際際滷shows by User: babloosharma336 / http://www.slideshare.net/images/logo.gif 際際滷shows by User: babloosharma336 / Mon, 14 Sep 2020 02:41:56 GMT 際際滷Share feed for 際際滷shows by User: babloosharma336 Tailored interactions of the secondary coordination sphere enhance the hydrolytic activity of crosslinked microgels /slideshow/tailored-interactions-of-the-secondary-coordination-sphere-enhance-the-hydrolytic-activity-of-crosslinked-microgels/238469101 acscatal-200914024156
Tailored interactions of the secondary coordination sphere enhance the hydrolytic activity of crosslinked microgels]]>
Tailored interactions of the secondary coordination sphere enhance the hydrolytic activity of crosslinked microgels]]> Mon, 14 Sep 2020 02:41:56 GMT /slideshow/tailored-interactions-of-the-secondary-coordination-sphere-enhance-the-hydrolytic-activity-of-crosslinked-microgels/238469101 babloosharma336@slideshare.net(babloosharma336) Tailored interactions of the secondary coordination sphere enhance the hydrolytic activity of crosslinked microgels babloosharma336 Tailored interactions of the secondary coordination sphere enhance the hydrolytic activity of crosslinked microgels <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/acscatal-200914024156-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Tailored interactions of the secondary coordination sphere enhance the hydrolytic activity of crosslinked microgels
Tailored interactions of the secondary coordination sphere enhance the hydrolytic activity of crosslinked microgels from aaaa zzzz
]]> 58 0 https://cdn.slidesharecdn.com/ss_thumbnails/acscatal-200914024156-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Crosslinked Microgels as Platform for Hydrolytic Catalysts Article pubs.acs.org/Biomac /slideshow/crosslinked-microgels-as-platform-for-hydrolytic-catalysts-article-pubsacsorgbiomac/238469090 acs-200914024012
Crosslinked Microgels as Platform for Hydrolytic Catalysts ]]>
Crosslinked Microgels as Platform for Hydrolytic Catalysts ]]> Mon, 14 Sep 2020 02:40:12 GMT /slideshow/crosslinked-microgels-as-platform-for-hydrolytic-catalysts-article-pubsacsorgbiomac/238469090 babloosharma336@slideshare.net(babloosharma336) Crosslinked Microgels as Platform for Hydrolytic Catalysts Article pubs.acs.org/Biomac babloosharma336 Crosslinked Microgels as Platform for Hydrolytic Catalysts <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/acs-200914024012-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Crosslinked Microgels as Platform for Hydrolytic Catalysts
Crosslinked Microgels as Platform for Hydrolytic Catalysts Article pubs.acs.org/Biomac from aaaa zzzz
]]> 90 0 https://cdn.slidesharecdn.com/ss_thumbnails/acs-200914024012-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Biomimetic Glycoside Hydrolysis by a Microgel Templated with a Competitive Glycosidase Inhibitor /slideshow/biomimetic-glycoside-hydrolysis-by-a-microgel-templated-with-a-competitive-glycosidase-inhibitor/238468917 acscatal-200914021511
Biomimetic Glycoside Hydrolysis by a Microgel Templated with a Competitive Glycosidase Inhibitor]]>
Biomimetic Glycoside Hydrolysis by a Microgel Templated with a Competitive Glycosidase Inhibitor]]> Mon, 14 Sep 2020 02:15:11 GMT /slideshow/biomimetic-glycoside-hydrolysis-by-a-microgel-templated-with-a-competitive-glycosidase-inhibitor/238468917 babloosharma336@slideshare.net(babloosharma336) Biomimetic Glycoside Hydrolysis by a Microgel Templated with a Competitive Glycosidase Inhibitor babloosharma336 Biomimetic Glycoside Hydrolysis by a Microgel Templated with a Competitive Glycosidase Inhibitor <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/acscatal-200914021511-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Biomimetic Glycoside Hydrolysis by a Microgel Templated with a Competitive Glycosidase Inhibitor
Biomimetic Glycoside Hydrolysis by a Microgel Templated with a Competitive Glycosidase Inhibitor from aaaa zzzz
]]> 58 0 https://cdn.slidesharecdn.com/ss_thumbnails/acscatal-200914021511-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Modulating the Catalytic Performance of an Immobilized Catalyst with Matrix Effects - A Critical Evaluation /slideshow/modulating-the-catalytic-performance-of-an-immobilized-catalyst-with-matrix-effects-a-critical-evaluation/238468880 acscatal-200914020645
Modulating the Catalytic Performance of an Immobilized Catalyst with Matrix Effects - A Critical Evaluation]]>
Modulating the Catalytic Performance of an Immobilized Catalyst with Matrix Effects - A Critical Evaluation]]> Mon, 14 Sep 2020 02:06:45 GMT /slideshow/modulating-the-catalytic-performance-of-an-immobilized-catalyst-with-matrix-effects-a-critical-evaluation/238468880 babloosharma336@slideshare.net(babloosharma336) Modulating the Catalytic Performance of an Immobilized Catalyst with Matrix Effects - A Critical Evaluation babloosharma336 Modulating the Catalytic Performance of an Immobilized Catalyst with Matrix Effects - A Critical Evaluation <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/acscatal-200914020645-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Modulating the Catalytic Performance of an Immobilized Catalyst with Matrix Effects - A Critical Evaluation
Modulating the Catalytic Performance of an Immobilized Catalyst with Matrix Effects - A Critical Evaluation from aaaa zzzz
]]> 48 0 https://cdn.slidesharecdn.com/ss_thumbnails/acscatal-200914020645-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Babloo presentation /slideshow/babloo-presentation-90598237/90598237 babloopresentation-180314050759
Fluorinated polymer]]>
Fluorinated polymer]]> Wed, 14 Mar 2018 05:07:59 GMT /slideshow/babloo-presentation-90598237/90598237 babloosharma336@slideshare.net(babloosharma336) Babloo presentation babloosharma336 Fluorinated polymer <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/babloopresentation-180314050759-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Fluorinated polymer
Babloo presentation from aaaa zzzz
]]> 252 3 https://cdn.slidesharecdn.com/ss_thumbnails/babloopresentation-180314050759-thumbnail.jpg?width=120&height=120&fit=bounds presentation Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Transcript /slideshow/transcript-76360186/76360186 c7491fc9-e94f-439e-9e0c-2998460b182f-141214164817-conversion-gate01-170525233125
Transcript]]>
Transcript]]> Thu, 25 May 2017 23:31:25 GMT /slideshow/transcript-76360186/76360186 babloosharma336@slideshare.net(babloosharma336) Transcript babloosharma336 Transcript <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/c7491fc9-e94f-439e-9e0c-2998460b182f-141214164817-conversion-gate01-170525233125-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Transcript
Transcript from aaaa zzzz
]]> 403 5 https://cdn.slidesharecdn.com/ss_thumbnails/c7491fc9-e94f-439e-9e0c-2998460b182f-141214164817-conversion-gate01-170525233125-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 1 universe = 1 mole /slideshow/1-universe/76360154 1universe-170525232932
1 mole = 1 universe]]>
1 mole = 1 universe]]> Thu, 25 May 2017 23:29:32 GMT /slideshow/1-universe/76360154 babloosharma336@slideshare.net(babloosharma336) 1 universe = 1 mole babloosharma336 1 mole = 1 universe <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/1universe-170525232932-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> 1 mole = 1 universe
1 universe = 1 mole from aaaa zzzz
]]> 34 2 https://cdn.slidesharecdn.com/ss_thumbnails/1universe-170525232932-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Renewable resource and waste material derivatives for oil and gas recovery /slideshow/renewable-resource-and-waste-material-derivatives-for-oil-and-gas-recovery/74304678 renewableresourceandwastematerialderivativesforoilandgasrecovery-170404052430
A composition for hydraulic fracking is provided, which includes a proppant particle and a ground rubber tire particle.]]>
A composition for hydraulic fracking is provided, which includes a proppant particle and a ground rubber tire particle.]]> Tue, 04 Apr 2017 05:24:30 GMT /slideshow/renewable-resource-and-waste-material-derivatives-for-oil-and-gas-recovery/74304678 babloosharma336@slideshare.net(babloosharma336) Renewable resource and waste material derivatives for oil and gas recovery babloosharma336 A composition for hydraulic fracking is provided, which includes a proppant particle and a ground rubber tire particle. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/renewableresourceandwastematerialderivativesforoilandgasrecovery-170404052430-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> A composition for hydraulic fracking is provided, which includes a proppant particle and a ground rubber tire particle.
Renewable resource and waste material derivatives for oil and gas recovery from aaaa zzzz
]]> 33 2 https://cdn.slidesharecdn.com/ss_thumbnails/renewableresourceandwastematerialderivativesforoilandgasrecovery-170404052430-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Book cover novel semi fluorinated perfluorocycloalkenyl (pfca) aryl ether polymers /slideshow/book-cover-novel-semi-fluorinated-perfluorocycloalkenyl-pfca-aryl-ether-polymers/74304218 bookcovernovelsemi-fluorinatedperfluorocycloalkenylpfcaaryletherpolymers-170404051908
This book focuses on novel perflurocycloalkenyl (PFCA) aryl ether polymers, derived via polycondensation of perfluorocycloalkenes with bisphenols. Chapter 1 describes the detailed background of fluorine, its reactivity and effect in organic chemistry. This chapter also discusses the application of fluoropolymers with a detailed study of two fluoropolymers: perfluorocyclobutyl aryl ether polymers and fluorinated arylene vinylene ether polymers. Chapter 2, 3 and 4 describe the detailed synthesis, characterization and different properties of bis-PFCA aryl ether monomers, perfluorocyclopentenyl (PFCP) aryl ether polymers and perfluorocyclohexenyl (PFCH) aryl ether polymers, respectively. Chapter 3 also includes the potential crosslinking and post-functionalization studies of PFCA aryl ether polymers. Chapter 5 discusses the application section of these newly synthesized PFCA aryl ether polymers. Ultra low dielectric constant (k = 1.53) materials with self-cleansing properties were synthesized via incorporation of fluorodecyl-polyhedral oligomeric silsesquioxane (FD-POSS) into PFCP aryl ether polymers.]]>
This book focuses on novel perflurocycloalkenyl (PFCA) aryl ether polymers, derived via polycondensation of perfluorocycloalkenes with bisphenols. Chapter 1 describes the detailed background of fluorine, its reactivity and effect in organic chemistry. This chapter also discusses the application of fluoropolymers with a detailed study of two fluoropolymers: perfluorocyclobutyl aryl ether polymers and fluorinated arylene vinylene ether polymers. Chapter 2, 3 and 4 describe the detailed synthesis, characterization and different properties of bis-PFCA aryl ether monomers, perfluorocyclopentenyl (PFCP) aryl ether polymers and perfluorocyclohexenyl (PFCH) aryl ether polymers, respectively. Chapter 3 also includes the potential crosslinking and post-functionalization studies of PFCA aryl ether polymers. Chapter 5 discusses the application section of these newly synthesized PFCA aryl ether polymers. Ultra low dielectric constant (k = 1.53) materials with self-cleansing properties were synthesized via incorporation of fluorodecyl-polyhedral oligomeric silsesquioxane (FD-POSS) into PFCP aryl ether polymers.]]> Tue, 04 Apr 2017 05:19:08 GMT /slideshow/book-cover-novel-semi-fluorinated-perfluorocycloalkenyl-pfca-aryl-ether-polymers/74304218 babloosharma336@slideshare.net(babloosharma336) Book cover novel semi fluorinated perfluorocycloalkenyl (pfca) aryl ether polymers babloosharma336 This book focuses on novel perflurocycloalkenyl (PFCA) aryl ether polymers, derived via polycondensation of perfluorocycloalkenes with bisphenols. Chapter 1 describes the detailed background of fluorine, its reactivity and effect in organic chemistry. This chapter also discusses the application of fluoropolymers with a detailed study of two fluoropolymers: perfluorocyclobutyl aryl ether polymers and fluorinated arylene vinylene ether polymers. Chapter 2, 3 and 4 describe the detailed synthesis, characterization and different properties of bis-PFCA aryl ether monomers, perfluorocyclopentenyl (PFCP) aryl ether polymers and perfluorocyclohexenyl (PFCH) aryl ether polymers, respectively. Chapter 3 also includes the potential crosslinking and post-functionalization studies of PFCA aryl ether polymers. Chapter 5 discusses the application section of these newly synthesized PFCA aryl ether polymers. Ultra low dielectric constant (k = 1.53) materials with self-cleansing properties were synthesized via incorporation of fluorodecyl-polyhedral oligomeric silsesquioxane (FD-POSS) into PFCP aryl ether polymers. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/bookcovernovelsemi-fluorinatedperfluorocycloalkenylpfcaaryletherpolymers-170404051908-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> This book focuses on novel perflurocycloalkenyl (PFCA) aryl ether polymers, derived via polycondensation of perfluorocycloalkenes with bisphenols. Chapter 1 describes the detailed background of fluorine, its reactivity and effect in organic chemistry. This chapter also discusses the application of fluoropolymers with a detailed study of two fluoropolymers: perfluorocyclobutyl aryl ether polymers and fluorinated arylene vinylene ether polymers. Chapter 2, 3 and 4 describe the detailed synthesis, characterization and different properties of bis-PFCA aryl ether monomers, perfluorocyclopentenyl (PFCP) aryl ether polymers and perfluorocyclohexenyl (PFCH) aryl ether polymers, respectively. Chapter 3 also includes the potential crosslinking and post-functionalization studies of PFCA aryl ether polymers. Chapter 5 discusses the application section of these newly synthesized PFCA aryl ether polymers. Ultra low dielectric constant (k = 1.53) materials with self-cleansing properties were synthesized via incorporation of fluorodecyl-polyhedral oligomeric silsesquioxane (FD-POSS) into PFCP aryl ether polymers.
Book cover novel semi fluorinated perfluorocycloalkenyl (pfca) aryl ether polymers from aaaa zzzz
]]> 22 2 https://cdn.slidesharecdn.com/ss_thumbnails/bookcovernovelsemi-fluorinatedperfluorocycloalkenylpfcaaryletherpolymers-170404051908-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Sulfonated perfluorocyclopentenyl polymers and uses thereof /babloosharma336/sulfonated-perfluorocyclopentenyl-polymers-and-uses-thereof-63422499 sulfonatedperfluorocyclopentenylpolymersandusesthereof-160624173957
An aspect of the invention is directed to a polymer comprising a Sulfonated PerfluorocycIopentyl compound. Another aspect of the invention is directed to a sulfonated copolymer comprising one or more sulfonated polymers.A further aspect of the invention is directed to membranes prepared from the polymers of the claimed invention.]]>
An aspect of the invention is directed to a polymer comprising a Sulfonated PerfluorocycIopentyl compound. Another aspect of the invention is directed to a sulfonated copolymer comprising one or more sulfonated polymers.A further aspect of the invention is directed to membranes prepared from the polymers of the claimed invention.]]> Fri, 24 Jun 2016 17:39:57 GMT /babloosharma336/sulfonated-perfluorocyclopentenyl-polymers-and-uses-thereof-63422499 babloosharma336@slideshare.net(babloosharma336) Sulfonated perfluorocyclopentenyl polymers and uses thereof babloosharma336 An aspect of the invention is directed to a polymer comprising a Sulfonated PerfluorocycIopentyl compound. Another aspect of the invention is directed to a sulfonated copolymer comprising one or more sulfonated polymers.A further aspect of the invention is directed to membranes prepared from the polymers of the claimed invention. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/sulfonatedperfluorocyclopentenylpolymersandusesthereof-160624173957-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> An aspect of the invention is directed to a polymer comprising a Sulfonated PerfluorocycIopentyl compound. Another aspect of the invention is directed to a sulfonated copolymer comprising one or more sulfonated polymers.A further aspect of the invention is directed to membranes prepared from the polymers of the claimed invention.
Sulfonated perfluorocyclopentenyl polymers and uses thereof from aaaa zzzz
]]> 83 4 https://cdn.slidesharecdn.com/ss_thumbnails/sulfonatedperfluorocyclopentenylpolymersandusesthereof-160624173957-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Ultra low dielectric, self-cleansing and highly oleophobic POSS-PFCP aryl ether polymer composites /slideshow/ultra-low-dielectric-selfcleansing-and-highly-oleophobic-posspfcp-aryl-ether-polymer-composites-63422378/63422378 ultralowdielectriccomposites-160624173611
Ultra low dielectric constant (k 14 1.53) materials with self-cleansing properties were synthesized via incorporation of fluorodecyl-polyhedral oligomeric silsesquioxane (FD-POSS) into recently synthesized perfluorocyclopentenyl (PFCP) aryl ether polymers. Incorporation of fluorine rich, high free volume, and low surface energy POSS into a semifluorinated PFCP polymer matrix at various weight percentages resulted in a dramatic drop in dielectric constant, as well as a significant increase in hydrophobicity and oleophobicity of the system. These ultra-low dielectric self-cleansing materials (qtilt 14 38) were fabricated into electrospun mats from a solvent blend of fluorinated FD-POSS with PFCP polymers.]]>
Ultra low dielectric constant (k 14 1.53) materials with self-cleansing properties were synthesized via incorporation of fluorodecyl-polyhedral oligomeric silsesquioxane (FD-POSS) into recently synthesized perfluorocyclopentenyl (PFCP) aryl ether polymers. Incorporation of fluorine rich, high free volume, and low surface energy POSS into a semifluorinated PFCP polymer matrix at various weight percentages resulted in a dramatic drop in dielectric constant, as well as a significant increase in hydrophobicity and oleophobicity of the system. These ultra-low dielectric self-cleansing materials (qtilt 14 38) were fabricated into electrospun mats from a solvent blend of fluorinated FD-POSS with PFCP polymers.]]> Fri, 24 Jun 2016 17:36:11 GMT /slideshow/ultra-low-dielectric-selfcleansing-and-highly-oleophobic-posspfcp-aryl-ether-polymer-composites-63422378/63422378 babloosharma336@slideshare.net(babloosharma336) Ultra low dielectric, self-cleansing and highly oleophobic POSS-PFCP aryl ether polymer composites babloosharma336 Ultra low dielectric constant (k 14 1.53) materials with self-cleansing properties were synthesized via incorporation of fluorodecyl-polyhedral oligomeric silsesquioxane (FD-POSS) into recently synthesized perfluorocyclopentenyl (PFCP) aryl ether polymers. Incorporation of fluorine rich, high free volume, and low surface energy POSS into a semifluorinated PFCP polymer matrix at various weight percentages resulted in a dramatic drop in dielectric constant, as well as a significant increase in hydrophobicity and oleophobicity of the system. These ultra-low dielectric self-cleansing materials (qtilt 14 38鐃) were fabricated into electrospun mats from a solvent blend of fluorinated FD-POSS with PFCP polymers. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/ultralowdielectriccomposites-160624173611-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> Ultra low dielectric constant (k 14 1.53) materials with self-cleansing properties were synthesized via incorporation of fluorodecyl-polyhedral oligomeric silsesquioxane (FD-POSS) into recently synthesized perfluorocyclopentenyl (PFCP) aryl ether polymers. Incorporation of fluorine rich, high free volume, and low surface energy POSS into a semifluorinated PFCP polymer matrix at various weight percentages resulted in a dramatic drop in dielectric constant, as well as a significant increase in hydrophobicity and oleophobicity of the system. These ultra-low dielectric self-cleansing materials (qtilt 14 38鐃) were fabricated into electrospun mats from a solvent blend of fluorinated FD-POSS with PFCP polymers.
Ultra low dielectric, self-cleansing and highly oleophobic POSS-PFCP aryl ether polymer composites from aaaa zzzz
]]> 119 7 https://cdn.slidesharecdn.com/ss_thumbnails/ultralowdielectriccomposites-160624173611-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Bis-perfluorocycloalkenyl (PFCA) aryl ether monomers towards a versatile class of semi-fluorinated aryl ether polymers /slideshow/bisperfluorocycloalkenyl-pfca-aryl-ether-monomers-towards-a-versatile-class-of-semifluorinated-aryl-ether-polymers-63422330/63422330 bis-pfcamonomers-160624173423
A unique class of perfluorocycloalkenyl (PFCA) aryl ether monomers was synthesized from commercially available perfluorocycloalkenes (PFCAs) and bisphenols in good yields. This facile one pot reaction of per- fluorocycloalkenes, namely, octafluorocyclopentene (OFCP), and decafluorocyclohexene (DFCH), with bisphenols occurs at room temperature via an additionelimination reaction in the presence of a base. The synthesis of PFCA monomers and their condensation with bisphenols lead to perfluorocycloalkenyl (PFCA) aryl ether homopolymers and copolymers with random and/or alternating polymer architectures. 鐃種深鐃Published by Elsevier Ltd.]]>
A unique class of perfluorocycloalkenyl (PFCA) aryl ether monomers was synthesized from commercially available perfluorocycloalkenes (PFCAs) and bisphenols in good yields. This facile one pot reaction of per- fluorocycloalkenes, namely, octafluorocyclopentene (OFCP), and decafluorocyclohexene (DFCH), with bisphenols occurs at room temperature via an additionelimination reaction in the presence of a base. The synthesis of PFCA monomers and their condensation with bisphenols lead to perfluorocycloalkenyl (PFCA) aryl ether homopolymers and copolymers with random and/or alternating polymer architectures. 鐃種深鐃Published by Elsevier Ltd.]]> Fri, 24 Jun 2016 17:34:23 GMT /slideshow/bisperfluorocycloalkenyl-pfca-aryl-ether-monomers-towards-a-versatile-class-of-semifluorinated-aryl-ether-polymers-63422330/63422330 babloosharma336@slideshare.net(babloosharma336) Bis-perfluorocycloalkenyl (PFCA) aryl ether monomers towards a versatile class of semi-fluorinated aryl ether polymers babloosharma336 A unique class of perfluorocycloalkenyl (PFCA) aryl ether monomers was synthesized from commercially available perfluorocycloalkenes (PFCAs) and bisphenols in good yields. This facile one pot reaction of per- fluorocycloalkenes, namely, octafluorocyclopentene (OFCP), and decafluorocyclohexene (DFCH), with bisphenols occurs at room temperature via an additionelimination reaction in the presence of a base. The synthesis of PFCA monomers and their condensation with bisphenols lead to perfluorocycloalkenyl (PFCA) aryl ether homopolymers and copolymers with random and/or alternating polymer architectures. 鐃種深鐃Published by Elsevier Ltd. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/bis-pfcamonomers-160624173423-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> A unique class of perfluorocycloalkenyl (PFCA) aryl ether monomers was synthesized from commercially available perfluorocycloalkenes (PFCAs) and bisphenols in good yields. This facile one pot reaction of per- fluorocycloalkenes, namely, octafluorocyclopentene (OFCP), and decafluorocyclohexene (DFCH), with bisphenols occurs at room temperature via an additionelimination reaction in the presence of a base. The synthesis of PFCA monomers and their condensation with bisphenols lead to perfluorocycloalkenyl (PFCA) aryl ether homopolymers and copolymers with random and/or alternating polymer architectures. 鐃種深鐃Published by Elsevier Ltd.
Bis-perfluorocycloalkenyl (PFCA) aryl ether monomers towards a versatile class of semi-fluorinated aryl ether polymers from aaaa zzzz
]]> 123 5 https://cdn.slidesharecdn.com/ss_thumbnails/bis-pfcamonomers-160624173423-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Triarylamine-enchained semifluorinated perfluorocycloalkenyl (PFCA) aryl ether polymers /slideshow/triarylamineenchained-semifluorinated-perfluorocycloalkenyl-pfca-aryl-ether-polymers/63422283 pfcapolymers-160624173222
A variety of perfluorocycloalkenyl (PFCA) aryl ether monomers and polymers with enchained triarylamine units were successfully synthesized, characterized and reported here. These polymers are highly thermally stable and show variable thermal properties. Successful conver- sion of the newly synthesized TAA enchained perfluoro- cyclopentenyl (PFCP) aryl ether polymers via formylation and EAS demonstrates the synthetic versatility of TAA moiety and provides an excellent option for application specific post polymerization reactions. The cross-linking behavior of PFCP aryl ether polymers was studied under different reaction conditions. The combination of pro- cessability, thermal stabilities, and tailorability makes these polymers suitable for a wide variety of applications including electro-optics, proton exchange membranes and super-hydrophobic applications.]]>
A variety of perfluorocycloalkenyl (PFCA) aryl ether monomers and polymers with enchained triarylamine units were successfully synthesized, characterized and reported here. These polymers are highly thermally stable and show variable thermal properties. Successful conver- sion of the newly synthesized TAA enchained perfluoro- cyclopentenyl (PFCP) aryl ether polymers via formylation and EAS demonstrates the synthetic versatility of TAA moiety and provides an excellent option for application specific post polymerization reactions. The cross-linking behavior of PFCP aryl ether polymers was studied under different reaction conditions. The combination of pro- cessability, thermal stabilities, and tailorability makes these polymers suitable for a wide variety of applications including electro-optics, proton exchange membranes and super-hydrophobic applications.]]> Fri, 24 Jun 2016 17:32:22 GMT /slideshow/triarylamineenchained-semifluorinated-perfluorocycloalkenyl-pfca-aryl-ether-polymers/63422283 babloosharma336@slideshare.net(babloosharma336) Triarylamine-enchained semifluorinated perfluorocycloalkenyl (PFCA) aryl ether polymers babloosharma336 A variety of perfluorocycloalkenyl (PFCA) aryl ether monomers and polymers with enchained triarylamine units were successfully synthesized, characterized and reported here. These polymers are highly thermally stable and show variable thermal properties. Successful conver- sion of the newly synthesized TAA enchained perfluoro- cyclopentenyl (PFCP) aryl ether polymers via formylation and EAS demonstrates the synthetic versatility of TAA moiety and provides an excellent option for application specific post polymerization reactions. The cross-linking behavior of PFCP aryl ether polymers was studied under different reaction conditions. The combination of pro- cessability, thermal stabilities, and tailorability makes these polymers suitable for a wide variety of applications including electro-optics, proton exchange membranes and super-hydrophobic applications. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/pfcapolymers-160624173222-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> A variety of perfluorocycloalkenyl (PFCA) aryl ether monomers and polymers with enchained triarylamine units were successfully synthesized, characterized and reported here. These polymers are highly thermally stable and show variable thermal properties. Successful conver- sion of the newly synthesized TAA enchained perfluoro- cyclopentenyl (PFCP) aryl ether polymers via formylation and EAS demonstrates the synthetic versatility of TAA moiety and provides an excellent option for application specific post polymerization reactions. The cross-linking behavior of PFCP aryl ether polymers was studied under different reaction conditions. The combination of pro- cessability, thermal stabilities, and tailorability makes these polymers suitable for a wide variety of applications including electro-optics, proton exchange membranes and super-hydrophobic applications.
Triarylamine-enchained semifluorinated perfluorocycloalkenyl (PFCA) aryl ether polymers from aaaa zzzz
]]> 126 5 https://cdn.slidesharecdn.com/ss_thumbnails/pfcapolymers-160624173222-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Perfluorocyclohexenyl Aryl Ether Polymers via Polycondensation of Decafluorocyclohexene with Bisphenols /slideshow/perfluorocyclohexenyl-aryl-ether-polymers-via-polycondensation-of-decafluorocyclohexene-with-bisphenols/63422245 perfluorocyclohexenyl-aryl-ether-polymers-via-polycondensation-of-decafluorocyclohexene-with-bisphen-160624173012
ABSTRACT: A novel class of semifluorinated perfluorocyclohex- enyl (PFCH) aryl ether homo/copolymers was successfully synthesized with high yield through the step-growth polymer- ization of commercially available bisphenols and decafluorocy- clohexene in the presence of a triethylamine base. The synthesized polymers exhibit variable thermal properties depending on the functional spacer group (R). PFCH aryl ether copolymers with random and alternating architectures were also prepared from versatile bis-perfluorocyclohexenyl aryl ether monomers. The PFCH polymers show high thermal stabilities with a 5% decomposition temperature ranging from 359 to 444 鎔C in air and nitrogen atmosphere. These semifluori- nated PFCH aromatic ether polymers contain intact enchained PFCH olefin moieties, making further reactions such as cross- linking and application specific functionalization possible. VC 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 232238]]>
ABSTRACT: A novel class of semifluorinated perfluorocyclohex- enyl (PFCH) aryl ether homo/copolymers was successfully synthesized with high yield through the step-growth polymer- ization of commercially available bisphenols and decafluorocy- clohexene in the presence of a triethylamine base. The synthesized polymers exhibit variable thermal properties depending on the functional spacer group (R). PFCH aryl ether copolymers with random and alternating architectures were also prepared from versatile bis-perfluorocyclohexenyl aryl ether monomers. The PFCH polymers show high thermal stabilities with a 5% decomposition temperature ranging from 359 to 444 鎔C in air and nitrogen atmosphere. These semifluori- nated PFCH aromatic ether polymers contain intact enchained PFCH olefin moieties, making further reactions such as cross- linking and application specific functionalization possible. VC 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 232238]]> Fri, 24 Jun 2016 17:30:12 GMT /slideshow/perfluorocyclohexenyl-aryl-ether-polymers-via-polycondensation-of-decafluorocyclohexene-with-bisphenols/63422245 babloosharma336@slideshare.net(babloosharma336) Perfluorocyclohexenyl Aryl Ether Polymers via Polycondensation of Decafluorocyclohexene with Bisphenols babloosharma336 ABSTRACT: A novel class of semifluorinated perfluorocyclohex- enyl (PFCH) aryl ether homo/copolymers was successfully synthesized with high yield through the step-growth polymer- ization of commercially available bisphenols and decafluorocy- clohexene in the presence of a triethylamine base. The synthesized polymers exhibit variable thermal properties depending on the functional spacer group (R). PFCH aryl ether copolymers with random and alternating architectures were also prepared from versatile bis-perfluorocyclohexenyl aryl ether monomers. The PFCH polymers show high thermal stabilities with a 5% decomposition temperature ranging from 359 to 444 鎔C in air and nitrogen atmosphere. These semifluori- nated PFCH aromatic ether polymers contain intact enchained PFCH olefin moieties, making further reactions such as cross- linking and application specific functionalization possible. VC 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 232238 <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/perfluorocyclohexenyl-aryl-ether-polymers-via-polycondensation-of-decafluorocyclohexene-with-bisphen-160624173012-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> ABSTRACT: A novel class of semifluorinated perfluorocyclohex- enyl (PFCH) aryl ether homo/copolymers was successfully synthesized with high yield through the step-growth polymer- ization of commercially available bisphenols and decafluorocy- clohexene in the presence of a triethylamine base. The synthesized polymers exhibit variable thermal properties depending on the functional spacer group (R). PFCH aryl ether copolymers with random and alternating architectures were also prepared from versatile bis-perfluorocyclohexenyl aryl ether monomers. The PFCH polymers show high thermal stabilities with a 5% decomposition temperature ranging from 359 to 444 鎔C in air and nitrogen atmosphere. These semifluori- nated PFCH aromatic ether polymers contain intact enchained PFCH olefin moieties, making further reactions such as cross- linking and application specific functionalization possible. VC 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 232238
Perfluorocyclohexenyl Aryl Ether Polymers via Polycondensation of Decafluorocyclohexene with Bisphenols from aaaa zzzz
]]> 209 6 https://cdn.slidesharecdn.com/ss_thumbnails/perfluorocyclohexenyl-aryl-ether-polymers-via-polycondensation-of-decafluorocyclohexene-with-bisphen-160624173012-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 Perfluorocyclopentenyl (PFCP) Aryl Ether Polymers via Polycondensation of Octafluorocyclopentene with Bisphenols /slideshow/perfluorocyclopentenyl-pfcp-aryl-ether-polymers-via-polycondensation-of-octafluorocyclopentene-with-bisphenols-63422130/63422130 macromolecules201245766771-160624172539
ABSTRACT: A unique class of aromatic ether polymers containing perfluorocyclopentenyl (PFCP) enchainment was prepared from the simple step growth polycondensation of commercial bisphenols and octafluorocyclopentene (OFCP) in the presence of triethylamine. Model studies indicate that the second addition/elimination on OFCP is fast and poly- condensation results in linear homopolymers and copolymers without side products. The synthesis of bis(heptafluoro- cyclopentenyl) aryl ether monomers and their condensation with bisphenols further led to PFCP copolymers with alternating structures. This new class of semifluorinated polymers exhibit surprisingly high crystallinity in some cases and excellent thermal stability.]]>
ABSTRACT: A unique class of aromatic ether polymers containing perfluorocyclopentenyl (PFCP) enchainment was prepared from the simple step growth polycondensation of commercial bisphenols and octafluorocyclopentene (OFCP) in the presence of triethylamine. Model studies indicate that the second addition/elimination on OFCP is fast and poly- condensation results in linear homopolymers and copolymers without side products. The synthesis of bis(heptafluoro- cyclopentenyl) aryl ether monomers and their condensation with bisphenols further led to PFCP copolymers with alternating structures. This new class of semifluorinated polymers exhibit surprisingly high crystallinity in some cases and excellent thermal stability.]]> Fri, 24 Jun 2016 17:25:39 GMT /slideshow/perfluorocyclopentenyl-pfcp-aryl-ether-polymers-via-polycondensation-of-octafluorocyclopentene-with-bisphenols-63422130/63422130 babloosharma336@slideshare.net(babloosharma336) Perfluorocyclopentenyl (PFCP) Aryl Ether Polymers via Polycondensation of Octafluorocyclopentene with Bisphenols babloosharma336 ABSTRACT: A unique class of aromatic ether polymers containing perfluorocyclopentenyl (PFCP) enchainment was prepared from the simple step growth polycondensation of commercial bisphenols and octafluorocyclopentene (OFCP) in the presence of triethylamine. Model studies indicate that the second addition/elimination on OFCP is fast and poly- condensation results in linear homopolymers and copolymers without side products. The synthesis of bis(heptafluoro- cyclopentenyl) aryl ether monomers and their condensation with bisphenols further led to PFCP copolymers with alternating structures. This new class of semifluorinated polymers exhibit surprisingly high crystallinity in some cases and excellent thermal stability. <img style="border:1px solid #C3E6D8;float:right;" alt="" src="https://cdn.slidesharecdn.com/ss_thumbnails/macromolecules201245766771-160624172539-thumbnail.jpg?width=120&amp;height=120&amp;fit=bounds" /><br> ABSTRACT: A unique class of aromatic ether polymers containing perfluorocyclopentenyl (PFCP) enchainment was prepared from the simple step growth polycondensation of commercial bisphenols and octafluorocyclopentene (OFCP) in the presence of triethylamine. Model studies indicate that the second addition/elimination on OFCP is fast and poly- condensation results in linear homopolymers and copolymers without side products. The synthesis of bis(heptafluoro- cyclopentenyl) aryl ether monomers and their condensation with bisphenols further led to PFCP copolymers with alternating structures. This new class of semifluorinated polymers exhibit surprisingly high crystallinity in some cases and excellent thermal stability.
Perfluorocyclopentenyl (PFCP) Aryl Ether Polymers via Polycondensation of Octafluorocyclopentene with Bisphenols from aaaa zzzz
]]> 177 5 https://cdn.slidesharecdn.com/ss_thumbnails/macromolecules201245766771-160624172539-thumbnail.jpg?width=120&height=120&fit=bounds document Black http://activitystrea.ms/schema/1.0/post http://activitystrea.ms/schema/1.0/posted 0 https://public.slidesharecdn.com/v2/images/profile-picture.png U know how I am... ;) https://cdn.slidesharecdn.com/ss_thumbnails/acscatal-200914024156-thumbnail.jpg?width=320&height=320&fit=bounds slideshow/tailored-interactions-of-the-secondary-coordination-sphere-enhance-the-hydrolytic-activity-of-crosslinked-microgels/238469101 Tailored interactions ... https://cdn.slidesharecdn.com/ss_thumbnails/acs-200914024012-thumbnail.jpg?width=320&height=320&fit=bounds slideshow/crosslinked-microgels-as-platform-for-hydrolytic-catalysts-article-pubsacsorgbiomac/238469090 Crosslinked Microgels ... https://cdn.slidesharecdn.com/ss_thumbnails/acscatal-200914021511-thumbnail.jpg?width=320&height=320&fit=bounds slideshow/biomimetic-glycoside-hydrolysis-by-a-microgel-templated-with-a-competitive-glycosidase-inhibitor/238468917 Biomimetic Glycoside H...