characterisation/41210515 cdtlecture6-junctioncharacterisation-141106090329-conversion-gate01
Lecture 6 of "Fundamentals of Photovoltaics" course, delivered by Dr. Jon Major at University of Liverpool, Nov 6 2014]]>

Lecture 6 of "Fundamentals of Photovoltaics" course, delivered by Dr. Jon Major at University of Liverpool, Nov 6 2014]]>
Thu, 06 Nov 2014 09:03:29 GMT /slideshow/lecture-6-junction-characterisation/41210515 RobertTreharne@slideshare.net(RobertTreharne) Lecture 6: Junction Characterisation RobertTreharne Lecture 6 of "Fundamentals of Photovoltaics" course, delivered by Dr. Jon Major at University of Liverpool, Nov 6 2014 <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/cdtlecture6-junctioncharacterisation-141106090329-conversion-gate01-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Lecture 6 of &quot;Fundamentals of Photovoltaics&quot; course, delivered by Dr. Jon Major at University of Liverpool, Nov 6 2014
Lecture 6: Junction Characterisation from University of Liverpool
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Lecture 5: Junctions /slideshow/lecture-5-junctions/41197011 lecture52-141106033719-conversion-gate01
Lecture 5 of "Fundamentals of Photovoltaics" course delivered by Rob Treharne at University of Liverpool, Nov 6 2014]]>

Lecture 5 of "Fundamentals of Photovoltaics" course delivered by Rob Treharne at University of Liverpool, Nov 6 2014]]>
Thu, 06 Nov 2014 03:37:19 GMT /slideshow/lecture-5-junctions/41197011 RobertTreharne@slideshare.net(RobertTreharne) Lecture 5: Junctions RobertTreharne Lecture 5 of "Fundamentals of Photovoltaics" course delivered by Rob Treharne at University of Liverpool, Nov 6 2014 <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/lecture52-141106033719-conversion-gate01-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Lecture 5 of &quot;Fundamentals of Photovoltaics&quot; course delivered by Rob Treharne at University of Liverpool, Nov 6 2014
Lecture 5: Junctions from University of Liverpool
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Lecture 4: Semiconductors and Recombination /slideshow/lecture-4-semiconductors-and-recombination/41193993 lecture4-141106020241-conversion-gate01
Lecture 4 of "Fundamentals of Photovoltaic" lecture course. Delivered by Prof. Ken Durose at University of Liverpool, Nov 6 2014]]>

Lecture 4 of "Fundamentals of Photovoltaic" lecture course. Delivered by Prof. Ken Durose at University of Liverpool, Nov 6 2014]]>
Thu, 06 Nov 2014 02:02:41 GMT /slideshow/lecture-4-semiconductors-and-recombination/41193993 RobertTreharne@slideshare.net(RobertTreharne) Lecture 4: Semiconductors and Recombination RobertTreharne Lecture 4 of "Fundamentals of Photovoltaic" lecture course. Delivered by Prof. Ken Durose at University of Liverpool, Nov 6 2014 <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/lecture4-141106020241-conversion-gate01-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Lecture 4 of &quot;Fundamentals of Photovoltaic&quot; lecture course. Delivered by Prof. Ken Durose at University of Liverpool, Nov 6 2014
Lecture 4: Semiconductors and Recombination from University of Liverpool
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Lecture 4: Semiconductors and Reco /slideshow/lecture-4-41193847/41193847 lecture4-141106015653-conversion-gate02
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Thu, 06 Nov 2014 01:56:53 GMT /slideshow/lecture-4-41193847/41193847 RobertTreharne@slideshare.net(RobertTreharne) Lecture 4: Semiconductors and Reco RobertTreharne <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/lecture4-141106015653-conversion-gate02-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br>
Lecture 4: Semiconductors and Reco from University of Liverpool
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Lecture 3: Fundamental Limitations of Solar Cells /slideshow/lecture-3-fundamental-limitations-of-solar-cells/41022063 lecture31-141102125800-conversion-gate01
Key Question: Why can't a solar cell convert incident light into electrical power with 100% efficiency.]]>

Key Question: Why can't a solar cell convert incident light into electrical power with 100% efficiency.]]>
Sun, 02 Nov 2014 12:58:00 GMT /slideshow/lecture-3-fundamental-limitations-of-solar-cells/41022063 RobertTreharne@slideshare.net(RobertTreharne) Lecture 3: Fundamental Limitations of Solar Cells RobertTreharne Key Question: Why can't a solar cell convert incident light into electrical power with 100% efficiency. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/lecture31-141102125800-conversion-gate01-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Key Question: Why can&#39;t a solar cell convert incident light into electrical power with 100% efficiency.
Lecture 3: Fundamental Limitations of Solar Cells from University of Liverpool
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The Physics of Transparent Conducting Oxides /slideshow/the-physics-of-transparent-conducting-oxides/40694281 physicsoftcos1-141024142123-conversion-gate01
An introduction to the fundamental physics of transparent conducting oxides including a review of the electrical and optical properties of common materials.]]>

An introduction to the fundamental physics of transparent conducting oxides including a review of the electrical and optical properties of common materials.]]>
Fri, 24 Oct 2014 14:21:23 GMT /slideshow/the-physics-of-transparent-conducting-oxides/40694281 RobertTreharne@slideshare.net(RobertTreharne) The Physics of Transparent Conducting Oxides RobertTreharne An introduction to the fundamental physics of transparent conducting oxides including a review of the electrical and optical properties of common materials. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/physicsoftcos1-141024142123-conversion-gate01-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> An introduction to the fundamental physics of transparent conducting oxides including a review of the electrical and optical properties of common materials.
The Physics of Transparent Conducting Oxides from University of Liverpool
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Fundamentals of Photovoltaics: Lecture 1 /slideshow/fundamentals-of-photovoltaics-lecture-1/40452212 lecture22-141019075759-conversion-gate01
CDT-PV Fundamentals of Photovoltaics. University of Liverpool 5th Nov 2014]]>

CDT-PV Fundamentals of Photovoltaics. University of Liverpool 5th Nov 2014]]>
Sun, 19 Oct 2014 07:57:59 GMT /slideshow/fundamentals-of-photovoltaics-lecture-1/40452212 RobertTreharne@slideshare.net(RobertTreharne) Fundamentals of Photovoltaics: Lecture 1 RobertTreharne CDT-PV Fundamentals of Photovoltaics. University of Liverpool 5th Nov 2014 <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/lecture22-141019075759-conversion-gate01-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> CDT-PV Fundamentals of Photovoltaics. University of Liverpool 5th Nov 2014
Fundamentals of Photovoltaics: Lecture 1 from University of Liverpool
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A Combinatorial Approach to the Optimisation of Cd (1−x) Zn x S Layers for CdTe Solar Cells /slideshow/a-combinatorial-approach-to-the-optimisation-of-cd-1x-zn-x-s-layers-for-cdte-solar-cells/40334047 treharnerevision1-141016004714-conversion-gate01
A combinatorial methodology has been adopted to determine the optimum composition of a Cd ( 1 − x)Zn x S window layer for CdTe solar cells. The methodology generated a large, self consistent dataset which permitted an unambiguous relationship between x, conversion efficiency and related cell parameters to be determined. An optimum composition of x = 0.57 was shown to maximise cell efficiency. Analysis of J − V curves, measured over 72 separate cells show that both short circuit current, J SC , and fill factor, F F , values increase with respect to x over the range 0.1−0.57. EQE measurements show that further increases in J SC value are limited by the band gap of the highly resistive transparent (HRT) ZnO layer. The methodology demonstrates a rapid route, compared to conventional experiments, to the further optimisation of CdTe solar cells.]]>

A combinatorial methodology has been adopted to determine the optimum composition of a Cd ( 1 − x)Zn x S window layer for CdTe solar cells. The methodology generated a large, self consistent dataset which permitted an unambiguous relationship between x, conversion efficiency and related cell parameters to be determined. An optimum composition of x = 0.57 was shown to maximise cell efficiency. Analysis of J − V curves, measured over 72 separate cells show that both short circuit current, J SC , and fill factor, F F , values increase with respect to x over the range 0.1−0.57. EQE measurements show that further increases in J SC value are limited by the band gap of the highly resistive transparent (HRT) ZnO layer. The methodology demonstrates a rapid route, compared to conventional experiments, to the further optimisation of CdTe solar cells.]]>
Thu, 16 Oct 2014 00:47:14 GMT /slideshow/a-combinatorial-approach-to-the-optimisation-of-cd-1x-zn-x-s-layers-for-cdte-solar-cells/40334047 RobertTreharne@slideshare.net(RobertTreharne) A Combinatorial Approach to the Optimisation of Cd (1−x) Zn x S Layers for CdTe Solar Cells RobertTreharne A combinatorial methodology has been adopted to determine the optimum composition of a Cd ( 1 − x)Zn x S window layer for CdTe solar cells. The methodology generated a large, self consistent dataset which permitted an unambiguous relationship between x, conversion efficiency and related cell parameters to be determined. An optimum composition of x = 0.57 was shown to maximise cell efficiency. Analysis of J − V curves, measured over 72 separate cells show that both short circuit current, J SC , and fill factor, F F , values increase with respect to x over the range 0.1−0.57. EQE measurements show that further increases in J SC value are limited by the band gap of the highly resistive transparent (HRT) ZnO layer. The methodology demonstrates a rapid route, compared to conventional experiments, to the further optimisation of CdTe solar cells. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/treharnerevision1-141016004714-conversion-gate01-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> A combinatorial methodology has been adopted to determine the optimum composition of a Cd ( 1 − x)Zn x S window layer for CdTe solar cells. The methodology generated a large, self consistent dataset which permitted an unambiguous relationship between x, conversion efficiency and related cell parameters to be determined. An optimum composition of x = 0.57 was shown to maximise cell efficiency. Analysis of J − V curves, measured over 72 separate cells show that both short circuit current, J SC , and fill factor, F F , values increase with respect to x over the range 0.1−0.57. EQE measurements show that further increases in J SC value are limited by the band gap of the highly resistive transparent (HRT) ZnO layer. The methodology demonstrates a rapid route, compared to conventional experiments, to the further optimisation of CdTe solar cells.
A Combinatorial Approach to the Optimisation of Cd (1−x) Zn x S Layers for CdTe Solar Cells from University of Liverpool
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A low-cost non-toxic post-growth activation step for CdTe solar cells /slideshow/a-lowcost-nontoxic-postgrowth-activation-step-for-cdte-solar-cells/40333882 nature134351-141016003935-conversion-gate01
Cadmium telluride, CdTe, is now firmly established as the basis for the market-leading thin-film solar-cell technology. With laboratory efficiencies approaching 20 per cent1, the research and development targets for CdTe are to reduce the cost of power generation further to less than half a US dollar per watt (ref. 2) and to minimize the environmental impact. A central part of the manufacturing process involves doping the polycrystalline thin-film CdTe with CdCl2. This acts to form the photovoltaic junction at the CdTe/CdS interface3, 4 and to passivate the grain boundaries5, making it essential in achieving high device efficiencies. However, although such doping has been almost ubiquitous since the development of this processing route over 25 years ago6, CdCl2 has two severe disadvantages; it is both expensive (about 30 cents per gram) and a water-soluble source of toxic cadmium ions, presenting a risk to both operators and the environment during manufacture. Here we demonstrate that solar cells prepared using MgCl2, which is non-toxic and costs less than a cent per gram, have efficiencies (around 13%) identical to those of a CdCl2-processed control group. They have similar hole densities in the active layer (9 × 1014 cm−3) and comparable impurity profiles for Cl and O, these elements being important p-type dopants for CdTe thin films. Contrary to expectation, CdCl2-processed and MgCl2-processed solar cells contain similar concentrations of Mg; this is because of Mg out-diffusion from the soda-lime glass substrates and is not disadvantageous to device performance. However, treatment with other low-cost chlorides such as NaCl, KCl and MnCl2 leads to the introduction of electrically active impurities that do compromise device performance. Our results demonstrate that CdCl2 may simply be replaced directly with MgCl2 in the existing fabrication process, thus both minimizing the environmental risk and reducing the cost of CdTe solar-cell production.]]>

Cadmium telluride, CdTe, is now firmly established as the basis for the market-leading thin-film solar-cell technology. With laboratory efficiencies approaching 20 per cent1, the research and development targets for CdTe are to reduce the cost of power generation further to less than half a US dollar per watt (ref. 2) and to minimize the environmental impact. A central part of the manufacturing process involves doping the polycrystalline thin-film CdTe with CdCl2. This acts to form the photovoltaic junction at the CdTe/CdS interface3, 4 and to passivate the grain boundaries5, making it essential in achieving high device efficiencies. However, although such doping has been almost ubiquitous since the development of this processing route over 25 years ago6, CdCl2 has two severe disadvantages; it is both expensive (about 30 cents per gram) and a water-soluble source of toxic cadmium ions, presenting a risk to both operators and the environment during manufacture. Here we demonstrate that solar cells prepared using MgCl2, which is non-toxic and costs less than a cent per gram, have efficiencies (around 13%) identical to those of a CdCl2-processed control group. They have similar hole densities in the active layer (9 × 1014 cm−3) and comparable impurity profiles for Cl and O, these elements being important p-type dopants for CdTe thin films. Contrary to expectation, CdCl2-processed and MgCl2-processed solar cells contain similar concentrations of Mg; this is because of Mg out-diffusion from the soda-lime glass substrates and is not disadvantageous to device performance. However, treatment with other low-cost chlorides such as NaCl, KCl and MnCl2 leads to the introduction of electrically active impurities that do compromise device performance. Our results demonstrate that CdCl2 may simply be replaced directly with MgCl2 in the existing fabrication process, thus both minimizing the environmental risk and reducing the cost of CdTe solar-cell production.]]>
Thu, 16 Oct 2014 00:39:34 GMT /slideshow/a-lowcost-nontoxic-postgrowth-activation-step-for-cdte-solar-cells/40333882 RobertTreharne@slideshare.net(RobertTreharne) A low-cost non-toxic post-growth activation step for CdTe solar cells RobertTreharne Cadmium telluride, CdTe, is now firmly established as the basis for the market-leading thin-film solar-cell technology. With laboratory efficiencies approaching 20 per cent1, the research and development targets for CdTe are to reduce the cost of power generation further to less than half a US dollar per watt (ref. 2) and to minimize the environmental impact. A central part of the manufacturing process involves doping the polycrystalline thin-film CdTe with CdCl2. This acts to form the photovoltaic junction at the CdTe/CdS interface3, 4 and to passivate the grain boundaries5, making it essential in achieving high device efficiencies. However, although such doping has been almost ubiquitous since the development of this processing route over 25 years ago6, CdCl2 has two severe disadvantages; it is both expensive (about 30 cents per gram) and a water-soluble source of toxic cadmium ions, presenting a risk to both operators and the environment during manufacture. Here we demonstrate that solar cells prepared using MgCl2, which is non-toxic and costs less than a cent per gram, have efficiencies (around 13%) identical to those of a CdCl2-processed control group. They have similar hole densities in the active layer (9 × 1014 cm−3) and comparable impurity profiles for Cl and O, these elements being important p-type dopants for CdTe thin films. Contrary to expectation, CdCl2-processed and MgCl2-processed solar cells contain similar concentrations of Mg; this is because of Mg out-diffusion from the soda-lime glass substrates and is not disadvantageous to device performance. However, treatment with other low-cost chlorides such as NaCl, KCl and MnCl2 leads to the introduction of electrically active impurities that do compromise device performance. Our results demonstrate that CdCl2 may simply be replaced directly with MgCl2 in the existing fabrication process, thus both minimizing the environmental risk and reducing the cost of CdTe solar-cell production. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/nature134351-141016003935-conversion-gate01-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Cadmium telluride, CdTe, is now firmly established as the basis for the market-leading thin-film solar-cell technology. With laboratory efficiencies approaching 20 per cent1, the research and development targets for CdTe are to reduce the cost of power generation further to less than half a US dollar per watt (ref. 2) and to minimize the environmental impact. A central part of the manufacturing process involves doping the polycrystalline thin-film CdTe with CdCl2. This acts to form the photovoltaic junction at the CdTe/CdS interface3, 4 and to passivate the grain boundaries5, making it essential in achieving high device efficiencies. However, although such doping has been almost ubiquitous since the development of this processing route over 25 years ago6, CdCl2 has two severe disadvantages; it is both expensive (about 30 cents per gram) and a water-soluble source of toxic cadmium ions, presenting a risk to both operators and the environment during manufacture. Here we demonstrate that solar cells prepared using MgCl2, which is non-toxic and costs less than a cent per gram, have efficiencies (around 13%) identical to those of a CdCl2-processed control group. They have similar hole densities in the active layer (9 × 1014 cm−3) and comparable impurity profiles for Cl and O, these elements being important p-type dopants for CdTe thin films. Contrary to expectation, CdCl2-processed and MgCl2-processed solar cells contain similar concentrations of Mg; this is because of Mg out-diffusion from the soda-lime glass substrates and is not disadvantageous to device performance. However, treatment with other low-cost chlorides such as NaCl, KCl and MnCl2 leads to the introduction of electrically active impurities that do compromise device performance. Our results demonstrate that CdCl2 may simply be replaced directly with MgCl2 in the existing fabrication process, thus both minimizing the environmental risk and reducing the cost of CdTe solar-cell production.
A low-cost non-toxic post-growth activation step for CdTe solar cells from University of Liverpool
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Non-parabolicity and band gap renormalisation in Si doped ZnO /slideshow/nonparabolicity-and-band-gap-renormalisation-in-si-doped-zno/40333541 treharne2014zno-si-141016002434-conversion-gate02
A combinatorial approach to developing doped transparent conductors and and an investigation into scattering and electronic structure of Si doped ZnO]]>

A combinatorial approach to developing doped transparent conductors and and an investigation into scattering and electronic structure of Si doped ZnO]]>
Thu, 16 Oct 2014 00:24:34 GMT /slideshow/nonparabolicity-and-band-gap-renormalisation-in-si-doped-zno/40333541 RobertTreharne@slideshare.net(RobertTreharne) Non-parabolicity and band gap renormalisation in Si doped ZnO RobertTreharne A combinatorial approach to developing doped transparent conductors and and an investigation into scattering and electronic structure of Si doped ZnO <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/treharne2014zno-si-141016002434-conversion-gate02-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> A combinatorial approach to developing doped transparent conductors and and an investigation into scattering and electronic structure of Si doped ZnO
Non-parabolicity and band gap renormalisation in Si doped ZnO from University of Liverpool
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