![SAFETY DATA SHEET
According to EC directive 2001/58/EC.
Shell Omala S2 G 220
Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020
5 / 14 800001005115
CL
Where material is heated, sprayed or mist formed, there is
greater potential for airborne concentrations to be generated.
General Information:
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product.
Ensure appropriate selection, testing and maintenance of
equipment used to control exposure, e.g. personal protective
equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or
maintenance.
Retain drain downs in sealed storage pending disposal or
subsequent recycle.
Always observe good personal hygiene measures, such as
washing hands after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard
contaminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
Personal protective equipment
Protective measures
Personal protective equipment (PPE) should meet recommended national standards. Check with
PPE suppliers.
Respiratory protection : No respiratory protection is ordinarily required under normal
conditions of use.
In accordance with good industrial hygiene practices,
precautions should be taken to avoid breathing of material.
If engineering controls do not maintain airborne
concentrations to a level which is adequate to protect worker
health, select respiratory protection equipment suitable for the
specific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are suitable, select an
appropriate combination of mask and filter.
Select a filter suitable for the combination of organic gases
and vapours and particles [Type A/Type P boiling point >65属C
(149属F)].
Hand protection
Remarks : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. PVC, neoprene or nitrile rubber
gloves Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, dexterity. Always seek advice
from glove suppliers. Contaminated gloves should be
replaced. Personal hygiene is a key element of effective hand](https://image.slidesharecdn.com/gsapmsds02054172-230606151852-2db2d088/85/GSAP_msds_02054172-PDF-5-320.jpg)
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- 1. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 1 / 14 800001005115 CL 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Shell Omala S2 G 220 Product code : 001D7837 Manufacturer or supplier's details Manufacturer/Supplier : Empresa Nacional de Energ鱈a ENEX S.A. Avenida del Condor # 520 Ciudad Empresarial Huechuraba Santiago de Chile Chile Telephone : (+562) 2 444 4000 Telefax : (+562) 2 444 4387 Emergency telephone number : (+562) 2 635 3800 ; Centro de Informaci坦n Toxicol坦gica de la Universidad Cat坦lica (CITUC) Recommended use of the chemical and restrictions on use Recommended use : Gear lubricant. 2. HAZARDS IDENTIFICATION Most important hazards Not a hazardous substance or mixture. Other hazards Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Used oil may contain harmful impurities. Not classified as flammable but will burn. 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Chemical nature : Highly refined mineral oils and additives. The highly refined mineral oil contains <3% (w/w) DMSO- extract, according to IP346. Hazardous components Chemical name / UN number CAS-No. Classification Concentration (% w/w)
- 2. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 2 / 14 800001005115 CL Amine phosphate 91745-46-9 Xi-N; R22-R41-R43- R51/53 0,1 - 0,9 For explanation of abbreviations see section 16. 4. FIRST-AID MEASURES If inhaled : No treatment necessary under normal conditions of use. If symptoms persist, obtain medical advice. In case of skin contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. In case of eye contact : Flush eye with copious quantities of water. Remove contact lenses, if present and easy to do. Continue rinsing. If persistent irritation occurs, obtain medical attention. If swallowed : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Most important symptoms and effects, both acute and delayed : Oil acne/folliculitis signs and symptoms may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. Protection of first-aiders : When administering first aid, ensure that you are wearing the appropriate personal protective equipment according to the incident, injury and surroundings. Notes to physician : Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable extinguishing media : Do not use water in a jet. Specific hazards during firefighting : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide may be evolved if incomplete combustion occurs. Unidentified organic and inorganic compounds. Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Special protective equipment : Proper protective equipment including chemical resistant
- 3. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 3 / 14 800001005115 CL for firefighters gloves are to be worn; chemical resistant suit is indicated if large contact with spilled product is expected. Self-Contained Breathing Apparatus must be worn when approaching a fire in a confined space. Select fire fighter's clothing approved to relevant Standards (e.g. Europe: EN469). 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Avoid contact with skin and eyes. Environmental precautions : Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for containment and cleaning up : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional advice : For guidance on selection of personal protective equipment see Section 8 of this Safety Data Sheet. For guidance on disposal of spilled material see Section 13 of this Safety Data Sheet. 7. HANDLING AND STORAGE General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Advice on safe handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Avoidance of contact : Strong oxidising agents. Product Transfer : Proper grounding and bonding procedures should be used during all bulk transfer operations to avoid static accumulation.
- 4. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 4 / 14 800001005115 CL Storage Other data : Keep container tightly closed and in a cool, well-ventilated place. Use properly labeled and closable containers. Store at ambient temperature. Packaging material : Suitable material: For containers or container linings, use mild steel or high density polyethylene. Unsuitable material: PVC. Container Advice : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis Oil mist, mineral Not Assigned TWA (inhalable fraction) 5 mg/m3 US. ACGIH Threshold Limit Values Biological occupational exposure limits No biological limit allocated. Monitoring Methods Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and samples analysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or contact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods http://www.cdc.gov/niosh/ Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods http://www.osha.gov/ Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances http://www.hse.gov.uk/ Institut f端r Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany http://www.dguv.de/inhalt/index.jsp L'Institut National de Recherche et de Securit辿, (INRS), France http://www.inrs.fr/accueil Engineering measures : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations.
- 5. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 5 / 14 800001005115 CL Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. General Information: Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or subsequent recycle. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Personal protective equipment Protective measures Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Respiratory protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for the combination of organic gases and vapours and particles [Type A/Type P boiling point >65属C (149属F)]. Hand protection Remarks : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection. PVC, neoprene or nitrile rubber gloves Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand
- 6. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 6 / 14 800001005115 CL care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same but recognize that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time maybe acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Eye protection : If material is handled such that it could be splashed into eyes, protective eyewear is recommended. Skin and body protection : Skin protection is not ordinarily required beyond standard work clothes. It is good practice to wear chemical resistant gloves. Thermal hazards : Not applicable Environmental exposure controls General advice : Take appropriate measures to fulfill the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Section 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Liquid at room temperature. Colour : brown Odour : Slight hydrocarbon Odour Threshold : Data not available pH : Not applicable pour point : -18 属C / -0,40 属FMethod: ISO 3016 Melting / freezing point Data not available Initial boiling point and boiling range : > 280 属C / 536 属Festimated value(s)
- 7. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 7 / 14 800001005115 CL Flash point : 240 属C / 464 属F Method: ISO 2592 Evaporation rate : Data not available Flammability (solid, gas) : Data not available Upper explosion limit : Typical 10 %(V) Lower explosion limit : Typical 1 %(V) Vapour pressure : < 0,5 Pa (20 属C / 68 属F) estimated value(s) Relative vapour density : > 1estimated value(s) Relative density : 0,899 (15 属C / 59 属F) Density : 899 kg/m3 (15,0 属C / 59,0 属F) Method: ISO 12185 Solubility(ies) Water solubility : negligible Solubility in other solvents : Data not available Partition coefficient: n- octanol/water : log Pow: > 6(based on information on similar products) Auto-ignition temperature : > 320 属C / 608 属F Decomposition temperature : Data not available Viscosity Viscosity, dynamic : Data not available Viscosity, kinematic : 220 mm2/s (40,0 属C / 104,0 属F) Method: ISO 3104 19,4 mm2/s (100 属C / 212 属F) Method: ISO 3104 Explosive properties : Not classified Oxidizing properties : Data not available Conductivity : This material is not expected to be a static accumulator.
- 8. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 8 / 14 800001005115 CL 10. STABILITY AND REACTIVITY Reactivity : The product does not pose any further reactivity hazards in addition to those listed in the following sub-paragraph. Chemical stability : Stable. Possibility of hazardous reactions : Reacts with strong oxidising agents. Conditions to avoid : Extremes of temperature and direct sunlight. Incompatible materials : Strong oxidising agents. Hazardous decomposition products : No decomposition if stored and applied as directed. 11. TOXICOLOGICAL INFORMATION Basis for assessment : Information given is based on data on the components and the toxicology of similar products.Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Information on likely routes of exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Acute toxicity Product: Acute oral toxicity : LD50 rat: > 5.000 mg/kg Remarks: Low toxicity: Based on available data, the classification criteria are not met. Acute inhalation toxicity : Remarks: Based on available data, the classification criteria are not met. Acute dermal toxicity : LD50 Rabbit: > 5.000 mg/kg Remarks: Low toxicity: Based on available data, the classification criteria are not met. Skin corrosion/irritation Product: Remarks: Slightly irritating to skin., Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis., Based on available data, the classification criteria are not met. Serious eye damage/eye irritation Product: Remarks: Slightly irritating to the eye., Based on available data, the classification criteria are not
- 9. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 9 / 14 800001005115 CL met. Components: Amine phosphate: Remarks: Based on available data, the classification criteria are not met. Respiratory or skin sensitisation Product: Remarks: Not a skin sensitiser. Based on available data, the classification criteria are not met. Components: Amine phosphate: Remarks: Experimental data has shown that the concentration of potentially sensitising components present in this product does not induce skin sensitisation. May cause an allergic skin reaction in sensitive individuals. Germ cell mutagenicity Product: Remarks: Non mutagenic, Based on available data, the classification criteria are not met. Carcinogenicity Product: Remarks: Not a carcinogen., Based on available data, the classification criteria are not met. Remarks: Product contains mineral oils of types shown to be non-carcinogenic in animal skin- painting studies., Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer (IARC). Material GHS/CLP Carcinogenicity Classification Highly refined mineral oil No carcinogenicity classification. Reproductive toxicity Product: Remarks: Not a developmental toxicant., Does not impair fertility., Based on available data, the classification criteria are not met. STOT - single exposure Product:
- 10. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 10 / 14 800001005115 CL Remarks: Based on available data, the classification criteria are not met. STOT - repeated exposure Product: Remarks: Based on available data, the classification criteria are not met. Aspiration toxicity Product: Not an aspiration hazard. Further information Product: Remarks: Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal., ALL used oil should be handled with caution and skin contact avoided as far as possible. Remarks: Slightly irritating to respiratory system. 12. ECOLOGICAL INFORMATION Basis for assessment : Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s).(LL/EL/IL50 expressed as the nominal amount of product required to prepare aqueous test extract). Ecotoxicity Product: Toxicity to fish (Acute toxicity) : Remarks: LL/EL/IL50 > 100 mg/l Practically non toxic: Based on available data, the classification criteria are not met. Toxicity to crustacean (Acute toxicity) : Remarks: LL/EL/IL50 > 100 mg/l Practically non toxic: Based on available data, the classification criteria are not met. Toxicity to algae/aquatic plants (Acute toxicity) : Remarks: LL/EL/IL50 > 100 mg/l Practically non toxic: Based on available data, the classification criteria are not met.
- 11. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 11 / 14 800001005115 CL Toxicity to fish (Chronic toxicity) : Remarks: Data not available Toxicity to crustacean (Chronic toxicity) : Remarks: Data not available Toxicity to microorganisms (Acute toxicity) : Remarks: Data not available Persistence and degradability Product: Biodegradability : Remarks: Not readily biodegradable., Major constituents are inherently biodegradable, but contains components that may persist in the environment. Bioaccumulative potential Product: Bioaccumulation : Remarks: Contains components with the potential to bioaccumulate. Partition coefficient: n- octanol/water : log Pow: > 6Remarks: (based on information on similar products) Mobility in soil Product: Mobility : Remarks: Liquid under most environmental conditions., If it enters soil, it will adsorb to soil particles and will not be mobile. Remarks: Floats on water. Other adverse effects no data available Product: Additional ecological information : Does not have ozone depletion potential, photochemical ozone creation potential or global warming potential., Product is a mixture of non-volatile components, which will not be released to air in any significant quantities under normal conditions of use. Poorly soluble mixture., Causes physical fouling of aquatic organisms. Mineral oil does not cause chronic toxicity to aquatic organisms at concentrations less than 1 mg/l. 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations.
- 12. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 12 / 14 800001005115 CL Do not dispose into the environment, in drains or in water courses Waste product should not be allowed to contaminate soil or ground water, or be disposed of into the environment. Waste, spills or used product is dangerous waste. Contaminated packaging : Dispose in accordance with prevailing regulations, preferably to a recognized collector or contractor. The competence of the collector or contractor should be established beforehand. Disposal should be in accordance with applicable regional, national, and local laws and regulations. Local legislation Remarks : Disposal should be in accordance with applicable regional, national, and local laws and regulations. 14. TRANSPORT INFORMATION National Regulations International Regulations ADR Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. MARPOL Annex 1 rules apply for bulk shipments by sea. Special precautions for user Remarks : Special Precautions: Refer to Section 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport. 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. DS 090 - 1996. Ministry of Economic Development and Reconstruction. DS 375 - 1985. Ministry of Economic Development and Reconstruction. DS 594 - 2000. Ministry of Health. DS 298 - 1995. Ministry of Transport and Telecommunications.
- 13. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 13 / 14 800001005115 CL Labelling according to EC 548/67, EC 45/1999 Symbol(s) : No Hazard Symbol required Risk phrase(s) : Not classified. Safety phrase(s) : Not classified. Sensitising components : Contains amine phosphate. May produce an allergic reaction. Other international regulations The components of this product are reported in the following inventories: EINECS : All components listed or polymer exempt. TSCA : All components listed. 16. OTHER INFORMATION Full text of R-Phrases R22 Harmful if swallowed. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Abbreviations and Acronyms : The standard abbreviations and acronyms used in this document can be looked up in reference literature (e.g. scientific dictionaries) and/or websites. SDS Regulation : The content and format of this safety data sheet is in accordance with Commission Directive 2001/58/EC of 27 July 2001, amending for the secondtime Commission Directive 91/155/EEC. Further information Training advice : Provide adequate information, instruction and training for operators. Other information : A vertical bar (|) in the left margin indicates an amendment from the previous version. Sources of key data used to compile the Safety Data Sheet : The quoted data are from, but not limited to, one or more sources of information (e.g. toxicological data from Shell Health Services, material suppliers data, CONCAWE, EU IUCLID date base, EC 1272 regulation, etc).
- 14. SAFETY DATA SHEET According to EC directive 2001/58/EC. Shell Omala S2 G 220 Version 1.3 Revision Date 06/05/2020 Print Date 06/06/2020 14 / 14 800001005115 CL This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.