Presentation used in EnviroInsite training workshop for description of geochemistry visualization tools such as the Piper, Stiff, Durov, and Schoeller Diagrams, scatter charts, and georeferenced Stiff Diagrams
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EnviroInsite training workshop - geochemistry visualization tools
2. What do we mean by geochemistry tools?
• Specialized graphics for assessment of
dominant aquatic ions
• Useful in characterizing ground-water
source areas
• What are the dominant aquatic ions?
Anions – HCO3, CO3, SO4, NO3, Cl, Fl
Cations – Ca, Mg, Na, K, Fe
EnviroInsite Training
3. What do we mean by geochemistry tools?
• Concentrations plotted as
milliequivalents per liter
• Conc. in meq/L = Conc.
in mg/L divided by
equivalent weight
• Equivalent weight – ion’s
atomic weight divided by
its valence
Carbonate
CO3
Molecular
Weight
60 amu
Valence
-2
Equivalent
Weight
-30 amu
Carbonate
CO3
Concentration 1200 mg/L
Concentration 4 milliequivalents/L
EnviroInsite Training
4. Entering Data for Geochemistry Tools
• Equivalent weight
entered in the
Constituents table
• Anion equivalent weight
entered as negative
values
Ion
Equivalent Weight
Cl
-35.45
HCO3
-61.01
SO4
-48
Mg
12.15
Na
22.99
K
39.1
Ca
20
Fl
-19
EnviroInsite Training
5. Conventional Stiff Diagram
• Cations on left / Anions on
Right
• Plotted in concentration units of
meq/L
EnviroInsite Training