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Amines & Diazonium Salts

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Shivani Jadhav

An In-Depth Concept of Amines & Diazonium Salts For IIT JEE (CHEMISTRY) Exams. Join Studyduniya.com for More. https://bit.ly/2q8Q8YD

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STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 STRUCTURE-BASICITY RELATIONSHIP OF AMINES Alkanamines versus ammonia
STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 STRUCTURE-BASICITY RELATIONSHIP OF AMINES Arylamines versus ammonia pKb value of aniline is quite high because of resonating structure of aniline In case of substituted aniline, it is observed that electron releasing groups like ¨COCH3, ¨C CH3 increase?basic strength whereas electron withdrawing groups like ¨CNO2, ¨C SO3H,?¨CCOOH, ¨CX decreases it.
STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 PREPARATION OF AMINES?FROM NITRO COMPOUNDS From nitro compounds
STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 REACTION WITH NITROUS ACID
STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 COUPLING REACTIONS
STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 REACTIONS OF DIAZONIUM SALTS Sandmeyer reaction.
STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 REACTIONS OF DIAZONIUM SALTS Gatterman reaction. Replacement by H
STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 REACTIONS OF DIAZONIUM SALTS Replacement by hydroxyl group Replacement by ¨CNO2 group
STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 CARBYLAMINE REACTION Aliphatic and aromatic primary amines on heating with chloroform & ethanolic KOH form isocyanides or carbylamines?which are foul smelling substances.

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Amines & Diazonium Salts

  • 1. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 STRUCTURE-BASICITY RELATIONSHIP OF AMINES Alkanamines versus ammonia
  • 2. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 STRUCTURE-BASICITY RELATIONSHIP OF AMINES Arylamines versus ammonia pKb value of aniline is quite high because of resonating structure of aniline In case of substituted aniline, it is observed that electron releasing groups like ¨COCH3, ¨C CH3 increase?basic strength whereas electron withdrawing groups like ¨CNO2, ¨C SO3H,?¨CCOOH, ¨CX decreases it.
  • 3. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 PREPARATION OF AMINES?FROM NITRO COMPOUNDS From nitro compounds
  • 4. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 REACTION WITH NITROUS ACID
  • 5. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 COUPLING REACTIONS
  • 6. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 REACTIONS OF DIAZONIUM SALTS Sandmeyer reaction.
  • 7. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 REACTIONS OF DIAZONIUM SALTS Gatterman reaction. Replacement by H
  • 8. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 REACTIONS OF DIAZONIUM SALTS Replacement by hydroxyl group Replacement by ¨CNO2 group
  • 9. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - O R G A N I C - ? A M I N E S IIT JEE @studyduniya +91 7744994714 CARBYLAMINE REACTION Aliphatic and aromatic primary amines on heating with chloroform & ethanolic KOH form isocyanides or carbylamines?which are foul smelling substances.