The document discusses various denim fabric finishing techniques, including both mechanical and chemical washes. Mechanical washes like stone wash and microsanding use abrasives like stones or sand to distress the fabric. Chemical washes include bleach wash, enzyme wash, and acid wash, which use chemicals to fade and distress the fabric. The techniques are described in detail, outlining the process involved and limitations of each method. Maintaining quality and controlling the finishing outcome are challenges discussed.
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1. National Institute of Fashion Technology
Hyderabad
Fabric and garment finishing : Basic washes in
denim fabric
Submitted by-
Noopur Shalini
AMIT 6th SEM
Group#1
2. THE HISTORY OF DENIMS
A popular conception of the etymology of the word denim is that it is a contraction or
derivative of the French term, serge de N樽mes. Denim was traditionally colored blue with
indigo dye to make blue "jeans," though "jean" then denoted a different, lighter cotton
textile; the contemporary use of jean comes from the French word for Genoa, Italy
(G棚nes), from which the first denim trousers were made.
A similarly woven traditional American cotton textile is the diagonal warp-striped hickory
cloth that was once associated with railroad mens overalls, in which blue or black
contrasting with undyed white threads form the woven pattern. Hickory cloth was
characterized as being as rugged as hickory woodnot to mention the fact that it was
deemed to be worn mainly by "hicks"although neither may be the origin of that term
[from a nickname for "Richard"]. Records of a group of New Yorkers headed for the
California gold fields in 1849 show that they took along four "hickory shirts" apiece.
Hickory cloth would later furnish the material for some "fatigue" pantaloons and shirts in
the American Civil War.
INTRODUCTION
Denim is a rugged cotton twill textile, in which
the weft passes under two (twi- "double") or
more warp fibers, producing the familiar
diagonal ribbing identifiable on the reverse of
the fabric.
DENIM WASHING
Denim washing is the aesthetic finish given to
the denim fabric to enhance the appeal and to
provide strength.
Dry denim, as opposed to washed denim, is a denim fabric that is not washed after being
dyed during its production.
Much of the appeal of dry denim lies in the fact that with time the fabric will fade in a
manner similar to that which artificially distressed denim attempts to replicate. With dry
denim, however, such fading is affected by the body of the person who wears the jeans
and the activities of their daily life. This creates what many feel to be a more natural,
unique look than pre-distressed denim.
3. DENIM WASHES ARE OF TWO TYPES:
1. Mechanical washes
- Stone wash
- Microsanding
2. Chemical washes
- Denim bleaching
- Enzyme wash
- Acid wash
CHEMICAL WASHES
Denim bleach
In this process a strong oxidative bleaching agent such as sodium hypochlorite or
KMnO4 is added during the washing with or without stone addition.
Discoloration produced is usually more apparent depending on strength of the bleach
liquor quantity, temperature and treatment time.
It is preferable to have strong bleach with short treatment time.
Care should be taken for the bleached goods so that they should be adequately
antichlored or after washed with peroxide to minimize yellowing. Materials should be
carefully sorted before processing for color uniformity.
4. Process cycle:
Limitations:
- Process is difficult to control i.e. difficult to reach the same level of bleaching in
repeated runs.
- When desired level of bleaching reached the time span available to stop the
bleaching is very narrow. Due to harshness of chemical, it may cause damage to
cellulose resulting in severe strength losses and/or breaks or pinholes at the seam,
pocket, etc.
- Harmful to human health and causes corrosion to stainless steel.
- Required antichlor treatment.
- Problem of yellowing is very frequent due to residual chlorine.
- Chlorinated organic substances occur as abundant products in bleaching, and pass
into the effluent where they cause severe environmental pollution.
Enzyme Wash
It is environmentally friendly wash. It involves the Application of organic enzymes that eat
away at the fabric, i.e. the cellulose.
When the desired color is achieved, the enzymes can be stopped by changing the
alkalinity of the bath or its temperature. Post treatment includes final rinsing and softening
cycle. The effects produced by the cellulose enzyme are---
1. Use of cellulase making the seams, hems, and pockets more noticeable
2. Salt pepper effect is color contrast effect.
3. Faded garment with acid cellulase enzyme provides less color contrast in proportion
to garment washed with neutral cellulase enzymes.
Garment load size of the machine is 35-40 jeans per machine and it cannot be
overloaded.
5. Acid wash
It is done by tumbling the garments with pumice stones presoaked in a solution of sodium
hypochlorite or potassium permanganate for localized bleaching resulting in a non
uniform sharp blue/white contrast.
In this wash the color contrast of the denim fabric can be enhanced by optical
brightening. The advantage of this process is that it saves water as addition of water is
not required.
Process cycle
6. Limitations of acid wash:
- Acid washed, indigo dyed denim has a tendency to yellow after wet processing.
- The major cause is residual manganese due to incomplete neutralization, washing or
rinsing.
Remedy:
- Manganese is effectively removed during laundering with addition of ethelene-
diamine-tetra-acetic acid as chelating agent.
- Acid washing jeans avoided some of problems of stone wash, but came with added
dangers, expenses, and pollution.
MECHANICAL WASHES
Stone wash:
In the process of stone washing, freshly dyed jeans are loaded into large washing
machines and tumbled with pumice stones to achieve a soft hand and desirable look.
Variations in composition, hardness, size shape and porosity make these stones
multifunctional. The process is quite expensive and requires high capital investment.
Pumice stones give the additional effect of a faded or worn look as it abrades the surface
of the jeans like sandpaper, removing some dye particles from the surfaces of the yarn.
Process cycle:
7. Selection of stone
Stone should be selected of the proper hardness, shape, and size for the particular end
product. It should be noted that large, hard stones last longer and may be suited for
heavy weight fabrics only.
Smaller, softer stones would be used for light weight fabrics and more delicate items.
Stone wt. /fabric wt. = 0.5 to 3 /1
It depends on the degree of abrasion needed to achieve the desired result. Stones can
be reused until they completely disintegrate or washed down the drain.
Problems caused by stones:
- Damage to wash machineries and garment due to stone to machine and machine to
stone abrasion
- Increase in labor to remove dust from finished garments.
- Water pollution during disposal of used liquor.
- Back staining and re deposition.
Back staining or Re-deposition:
The dye removed from denim material after the treatment with cellulose or by a
conventional washing process may cause "back staining or "redeposition. Re-coloration
of blue threads and blue coloration of white threads, resulting in less contrast between
blue and white threads.
Remedy of back staining ---
- Adding dispersion/suspension agent to wash cycle.
- Intermediate replacement of wash liquor.
- Using alkaline detergent like sodium per borate with optical brightener as after wash.
Limitations of stone washing:
- Quality of the abrasion process is difficult to control Outcome of a load of jeans is
never uniform, little percentage always getting ruined by too much abrasion.
- The process is non-selective.
- Metal buttons and rivets on the jeans in the washing machines get abraded.
- This reduces quality of the products and life of equipment, and increases production
costs.
- Stones may turn into powder during the process of making the garment grayish in
color and rough too
- Provides rougher feel than enzyme wash
- Stone may lead the harm to the machine parts
8. Microsanding
There are 3 ways for this technique:
Sandblasting
Machine sanding
Hand sanding or hand brushing
Used in various ways:
- Flat surfaces (tables, ironing boards)
- On the dummy (inflatable dummies, sometimes standing, sometimes flat,
sometimes 'seated')
- Various templates can be used to create a 3D effect.
SAND BLASTING
Sand blasting technique is based on blasting an abrasive material in granular, powdered
or other form through a nozzle at very high speed and pressure onto specific areas of the
garment surface to be treated to give the desired distressed/ abraded/used look.
- It is purely mechanical process, not using any chemicals.
- It is a water free process therefore no drying required.
- Variety of distressed or abraded looks possible.
- Any number of designs could be created by special techniques.
9. WHISKERING
- Also known as Cat's Whiskers
- Crease lines around the crotch.
- Industrially done with laser, sandblasting, machine sanding, hand sanding and
abrasive rods.
- Also used for 'knee whiskers' (whiskers on the sides of knees) and 'honeycombs'
(crease marks on the back of the knee)
Other chemical washes:
Rinse wash
Cellulase wash
Ozone fading
Snow wash
Salt water denim
Flat finish
Over dye
Sun washing
Super dark stone
RINSE WASH
- Chemically bleaching jeans so that the color fades away
- Breaks down the fibers of jeans and creates white streaks or spots on denim
- Gives a unique rugged look, also called snow wash
- Earlier involved the use of pumice stone
- Presently process involves spraying chemical and removing it immediately
- Come in colors like blue, black, green, brown, grey etc.
CELLULASE WASH
- This is done to achieve a wash down appearance without the use of stones or with
reduced quantities of stones.
- Cellulase enzymes are selective only to the cellulose and will not degrade starch.
- Under certain conditions, their ability to react with cellulose (cotton) will result in
surface fiber removal (weight loss).
- This will give the garments a washed appearance and soft hand.
Factors influencing cellulase performance
- pH
- Temperature
- Time
- Dose
- Mechanical action
OZONE FADING
- By using this technique, the garment can be bleached.
- Bleaching of denim garment is done in washing machine with ozone dissolved in
water.
- Denim garments can also be bleached or faded by using ozone gas in closed
chamber.
- In the presence of UV light, there is an interaction between the hydrocarbons, oxides
of nitrogen and oxygen that causes release of ozone.
- Indigo dyestuff tends to fade or turn yellow due to ozone reaction.
10. The advantages associated with this process are:
- Color removal is possible without losing strength.
- This method is very simple and environmentally friendly because after laundering,
ozonized water can easily be deozonized by UV radiation.
FLAT FINISH
It is a special process done to impart fabric with an even wash down effect and very
clean surface. Originally liquid ammonia was used, but now use mercerization plus
calendering processes to achieve the flat surface.
Mercerization swells up the cotton fibers and allows the calendering to press flat the
surface.
They consider this as an imitation process to the use of ammonia, which is toxic and not
allowed in commercial use in most countries
OVERDYE
- Dyeing over the fabric or jeans to add another tone of color
- Most often used is a 'yellowy' overdye to create a 'dirty' look
- Also can be applied with spray gun or paintbrush for local coloring
SUNWASHING
- A very light shade by bleaching and stoning
- Looks as if the sun faded the fabric
SUPER DARK STONE
- Commercial term for an extra dark indigo color
- Results from a double-dyeing technique
SNOW WASH DENIM
Denim treated with a variation of acid wash that imparts bright white highlights.
QUICK WASH DENIM
Aims at minimizing wash cycle time
Results in more economical washes and solving many other washing problems faced
by launderes during fashion wash cycles
The yarns are ring dyed using indigo giving 25 to 30% less fixed dye to obtain a
given shade
During wash cycle,indigo dye can be removed quickly,giving washed look
11. Advantages of quick wash denim
1. Streaks develop in garments after washing process
due to differences in dye concentration of denim fabrics
are avoided using a modified alkali-ph controlled system
giving uniformity of shade.
2. Amount of indigo dye required is less thus making it an
economical process
3. Time required for washing is 20-30% less than that
required for conventional denim.
4. Lesser enzymes and oxidising agent used
5. Environment friendly process
6. Back staining is minimised due to less concentration of
of indigo dye in the wash liqour.
Other Mechanical washing
Whiskering
Shot gun denim
Water jet fading
Super stone wash
Ice wash
Thermo denim
Laser technology finish
WATERJET FADING
- Hydrojet treatment is used for enhancing the surface finish, texture, durability of
denim garment.
- Hydroject treatment involves exposing one or both surfaces of the garment through
hydrojet nozzles.
- The degree of colour washout, clarity of patterns, and softness of the resulting fabric
are related to the type of dye in the fabric and the amount and manner of fluid impact
energy applied to the fabric.
- As this process is not involved with any chemical, it is pollution free.
12. LASER TECHNOLOGY
- It is a computer controlled process for denim fading.
- This technique enables patterns to be created such as lines and/or dots, images, text
or even pictures.
- It is water free fading of denim.
- Being an automatic system, chances of human error are slim.
- Also called spray painting in denims.
- This technique has relatively high cost.
SUPER STONEWASH
- Prolonged stonewashing, up to six hours or more.
ICE WASH
- Ice washing in denim fabrics is done to remove more than half the dye during
washing
THERMO-DENIM
Also called double denim. A lightweight fabric (either plain, fancy or colored) is glued to
the denim. The glue comes off after washing and the trousers look like they've been lined
VINTAGE
Applies heavy stonewashing or a cellulose enzyme wash, with or without bleach
Gives an old and worn look
CHEMICALS ON DENIMS
1. Bleach fast Indigo
Value addition to denim
Retains indigo on certain parts
Kind of resist effect
Chemical applied by brush, cured at 150尊C
Ex. Indigofix AXN
2. Anti-depositing agent
Prevents back staining of fabric by loose indigo during washing
Improves contrast in denim
Used in stone wash step
13. 3. Dye stuffs with softener
To carry dyeing and softening in one step
Soft and supple hand
Saves time, money and energy as added to final rinse
Gives used and worn out effect
4. Anti creasing agent
Provides fabric to fabric lubrication
Prevents formation of crack marks and streaks
Minimizes abrasion and gives strength
5. Wrinkle formation
Creating smooth and permanent wrinkle
Cross linking concept
Ex. DMDHEU
White pigment
Can be applied by brush, spray or screen
Then cured at 150尊C
Washed and treated with softener
6. White pigment
Can be applied by brush, spray or screen
Then cured at 150尊C
Washed and treated with softener
CONCLUSION
Denim is unique in its singular connection with one colour. The warp yarn is traditionally
dyed with the blue pigment obtained from indigo dye. Until the introduction of synthetic
dyes, at the end of the 19th century, indigo was the most significant natural dye known to
mankind, linked with practical fabrics and work clothing. The durability of indigo as a color
and it's darkness of tone made it a good choice, when frequent washing was not
possible.
The old mass market has segmented, fragmented, shattered into a multitude of mini,
micro and niche markets. The last generation has a vast quantity of brands to choose
from, a different perception of the cult value of owning small insider labels and a fanatical
loyalty only to what's hot on a daily basis.
Freed of all social and creative restrictions, denim is assuming any number of disguises
and contexts to be worn in and has broken through almost any limitation on price. It can
also be found in home collections, appearing in cushions, bed spreads and furniture-
coverings.
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