09 104ָѧ
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![104ָ 2
W 7
- 2 -
6. ͬ W y B ] e b 2.0 3NH (g) c 1.6
H C l ( g ) D 1 ֮ _ y w l F
ɫ w w 27 C 87 Ct
һ ֵ B y w e Ӌ
(A) 0.20 (B) 0.24 (C) 0.40 (D) 0.48 (E) 1.8
7. ij һ W ^ E
E 1 3 2 2H O (aq) HOOH(aq) HOOH (aq) H O(aq)? ?
? ??? ?
E 2 2 2HOOH (aq) Br (aq) HOBr(aq) H O(aq)? ?
? ??? ?
E 3 3 2HOBr(aq) HOOH(aq) Br (aq) H O (aq) O (g)? ?
? ??? ? ?
W E | ɫ һ _
(A) 3H O (aq)?
g (B) HOBr(aq) (C) Br (aq)?
(D) 2HOOH (aq)?
(E) 2H O(aq) g
8. P 2
S ?
Cl?
Ar K?
2
Ca ?
N ԭ x һ e `
(A)
(B) 2
S ?
16
(C) ܉ ͬ
(D) С 2
S ?
Cl?
Ar K?
2
Ca ?
(E) Cl (g) Cl (g) e? ?
? ? Ҫ H ֵ Ԫ
9. H N O N Ԫ M N _
2 2 2 22 H O 2 H O + O? ֪ 2 2H O ߀ ԭ
2 4N H ] p I
NO 2N O 2NO ͬ
3NH c 2H O g I O
(A)ֻ (B)ֻ (C) c (D) c (E) c
10. V c N
25 u ͬ B w e Һ r | С t
һ x _
(A) (B) (C)
(D) (E)
y
1.0
2.0 ≺
1.0
1.6 ≺
D 1](https://image.slidesharecdn.com/09-104-150701080043-lva1-app6891/85/09-104-3-320.jpg)
![104ָ 4
W 7
- 4 -
15. ] ij w X w Y w Z һ
(g) (g) (gX Y Z H = J) k /molm n p q?
ʽ m n p S O X Y Z w ƽ
cK ʾ ƽ pK cK pK r ƽ
Ҳ t һ _
(A) 0q
(B) m n p?
(C) _ ƽ w e t ƽ
(D) _ ƽ Ar(g) t ƽ
(E) _ ƽ Y w t ϵ y _ ƽ r Z
w
16. S ء Ѫ Ѫ Һ ѭ h ֹ Ѫ
Ч ⣬ Ҳ ~ ζ ԭ ֮ һij һ ֮ Y
D 4
P һ _
(A) ˮ
(B) g I
(C) Y
(D)Y u c
(E)c ԇ a t ɫ
x } ռ 3 6
f17}25}ÿ}5x헣һ_x헡Ո
_x헮ӛڴ𰸿֮x}𰸅^}֮x헪жx
ߣ4֣e1xߣ2.4֣e2xߣ0.8֣
e2x헻x헾δߣԓ}Ӌ㡣
17. P ̼ ϩ
| Щ _
(A) | ?I
(B) | c
(C) Һ B r | g I
(D) | · ˹ Y
(E) Һ B r | g Ҫ ɢ
18. θ pH ֵ s 1.5 c θ P Щ _
(A) pOHs 12.5 (B) x s 1.5M
(C) x s 1.5ppm (D) x s 0.03M
(E) x s 0.003M
D 4](https://image.slidesharecdn.com/09-104-150701080043-lva1-app6891/85/09-104-5-320.jpg)
![104ָ 6
W 7
- 6 -
23. u y R ԇ E 10 mL Ǭ Q ԇ
0.60 M y Һ 3.0 mL Ȼ 2.5 M NaOH Һ 0.15 mL
s 2.0 mL 2.0 M ˮ ԇ 10% Һ 6
0.30 mL K ˮ ᣬt a y R P
Щ _
(A) ԇ
(B) Y f ߀ ԭ
(C)y R w | W ʽ 2Ag O
(D) ȡ t ͬ y R a
(E) ˮ Ŀ a y e x 3 2[Ag(NH ) ]?
24. C ~ Y ʽ
P @ Щ C Щ _
(A) c
(B) t Һ
(C) ߀ ԭ c ԇ a y R
(D) ˮ Ҫ 3 3NH CH(CH )COO? ? ʽ
(E) c c a } ʳ
25. ͬ W 25 1 y X 2Y Z? ? D 6 c 7
M y X c r g P S P ԓ
Щ _
(A) Y
(B)
(C) X ʼ 0.067 M
(D) ^ X ֮ g ײ l
(E) X ׃ Xͣ ֹ
0 2 4 6 8 10 12
0.010
0.015
0.020
0.025
0.030
0.035
0.040
[A](M)
rg()
D һ
0 2 4 6 8 10 12
10
20
30
40
50
60
70
80
90
100
1/[A](M-1)
rg()
D
rg룩
D 7
0 2 4 6 8 10 12
0.010
0.015
0.020
0.025
0.030
0.035
0.040
[A](M)
rg()
D һ
0 2 4 6 8 10 12
10
20
30
40
50
60
70
80
90
100
1/[A](M-1)
rg()
D
[X]
M
rg룩
D 6](https://image.slidesharecdn.com/09-104-150701080043-lva1-app6891/85/09-104-7-320.jpg)
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09 104ָѧ
- 1. WWԇ 104WָĿԇԇ} ѧ ע헣 ԇrg80 ʽ Bx} 2B UPڡ𰸿𣻸rƤ ãʹҺ Bx}ùP^֮ɫīˮĹPڡ𰸾 rʹҺ BδҎӛ𰸿CoR𰸣δʹ ɫīˮĹP𰸾uˆToJC ֮ߣɿгГ B𰸾ÿһҪa Y fYϣɹش}֮ һԪLڱ1~36 ̖Ԫأ 1 H 1.0 2 He 4.0 3 Li 6.9 4 Be 9.0 5 B 10.8 6 C 12.0 7 N 14.0 8 O 16.0 9 F 19.0 10 Ne 20.2 11 Na 23.0 12 Mg 24.3 13 Al 27.0 14 Si 28.1 15 P 31.0 16 S 32.1 17 Cl 35.5 18 Ar 40.0 19 K 39.1 20 Ca 40.1 21 Sc 45.0 22 Ti 47.9 23 V 50.9 24 Cr 52.0 25 Mn 54.9 26 Fe 55.8 27 Co 58.9 28 Ni 58.7 29 Cu 63.5 30 Zn 65.4 31 Ga 69.7 32 Ge 72.6 33 As 74.9 34 Se 79.0 35 Br 79.9 36 Kr 83.8 w 1 1 1 1 R 0 08205 L atm K mol 8 31 J K mol? ? ? ? ? ?. . ̪׃ɫpH 8.2~10.0͞oɫ|͞ۼtɫ ġlog2 0.30? log3 0.48?
- 2. 1 104ָ 7 W - 1 - Ҽ x } ռ 84 һ x } ռ 4 8 f1}16}ÿ}5x헣ֻһ_mx헣Ո ӛڴ𰸿֮x}𰸅^}ߣ3֣eδ ӛһxߣԓ}Ӌ㡣 1. V c } ʳ I B h ÿ ÿ ʳ c 2400 ˡ 2400 c Q H z ȡ ʳ } t һ ֵ (A)0.5 (B)1 (C)3 (D)6 (E)10 2. ƽ Ϫ H ֪ c ӡ c ᣬ Ƚ Ƚ N P N Ҫ ԭ һ _ (A) ȼ r ȥ w p (B) ȼ w Û (C) ȼ w ׃ w (D) ȼ w Û ׃ (E) ȼ w ײ l 3. 2.0 2X w c 1.0 2Y w ȫ o ʣ N a 2.0 R wt һ x R W ʽ O w w ǰ ͬ ͬ l (A) XY (B) 2XY (C) 3XY (D) 2X Y (E) 3X Y 4. ͬ W u 0.100 M c ˮ Һ һ δ ֪ } Һ ^ ʹ һ (A) (B) (C) (D) (E) 5. P W һ _ (A) (B) ׃ ; Ҳ ׃ (C) w t (D) c P S (E) һ S r g p С
- 3. 104ָ 2 W 7 - 2 - 6. ͬ W y B ] e b 2.0 3NH (g) c 1.6 H C l ( g ) D 1 ֮ _ y w l F ɫ w w 27 C 87 Ct һ ֵ B y w e Ӌ (A) 0.20 (B) 0.24 (C) 0.40 (D) 0.48 (E) 1.8 7. ij һ W ^ E E 1 3 2 2H O (aq) HOOH(aq) HOOH (aq) H O(aq)? ? ? ??? ? E 2 2 2HOOH (aq) Br (aq) HOBr(aq) H O(aq)? ? ? ??? ? E 3 3 2HOBr(aq) HOOH(aq) Br (aq) H O (aq) O (g)? ? ? ??? ? ? W E | ɫ һ _ (A) 3H O (aq)? g (B) HOBr(aq) (C) Br (aq)? (D) 2HOOH (aq)? (E) 2H O(aq) g 8. P 2 S ? Cl? Ar K? 2 Ca ? N ԭ x һ e ` (A) (B) 2 S ? 16 (C) ܉ ͬ (D) С 2 S ? Cl? Ar K? 2 Ca ? (E) Cl (g) Cl (g) e? ? ? ? Ҫ H ֵ Ԫ 9. H N O N Ԫ M N _ 2 2 2 22 H O 2 H O + O? ֪ 2 2H O ߀ ԭ 2 4N H ] p I NO 2N O 2NO ͬ 3NH c 2H O g I O (A)ֻ (B)ֻ (C) c (D) c (E) c 10. V c N 25 u ͬ B w e Һ r | С t һ x _ (A) (B) (C) (D) (E) y 1.0 2.0 ≺ 1.0 1.6 ≺ D 1
- 4. 3 104ָ 7 W - 3 - CH2C CH3 CH CH2CH C CH2 H3C CH2CH CH CHH3C C C CH2 H3C H CH2 C C CH2 H3C CH2 H n n n n CH2 n (A) (B) (C) (D) (E) CH2C CH3 CH CH2CH C CH2 H3C CH2CH CH CHH3C C C CH2 H3C H CH2 C C CH2 H3C CH2 H n n n n CH2 n (A) (B) (C) (D) (E) CH2C CH3 CH CH2CH C CH2 H3C CH2CH CH CHH3C C C CH2 H3C H CH2 C C CH2 H3C CH2 H n n n n CH2 n (A) (B) (C) (D) (E) CH2C CH3 CH CH2CH C CH2 H3C CH2CH CH CHH3C C C CH2 H3C H CH2 C C CH2 H3C CH2 H n n n n CH2 n (A) (B) (C) (D) (E) CH2C CH3 CH CH2CH C CH2 H3C CH2CH CH CHH3C C C CH2 H3C H CH2 C C CH2 H3C CH2 H n n n n CH2 n (A) (B) (C) (D) (E) 11-12 } M 0.1M N ˮ Һ 3AgNO NaBr HCl 2Na S 2 3Na CO D 2 ʾ P S D ÿ l B Һ @ J W ԇ ÿ һ N Һ D λ } 11~12 11. һ W ʽ Һ | (A) 3AgNO (B) NaBr (C) HCl (D) 2Na S (E) 2 3Na CO 12. һ W ʽ Һ | (A) 3AgNO (B) NaBr (C) HCl (D) 2Na S (E) 2 3Na CO 13. ϩ W 2- -1,3- ϩ a ϩ һ x ϩ (A) (B) (C) (D) (E) 14. D 3 ̼ c Һ 0.1000M } D ɫ ^ K ָ ʾ ׃ ɫ D c w e HClV mL 0 10.00 25.00 40.00 48.00 48.00 50.00 55.00 ԇ ^ ̎ Һ n | (A)ֻ (B)ֻ (C) c (D) c (E) c D 2 12 10 8 6 4 2 0 0 10 20 30 40 50 60 pH D 3
- 5. 104ָ 4 W 7 - 4 - 15. ] ij w X w Y w Z һ (g) (g) (gX Y Z H = J) k /molm n p q? ʽ m n p S O X Y Z w ƽ cK ʾ ƽ pK cK pK r ƽ Ҳ t һ _ (A) 0q (B) m n p? (C) _ ƽ w e t ƽ (D) _ ƽ Ar(g) t ƽ (E) _ ƽ Y w t ϵ y _ ƽ r Z w 16. S ء Ѫ Ѫ Һ ѭ h ֹ Ѫ Ч ⣬ Ҳ ~ ζ ԭ ֮ һij һ ֮ Y D 4 P һ _ (A) ˮ (B) g I (C) Y (D)Y u c (E)c ԇ a t ɫ x } ռ 3 6 f17}25}ÿ}5x헣һ_x헡Ո _x헮ӛڴ𰸿֮x}𰸅^}֮x헪жx ߣ4֣e1xߣ2.4֣e2xߣ0.8֣ e2x헻x헾δߣԓ}Ӌ㡣 17. P ̼ ϩ | Щ _ (A) | ?I (B) | c (C) Һ B r | g I (D) | · ˹ Y (E) Һ B r | g Ҫ ɢ 18. θ pH ֵ s 1.5 c θ P Щ _ (A) pOHs 12.5 (B) x s 1.5M (C) x s 1.5ppm (D) x s 0.03M (E) x s 0.003M D 4
- 6. 5 104ָ 7 W - 5 - D 5 H2N O OH PABA N O O DMAB 19. W I Y W | Q Ӱ 푣 ܉ W I Փ ֮ һ P ܉ Щ _ (A) Ȳ I 2 I c 1 I (B) ϩ I 2 ̼ ԭ 2 sp ܉ B (C) Ȳ ̼ ԭ 2 sp ܉ ֱ (D)ˮ Σ ԭ 4 3 sp ܉ У 2 (E) ԭ 3 ͬ 2 sp ܉ e c 3 3p܉ I Y 3 I 20. P 2- ϩ 2- ϩ 2- ϩ 1- ϩ Щ _ (A) c ^ i Һ (B)ֻ 2- ϩ 2- ϩ (C)ֻ 2- ϩ 2- ϩ 1- ϩ Y (D)M r ֻ 2- ϩ 2- ϩ ͬ a (E) ˮ z r ֻ 2- ϩ 2- ϩ ɫ 21. \ y ʽ ʾ 2 Zn(s) | Zn (aq) Ag (aq) | Ag(s)? ? } P \ y Щ _ (A) ȫ 2 Zn(s) 2 Ag (aq) Zn (aq) 2 Ag(s)? ? ? ? ? (B) r \ O · y O (C) һ ʾ ʽ O (D) Ag? a Ag y ʾ Ag (aq) Ag(s)? | (E) һ ֱ y ߀ ԭ λ p ȥ \ ߀ ԭ λ 22. ij Щ C PABA DMAB @ D 5 ʾ P @ C Щ _ (A)PABA ? ? (B)DMAB (C)PABA c (D)DMAB (E)PABA DMAB
- 7. 104ָ 6 W 7 - 6 - 23. u y R ԇ E 10 mL Ǭ Q ԇ 0.60 M y Һ 3.0 mL Ȼ 2.5 M NaOH Һ 0.15 mL s 2.0 mL 2.0 M ˮ ԇ 10% Һ 6 0.30 mL K ˮ ᣬt a y R P Щ _ (A) ԇ (B) Y f ߀ ԭ (C)y R w | W ʽ 2Ag O (D) ȡ t ͬ y R a (E) ˮ Ŀ a y e x 3 2[Ag(NH ) ]? 24. C ~ Y ʽ P @ Щ C Щ _ (A) c (B) t Һ (C) ߀ ԭ c ԇ a y R (D) ˮ Ҫ 3 3NH CH(CH )COO? ? ʽ (E) c c a } ʳ 25. ͬ W 25 1 y X 2Y Z? ? D 6 c 7 M y X c r g P S P ԓ Щ _ (A) Y (B) (C) X ʼ 0.067 M (D) ^ X ֮ g ײ l (E) X ׃ Xͣ ֹ 0 2 4 6 8 10 12 0.010 0.015 0.020 0.025 0.030 0.035 0.040 [A](M) rg() D һ 0 2 4 6 8 10 12 10 20 30 40 50 60 70 80 90 100 1/[A](M-1) rg() D rg룩 D 7 0 2 4 6 8 10 12 0.010 0.015 0.020 0.025 0.030 0.035 0.040 [A](M) rg() D һ 0 2 4 6 8 10 12 10 20 30 40 50 60 70 80 90 100 1/[A](M-1) rg() D [X] M rg룩 D 6
- 8. 7 104ָ 7 W - 7 - E x } ռ 1 6 fֹж}𰸱회ڡ𰸾ϣK}̖ژ}̖һ c}̖12rس}Ӌ}회Ӌ^̣ 𰸑Bͬλ˳ձʹùP^֮ɫīˮĹP ҲʹUPÿһ}֘}ĩ һ N Ԫ أ ̖ 飺WXYZ Ԫ L ͬ L H X c Y ͬ c ԭ Z ֪ (1) W һ L (2) Ԫ ԭ 78 (3) W X Y Ԫ M Q (4) Q 6 ԭ 42 | 82 (5) 2Z ɫ w N A | (6) 2Z Z? x ˮ ɫ x 3Z? } ÿ һ } 2 8 1. W Z Ԫ ̖ 2. Xc Y N Ԫ M N W ʽ 3. Q W ʽ 4. 0.1M 3Z? ˮ Һ 0.1M Qˮ Һt Һ o ɫ ԓ ߀ ԭ W ʽ Ҫ | B U e x Q y E E 1. 25.00 U ˮ Һ һ ̎ ^ x Q ֬ Һ M x Q K һ 250 Һ E 2. 50 ˮ x Q ^ x ȫ ͬ һ E 3. Һ ϡ 100.00 ˮ Һ Һ E 4. Һ ȡ 25.00 K ̪ ָ ʾ 0.0100 M c Һ 20.00 r _ K c } ÿ һ } 2 8 1. E 1 2 x x W ʽ 2. E 3 Ҫ Һ ϡ 100.00 ˮ Һ r Ҫ ʹ Q _ K c r Һ F ɫ 3. Ӌ Һ x 4. Ӌ U e