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Geochemistry Tools
EnviroInsite Training Workshop
March 2013
What do we mean by geochemistry tools?
• Specialized graphics for assessment of
dominant aquatic ions
• Useful in characterizing ground-water
source areas
• What are the dominant aquatic ions?
Anions – HCO3, CO3, SO4, NO3, Cl, Fl
Cations – Ca, Mg, Na, K, Fe

EnviroInsite Training
What do we mean by geochemistry tools?
• Concentrations plotted as
milliequivalents per liter
• Conc. in meq/L = Conc.
in mg/L divided by
equivalent weight
• Equivalent weight – ion’s
atomic weight divided by
its valence

Carbonate

CO3

Molecular
Weight

60 amu

Valence

-2

Equivalent
Weight

-30 amu

Carbonate

CO3

Concentration 1200 mg/L

Concentration 4 milliequivalents/L

EnviroInsite Training
Entering Data for Geochemistry Tools
• Equivalent weight
entered in the
Constituents table
• Anion equivalent weight
entered as negative
values

Ion

Equivalent Weight

Cl

-35.45

HCO3

-61.01

SO4

-48

Mg

12.15

Na

22.99

K

39.1

Ca

20

Fl

-19

EnviroInsite Training
Conventional Stiff Diagram
• Cations on left / Anions on
Right
• Plotted in concentration units of
meq/L

EnviroInsite Training
Piper Diagram

EnviroInsite Training
Durov Diagram

EnviroInsite Training
Schoeller Diagram

EnviroInsite Training
Geochemistry Tools
Hands-on Exercise

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EnviroInsite training workshop - geochemistry visualization tools

  • 2. What do we mean by geochemistry tools? • Specialized graphics for assessment of dominant aquatic ions • Useful in characterizing ground-water source areas • What are the dominant aquatic ions? Anions – HCO3, CO3, SO4, NO3, Cl, Fl Cations – Ca, Mg, Na, K, Fe EnviroInsite Training
  • 3. What do we mean by geochemistry tools? • Concentrations plotted as milliequivalents per liter • Conc. in meq/L = Conc. in mg/L divided by equivalent weight • Equivalent weight – ion’s atomic weight divided by its valence Carbonate CO3 Molecular Weight 60 amu Valence -2 Equivalent Weight -30 amu Carbonate CO3 Concentration 1200 mg/L Concentration 4 milliequivalents/L EnviroInsite Training
  • 4. Entering Data for Geochemistry Tools • Equivalent weight entered in the Constituents table • Anion equivalent weight entered as negative values Ion Equivalent Weight Cl -35.45 HCO3 -61.01 SO4 -48 Mg 12.15 Na 22.99 K 39.1 Ca 20 Fl -19 EnviroInsite Training
  • 5. Conventional Stiff Diagram • Cations on left / Anions on Right • Plotted in concentration units of meq/L EnviroInsite Training