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linalool
Prepared by
Dr. N.GOPINATHAN
ASSISTANT PROFESSOR
DEPARTMENT OF PHARMACEUTICAL CHEMISTRY
FACULTY OF PHARMACY
SRI RAMACHANDRA UNIVERSITY
CHENNAI-116
TAMILNADU
INDIA
Properties
 3,7-Dimethylocta-1,6-dien-3-ol
 Colourless Liquid
 Stable
 Origin: Rose, rosewood, Lavender, minor
constituent of others.
 Optially active acyclic oxygenated
monoterpenoid
 Boiling point 198-199C
 Molecular formulae: C10H18O
Structure
Presence of double bond
 On bromination yield tetra bromine indicates
presence of two double bond.
OH group [tertiary alcohol]
 It reacts with PCl5 hence OH is present.
 On catalytic dehydrogenation yield oleffin
reveals that presence of tertiary OH group.
Linalool is isomeric with geraniol
steam at 200C
Synthesis

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