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David Peterson, Ph.D.
The MoDa Group and Director, Samara Ancient Metals Project
Eurasia Before the Golden Age
Metal Technology and Metal Networks, ca. 3000-1500 BC
	
AIA, Minnesota Society and Macalester College
September 24, 2015
AIA Presentation 2015
structure									+						composi-on
Source: http://thehistoryofeuropepodcast.blogspot.com/2012/06/incredible-khvalynsk-culture-of-lower.html
Khvalynsk
Khvalynsk	Cemetery	Eneolithic,	5000-4500	BCE
circumpon-c	metallurgical	province	
P r o v i n c e
Metallurgical
Focus
Metalworking
Focus
Metalworking
Focus
Metallurgical
Focus
Metallurgical
Focus
Eurasian Steppe ZoneCaucasus Zone
Metallurgical
Focus
Metalworking
Focus
Metalworking
Focus
Metallurgical
Focus
Metallurgical
Focus
Province
ca.	3500-2000	BC	(E.	N.	Chernykh	1992)	
Caspian	Sea	
.	Samara
arc	OES	studies	of	copper	and	bronze	from	the	
Eurasian	steppes		
E.	N.	Chernykh	(1970,	1992);	Chernykh	and	Kuzminykh	(1987)
arc	OES	studies	of	copper	and	bronze	from	the	
Eurasian	steppes		
E.	N.	Chernykh	(1970,	1992);	Chernykh	and	Kuzminykh	(1987)	
cri-que	of	method		
M.	Pollard,	C.	BaS,	B.	Stearn,	and	S.	Young,	Analy/cal	Chemistry	in	
Archaeology
arc	OES	studies	of	copper	and	bronze	from	the	
Eurasian	steppes		
E.	N.	Chernykh	(1970,	1992);	Chernykh	and	Kuzminykh	(1987)	
cri-que	of	method		
M.	Pollard,	C.	BaS,	B.	Stearn,	and	S.	Young,	Analy/cal	Chemistry	in	
Archaeology	
lead	isotopes		
T.	St?llner,	et	al.	Anatolian	Metal	V	(2011)
arc	OES	studies	of	copper	and	bronze	from	the	
Eurasian	steppes		
E.	N.	Chernykh	(1970,	1992);	Chernykh	and	Kuzminykh	(1987)	
cri-que	of	method		
M.	Pollard,	C.	BaS,	B.	Stearn,	and	S.	Young,	Analy/cal	Chemistry	in	
Archaeology	
lead	isotopes		
T.	St?llner,	et	al.	Anatolian	Metal	V	(2011)	
used	in	recent	major	syntheses	
2	published	by	CUP	(both	in	2007),	1	by	U	of	CA	(2008)
AIA Presentation 2015
AIA Presentation 2015
Kamyshla	sites			Samara,	Russia,	15th	century	BCE
Samara	Valley	Project	
The	Samara	Valley	Project:		A	Bronze	Age	Landscape	in	the	Russian	
Steppes,	edited	by	D.	Anthony,	D.	Brown,	A.	Khokhlov,	P.	Kuznetsov,	
and	O.	Mochalov.	Los	Angeles:	Cotsen	Ins-tute	of	Archaeology,	
UCLA.
¡®Moonscape¡¯	of	ancient	mine	pits																									Excavated	copper	mine	shad	
Kargaly	complex			Orenburg,	Russia
Dri&	mine	in	Kargaly			ca.	1800-1400	BCE	
																												
Drid	mine	at	Kargaly			ca.	1800-1400	BC
samples	
removed	by	hand	with	jeweler¡¯s	
saw,	mounted	in	bakelite,	ground	
and	polished		
?? samples	are	preserved	
?? analysis	is	repeatable	
?? the	same	samples	are	used	for	
electron	microprobe,	
metallography,	SEM-EDS,	and	
nanoSIMS	
16	elements	were	analyzed	by	electron	microprobe	wavelength-	
dispersive	spectrometry	(WDS),	200	ppm	resolu-on:	
?? iron	
?? cobalt	
?? nickel	
?? copper	
?? zinc	
?? arsenic	
?? an-mony	
?? -n	
?? sulfur	
?? aluminum	
?? silicon	
?? manganese	
?? silver	
?? bismuth	
?? lead	
?? gold
AIA Presentation 2015
AIA Presentation 2015
AIA Presentation 2015
cm
metalworking
casting
annealing
forging
ingot
object
process
product /
by-product
slag
mining
ore processing
sorting
crushing
roasting
smelting
ore
ore
alloying
recycling
splash
scrap
co-smelting
metallurgical	
cycle:	
processes	
and	products
metalworking
casting
annealing
forging
ingot
object
process
product /
by-product
slag
mining
ore processing
sorting
crushing
roasting
smelting
ore
ore
alloying
recycling
splash
scrap
co-smelting
metallurgical	
cycle:	
processes	
and	products	
recycling
Utevka	VI	kurgan	cemetery			ca.	2000	BC	
kurgan	6,	grave	6	
Kurgan	6
arsenic	values			electron	microprobe	results												
metalwork	from	burial	assemblages	(Samara,	Russia,	3rd	and	2nd	
millennium	BCE)
iron	and	
an-mony	
electron	microprobe	
results	
	
metalwork	from	burials	in	
the	Utevka	VI	and	
Potapovka	I	kurgan	
cemeteries	(Samara,	
Russia)
Potapovka	I	
Utevka	VI	
Samara	R.		
Volga	R.
work	paSern	2	
worked	+	annealed	+	light-moderate	
cold	work	(hammering)	
work	paSern	3	
worked	+	annealed	+	heavy	cold	work	
	
chisel,	Utevka	VI,	kurgan	6,	grave	6	 knife,	Utevka	VI,	kurgan	6,	grave	6	
	
	
	
chisel
0
5
10
15
20
25
Potapovka I Utevka VI
WP 2
WP 3
21	
12	
16	
9	
comparison	of	work	paSerns			copper	and	
bronze	metalwork	from	Potapovka	I	and	Utevka	VI
AIA Presentation 2015
Nizhnyaya	Orlyanka	
Spiridonovka	II	 Samara	R.		
Volga	R.		
Potapovka	I	
Utevka	VI
electrum	foil-covered	
pendants			from	Early	
Srubnaya-Pokrovka	kurgan	
burials																									
Middle	Volga,	ca.	1850-1700	BCE	
Spiridonovka	II	
Nizhnyaya		
Orlyanka
electron	microprobe	results*	
foil-covered	pendants,	Nizhnyaya	Orlyanka	and	Spiridonovka	II	
gold	content	is	over	20x	greater	near	the	surface	
*Dr.	Peter	Northover	and	Dr.	Chris	Salter	
Department	of	Materials,	Oxford	University
the	SEM	image	shows	that	the	gold-
silver	crystal	structure	goes	to	surface	
gold	enrichment	was	not	caused	
by	adding	a	new	layer	of	gold	to	
outside	of	the	foil	
gold	enrichment	was	caused	by	
removing	silver	from	the	surface	
of	the	foil	to	a	depth	of	5¦Ìm		
Spiridonovka	II	pendant		DP94				
backscaSer	SEM	image
nanoSIMS	
map	of	foil*	
Spiridonovka	II	
pendant	
	
											
										gold	
										silver	
										copper	
*Dr.	Zihua	Zhu,	EMSL	(DoE),	Richland,	WA	
ca.	7	¦Ìm		
there	is	no	
di?usion	
bond	
there	is	overlap	
between	gold-	
and	silver-
enriched	zones	
	
this	supports	the	
hypothesis	of	
deple-on	gilding
Gold-covered	ornaments	from	other	
LBA		kurgan	graves	in	the	Middle	
Volga	(untested)	
ancient	deple-on	
gilding	
	
Andes									H.	Lechtman	(1973)	The	
Gilding	of	Metals	in	Pre-Columbian	
Peru.	Applica/on	of	Science	in	
Examina/on	of	Works	of	Art	(W.	
Young,	ed.),	pp.	38-52		
Mesopotamia						S.	La	Niece	(1995)	
Deple-on	Gilding	from	Third	
Millennium	BC	Ur.	Iraq	57:	41-47	
		A.	Hauptmann	et	al.	(2010)	Gold	
from	the	Royal	Tombs	of	Ur,	2600	
BC:	Gilding	Techniques,	Tumbaga	
Alloys,	Deple-on	Gilding	¨C	on	the	
Use	of	a	Hand-Held	XRF	
Spectrometer.	Metalla	SonderheH	
3:	57-59
Badakhshan
Royal Cemetery of Ur
ca. 2600 BC
Samara
Samara, ca. 1800 BC
was	the	deple-on	gilding	technique	
transferred	along	the	same	routes	as	lapis?
¡®pearls¡¯
DP88
DP89
¡®pearls¡¯
DP88
DP89
Kutuluk	I	
EBA	(Yamnaya),		
ca.	1950	BCE
Inventory from Sintashta
grave 30
Reconstruction of the Arkaim Settlement
Sintashta	paSern	MBA	II,	ca.	2100-1800	BCE
Funding	
??Wenner-Gren	Founda-on	
??Na-onal	Science	Founda-on	
??O?ce	of	Research,	Faculty	Research																																																																	
CommiSee,	Humani-es	and	Social	Sciences																																																								
Research	CommiSee,	and	College	of	Art	&	LeSers,	Idaho	State	University	
Research	Centers	and	Ins2tutes	
??Environmental	Molecular	Sciences	Laboratory	(Richland,	Washington)	
??Ins-tute	for	the	History	and	Archaeology	of	the	Volga	(Samara,	Russia)		
??Center	for	Archaeology,	Materials	and	Applied	Spectroscopy,	Idaho	State	
University	
Students	and	Colleagues	from	
??University	of	Chicago	
??Hartwick	College	
te ?University¡¯s ?
ch ?pixel ?in ?the ?
t ?pa ern. ?Sig-?©\
 ?in ?Fig. ?4. ?The ?
of ?silver ?in ?the ?
. ?4, ?right) ?also ?
. ?Gold ?enrich-?©\
d ?on ?to ?it ?as ?is ?
the ?par cipa on ?Ur ?and ?the ?Bronze ?Age ?steppes ?in ?networks ?for ?the ?distribu on ?of ?lapis ?lazuli ?[3] ?suggest ?
that ?knowledge ?of ?this ?technique ?may ?have ?traveled ?the ?prehistoric ?Silk ?Road ?with ?early ?luxuries. ?Deple on ?
gilding ?implies ?the ?associa on ?of ?gold ?with ?beauty ?and ?greater ?value ?than ?the ?other ?metals ?that ?were ?re-?©\
moved ?and ?hidden ?below ?the ?surface ?of ?the ?object. ?It ?was ?2000 ?years ?before ?technology ?for ?"gilding ?the ?
lily"¡ªgiving ?the ?surface ?of ?a ?rare ?and ?valuable ?material, ?electrum, ?a ?more ?golden ?color¡ªwas ?used ?to ?re?ne ?
gold. ?If ?gold ?was ?so ?valuable, ?why ?did ?it ?take ?so ?long ?for ?this ?shi  ?to ?occur? ?The ?uses ?of ?gold ?went ?beyond ?
the ?desire ?to ?acquire ?more ?of ?the ?precious ?material. ?Gold ?re?nement ?produces ?a ?color ?change ?and ?a ?loss ?of ?
mass ?from ?the ?removal ?of ?silver. ?The ?manipula on ?of ?electrum ?for ?bodily ?adornment ?in ?the ?Spiridonovka ?II ?
pendant ?would ?have ?been ?made ?more ?di?cult ?by ?puri?ca on; ?removal ?of ?all ?of ?the ?silver ?would ?have ?result-?©\
ed ?in ?loss ?of ?95% ?of ?a ?scarce ?material ?that ?was ?already ?worked ?into ?a ?very ?thin ?foil. ?The ?mo va on ?for ?re-?©\
?nement ?was ?not ?adornment, ?but ?control ?of ?the ?composi on ?of ?the ?material ?itself. ?Analysis ?of ?the ?earliest ?
Lydian ?coins ?shows ?that ?slightly ?before ?re?nement ?was ?introduced, ?electrum ?was ?struck ?into ?coins ?of ?regular ?
weight ?and ?form ?as ?assurance ?of ?redeemability ?by ?the ?Lydian ?state ?[12]. ?Faith ?in ?this ?new ?medium ?for ?mar-?©\
ket ?interac ons, ?tax, ?and ?tribute ?was ?tested ?in ?its ?early ?years, ?crea ng ?a ?greater ?need ?to ?control ?the ?make-
up ?of ?o?cial ?currency ?and ?to ?sustain ?permanent ?shops ?[13]. ?Size ?and ?weight ?were ?not ?enough. ?The ?ideal ?be-?©\
came ?a ?pure ?material ?that ?remained ?as ?a ?commodity ?itself ?when ?faith ?in ?coin ?and ?state ?was ?challenged.
ONGOING ?RESEARCH
Iden ?ca on ?of ?deple on ?gilding ?during ?the ?Bronze ?Age ?in ?the ?Volga-Ural ?steppes ?has ?led ?to ?the ?ques on ?of ?
how ?widespread ?these ?techniques ?were ?in ?the ?prehistory ?of ?the ?surrounding ?region. ?Peterson ?will ?travel ?to ?
Kazakhstan ?to ?collect ?samples ?from ?Bronze ?and ?Iron ?Age ?contexts ?in ?May ?2013 ?for ?new ?analyses. ? ? ?
ck ?and ?white ?
vka ?II ?pendant ?
foil
, ? ? ? ? ?
g) ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ? ?
ACKNOWLEDGMENTS
A ?por on ?of ?the ?research ?was ?performed ?using ?EMSL, ?a ?na onal ?scien ?c ?user ?facility ?sponsored ?by ?the ?Department ?of ?Energy¡¯s ?o?ce ?of ?Biological ?and ?Environmental ?Research ?and ?locat-?©\
ed ?at ?Paci?c ?Northwest ?Na onal ?Laboratory. ?Acquisi on ?of ?the ?samples ?was ?facilitated ?by ?Peterson¡¯s ?par cipa on ?in ?the ?Samara ?Valley ?Project ?(Dr. ?David ?Anthony, ?PI), ?and ?collec on ?of ?
new ?samples ?in ?Kazakhstan ?will ?be ?done ?in ?coordina on ?with ?the ?Tuzusai ?project ?directed ?by ?Dr. ?Claudia ?Chang ?(Sweet ?Briar ?College. ? ?EPMA ?was ?performed ?at ?Oxford ?Materials ?by ?Dr. ?Pe-?©\
ter ?Northover ?and ?Dr. ?Chris ?Salter, ?with ?assistance ?from ?Dr. ?Blanca ?Maldonado. ?Funding ?was ?provided ?by ?the ?Wenner-Gren ?Founda on ?for ?Anthropological ?Research ?through ?Individual ?Re-?©\
search ?Grant ?6760. ?This ?material ?is ?based ?upon ?work ?supported ?by ?the ?Na onal ?Science ?Founda on ?under ?Grant ?No. ?0431940. ?Any ?opinions, ??ndings, ?and ?conclusions ?or ?recommenda-?©\
ons ?expressed ?in ?this ?material ?are ?those ?of ?the ?authors ?and ?do ?not ?necessarily ?re?ect ?the ?views ?of ?the ?Na onal ?Science ?Founda on. ?This ?work ?was ?also ?partly ?supported ?by ?the ?Na onal ?
Science ?Founda on ?under ?Grant ?No. ?BSC ?0821783, ?PHY ?0852060, ?and ?the ?O?ce ?of ?Research ?and ?College ?of ?Arts ?and ?Le ers, ?Idaho ?State ?University. ?
 ?III: ?67-77. ?
the ?Altai ?Moun-?©\
i ?Kul¡¯tury ?v ?Samar-?©\
-60.
93-97. ?
D. ?disserta on, ?Uni-?©\
Boston, ?pp. ?38-52.
??Samara	State	Pedagogical	
University	
??	Oxford	Materials	
??	Idaho	State	University

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