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Ap chemistry notes chapter 1

Sherri Mazzone
Sherri Mazzone

Chemistry is the study of matter and its composition and changes. Matter is composed of elements and compounds. The main areas of study in chemistry include organic chemistry, inorganic chemistry, analytical chemistry, physical chemistry, biochemistry. [Chemistry notes provide an overview of key areas of chemistry including matter, elements, compounds, mixtures, states of matter, and areas of study in chemistry such as organic, inorganic, analytical, physical, and biochemistry.]

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1 AP Chemistry Notes Chapter 1 Chemistry Notes Chapter 1, 2, 3, & 4 Chemistry is the study of the composition of matter- the stuff things are made of- and the changes matter undergoes. Matter is ultimately composed of chemical elements (atoms) and their compounds. Most matter can exist in one or more states: solid, liquid, and gas. Areas of Study in Chemistry: Organic Chemistry Study of substances containing carbon. Inorganic Chemistry* Study of substances NOT containing carbon. Analytical Chemistry* Study of the composition of substances. Physical Chemistry* Study of the theories and experiments that describe the behavior of substances. Biochemistry Study of the chemistry of living things. I. Matter and Measurement A. Matter: Elements, Compounds, or Mixtures (20+ million) 117 elements Elements united into fixed ratios Cannot be subdivided by chemical or Physical processes Table salt (NaCl) Water (H2O) Sodium (Na) Silicon (Si) Sand (SiO2) Sugar (C12H22O11) Chlorine (Cl) Oxygen (O2) Fools Gold (FeS2) Hydrogen (H2) Iron (Fe) *When elements become part of a compound, their original properties such as color, hardness, melting point are replaced by the characteristic properties of the new compound. Consider table salt (sodium chloride)
2 B. Elements and Atoms 117 elements are known of these only 90 are found in nature; the remainder being created by scientists in a laboratory using techniques of modern physics. Many elements names often have names and symbols relating to their Latin or Greek origin Element Symbol Latin or Greek Iron Fe Ferrum Lead Pb Plumbum Tin Sn Stannum Mercury Hg Mercurum (Hydragyrum Greek) CopperCu Cuprum Silver Ag Argentum Potassium K Kalium Sodium Na Natrium Note: Elements can have a one or two letter symbol. Only the first letter of an elements symbol is capitalized. Elements are listed in the Periodic Table. An atom is the smallest particle of an element that retains the properties (color, hardness, melting point) of that element. Element: A substance that CANNOT be changed into a simpler substance (see periodic table) Compound: A substance that CAN be changed into a simpler substance Mixture: A physical blend of two or more substances (elements or compounds) that are not chemically combined ReviewPractice Identify the following as an element, mixture, compound then identify each as a homogeneous or heterogeneous. Element, Mixture, Compound If Mixture Homogeneous or Heterogeneous 1. Oxygen _____________________ ________________ 2. Air _____________________ ________________ 3. blood _____________________ ________________ 4. brass ( a blend of copper and zinc) _____________________ ________________ 5. Food coloring _____________________ ________________ 6. Soda _____________________ ________________ 7. Silver _____________________ ________________ 8. Salt Water _____________________ ________________ 9. Oil and Water _____________________ ________________ 10. Candle Wax (C20H42) _____________________ ________________ 11. Ice _____________________ ________________ 12. Carbon monoxide (CO) _____________________ ________________ 13. Sugar (C12H22O11) _____________________ ________________
3 II. The Measures of Science -Observations of Matter Doing chemistry requires observing elements and compounds undergoing chemical and physical changes. A. Qualitative Measurements Observations that involve no measurements or units. B. Quantitative Measurements Observations that involve measurements or numbers w/ units. Classify each observation as qualitative or quantitative: Blue-Grey color _____________________ Melts at 1410o C _____________________ Brittle _____________________ 1. SI System- International System of Units The scientific community has chosen a modified version of the metric system as the standard system Measured Property Name of Unit Abbreviation Mass kilogram kg Length meter m Time second s Temperature kelvin K Amount of substance mole mol Electric Current ampere A Prefixes are used to change SI units by powers of 10. To use the SI units effectively, you should know the meanings of the prefixes. Prefix Symbol Multiplier Exponential Example Femto f 1/1 000 000 000 000 000 1 x 10-15 femtosecond (fs) Pico p 1/1 000 000 000 000 1 x 10-12 picometer (pm) Nano n 1/1 000 000 000 1 x 10-9 nanometer (nm) Micro 1/1 000 000 1 x 10-6 microgram (g) Milli m 1/1 000 1 x 10-3 milligram (mg) Centi c 1/100 1 x 10-2 centimeter (cm) Deci d 1/10 1 x 10-1 deciliter (dL) Kilo k 1000 1 x 103 kilometer (km) Mega M 1 000 000 1 x 106 megagram (Mg) Giga G 1 000 000 000 1 x 109 gigameter (Gm) Tera T 1 000 000 000 000 1 x 1012 terameter (Tm) When choosing the best unit and prefix for a measurement you need to choose the correct unit and then the prefix that will give you a measurement that is not extremely large or small. Radius of an atom 1 x 10-12 m so 1 pm Diameter of a virus 1 x 10-6 m so 1 m Circumference of Earth 1 x 107 m so 10 Mm
4 2. Significant Digits in Measurements The valid digits (all certain plus one uncertain/estimated) in a measurement are called significant digits. Rules for determining the number of significant figures in a measurement: 1. Non zero numbers are always significant. 2.84 km ______ sig figs 1.8 x 106 mL ______ sig figs 2. All final zeros after a decimal point are significant. 0.760 s ______ sig figs 75.00 kg ______ sig figs 3. Leading zeros used solely as placeholders are not significant. 0.00345 ______ sig figs 0.023 ______ sig figs 4. Zeros between two other significant digits are always significant. 2804 m ______ sig figs 0.003086 ______ sig figs 5. Zeros located at the end of a number and to the left of a decimal point are significant. 20. 0 C ______ sig figs 3000. K ______ sig figs 20 o C ______ sig figs 3000 K ______ sig figs
5 Practice: Complete the table below Measurement Number of Sig. Figs Measurement Number of Sig. Figs 2804 m _______________ 30.9 V _______________ 2.84 km _______________ 0.001 010 0 s _______________ 0.0029 m _______________ 0.106 W _______________ 4.6 x 105 m _______________ 0.160 A _______________ 4.06 x 10-5 _______________ 5.20 N _______________ 4.060 x 10-5 _______________ 30.9 V _______________ 250 600 m _______________ 5.2234 x 1012 mol _______________ 250 600. m _______________ 4.2 x 106 g _______________ 3. Scientific (Exponential) Notation Many measurements are very large or very small numbers. Written in this form, the values of the quantities take up to much space, are difficult to read, and are awkward to use in calculations. To work with such numbers, write them in scientific (exponential) notation by expressing decimal places as powers of ten. _________ X 10 ___ If this value is negative your number in long form will be <1 Number between 1 and 9.9999 If this value is positive your number in long form will be >1 The average distance from the sun to Mars is 227 800 000 000 m. To write this number is correct scientific notation the decimal is moved to the left 11 places. In scientific notation this distance would be 2.278 x 1011 m. The mass of a single electron is about 0.000 000 000 000 000 000 000 000 000 000 911 kg. To write this number is correct scientific notation the decimal is moved to the right 31 places. In scientific notation this mass would be 9.11 x 10-31 m. Review/Practice: 1. Correct the measurements so that they are in PROPER scientific notation THEN use a prefix rather than scientific notation: Incorrect Scientific Notation Correct Scientific Notation Using Prefix 128. x 103 m _____________________ _________________ 0.009320 x 105 K _____________________ _________________ 2345 x 10-2 g _____________________ _________________ 0.562 x 10-5 s _____________________ _________________
6 2. Complete the Table Long Form Number of Sig figs Scientific Notation 0.0001267 m 4 1.267 x 10-4 m 10022.5 kg ____ __________________ 0.034500 s ____ __________________ ____________ A ____ 2.43 x 105 A ____________ mol ____ 1.23450 x 10-3 mol 200 kg ____ __________________ 200. kg ____ __________________ 200.0 kg ____ __________________ _____________ s ____ 1,243 x 103 s _____________ A ____ 5.6 x 104 A 3. Using the five rules of significant figures, use of scientific notation, and use of prefixes complete the following table: Long Form #Sig Figures Scientific Notation Unit w/ Prefix a) 0.004080 g ________________ _______________ ________________ b) 0.0180 m ________________ _______________ ________________ c) 3450000 s ________________ _______________ ________________ d) 0.0000012 m ________________ _______________ ________________ e) ____________ ________________ _______________ 3.3 dm f) ____________ ________________ 1. 67 x 102 g ________________ g) ____________ ________________ 2.33 x 10-3 s ________________ h) ____________ ________________ ________________ 2.35 袖s 4. Place the following measurements in order from smallest to largest 1.0 km, 1.0 Tm, 1.0 cm, 1.0 m, 1.0 nm, 1.0 袖m _______________________________________________ 4. Significant Figures When Measuring with Laboratory Equipment When recording measurements taken during an experiment, you must always record them with the correct number of significant figures (all certain plus one uncertain/estimated digit) Measuring Volume: Using the graduated cylinders below report the correct volume of liquid
7 Measuring Length: Using the rulers below report the length of your pencil _________cm _________ cm _________ cm Measuring Temperature: Using the thermometers below report the correct temperature _______o C _______o C _________o C Measuring Mass: Electronic balances always report all significant digits. This means that the last digit reported by an electronic balance is uncertain/estimated but it is still significant 208.569 g
8 Review Practice: Read the following instruments. Express your measurement using the correct number of significant figures _________cm _________cm ______mL _______mL ________o C _________o C 5. Arithmetic with Significant Figures As mentioned previously, when recording the results of an experiment, you must always record them with the correct number of significant figures. Frequently you will need to add, subtract, multiply, or divide the measurements. When you perform these arithmetic operations, it is important to remember that the result can never be more precise than the least precise measurement. YOUR CALCULATOR DOES NOT DO THIS FOR YOU!!! Rule #1: Addition and Subtraction: To add or subtract measurements, first perform the operation, then round off the answer to correspond with the least precise measurement 24.686 m 2.456 s 2.341 m - 0.03 s + 3.2 m ________ _________ Rule #2: Multiplication and Division A different rule governs multiplication and division. After performing a calculation, note the measurement with the least number of significant figures and round your final answer to this number of significant figures. 3.22 cm x 2.1 cm = 36.5 m / 3.414 s = Review/Practice 1. Round each measurement to three significant figures. a) 98.473 L ___________ b) 12.17 o C _________ c) 57.048 m ____________ d) 4323.34 s ___________ e) 4327 s _________ f) 0.0007635211 L ____________ (Use Sci. Notation)
9 2. Complete the table Report answers to the correct number of significant figures and include correct units with each answer): Long Form Scientific Notation 1. 6.201 cm + 7.4 cm + 0.68 cm + 12. cm = ___________ ____________ 2. 1.6 km + 0.0162 km + 1.2 km = ___________ ____________ 3. 10.8 g - 8.264 g = ___________ ____________ 4. 475 m - 0.4168 m = ___________ ____________ 5. 131 cm x 2.3 cm = ___________ ____________ 6. 5.761 N x 6.20 m = ___________ ____________ 7. 13.78 g / 11 mL = ___________ ____________ 8. 3.1416 cm / 12.4 s = ___________ ____________ 9. (1.68) ( 23.56 - 2.3) = 1.248 x 103 ___________ ____________ 10. (6.2 x 1018 m ) ( 4.7 x 10-10 m) = ___________ ____________ 11. (6.5 x 105 kg) / (3.4 x 103 m3 ) = ___________ ____________ 3. The following operations were completed on a calculator. The answer the calculator provided is provided for you. Please round the provided answer to the correct number of significant figures with the correct units. Rounded to Calculator Answer Correct num. of SFs a) 3.46 cm + 104.5 cm + 0.346 cm = _________________ _________________ b) 2.384 g - 1.5 g = _________________ _________________ c) 9.40 mm x 2.6 mm = _________________ _________________ d) 1.50 g / 2 cm3 = _________________ _________________ e) 21.50 g/(4.06cm x 1.8 cm x 0.905cm) = _________________ _________________ 6. Unit Conversions (dimensional analysis) Many time the measurements you collect in laboratory are not the units you desire. This will require you to convert a measurement to another unit using dimensional analysis. Measurement in original unit x [ new unit] = Measurement in new units original unit Conversion factor (s) a. Converting Units Within the Metric System Example 1: Convert 456 to kg 456 g 1 kg = 1000g
10 Example 2: Convert 2.1 m to cm 2.1 m ___ cm = m Example 3: Convert 76.2 pm to mm 76.2 pm ____________m _____________mm = pm m b. Converting Ratios Example 1: Convert 65 mi /hr to m/s 65 mi _____km _________m _________hr ________min = m/s hr mi km min s Example 2: Convert 42.3 g/mL to mg/L 45.3 g _____mg _________mL = mg/L mL g L c. Converting Volumes and Areas Example 1: Convert 6.2 m2 to mm2 Example 2: Convert 6.34 x 10-8 cm3 to m3 C. Accuracy and Precision of Laboratory Measurements In laboratory we will often do several quantitative measurements of on a sample of matter (i.e. density, melting point, boiling point .)
11 The PRECISION of a set of measurements is how well several measurements of the same quantity agree. The precision of a set of measurements is often expressed by the average deviation and/or percent deviation. That is we calculate the difference between each experimental result and the average result. The differences, each expressed as a positive quantity, are averaged, and the experiments results are reported as the average value () the average deviation. % deviation = avg deviation x 100% avg. of experimentally determined values If percent deviation is less than 20% you are accurate ACCURACY is the agreement of a measurement with the accepted value of a quantity. Measurements can be precise but not accurate. The accuracy of a set of measurements is often expressed by the percent error. If percent error is less than 20% you are accurate % error = avg of experimentally determined values - accepted value x 100% accepted value If percent error is less than 20% you are accurate Example: Pam makes four measurements of the diameter of a coin using a micrometer. Max measures the same coin using a simple plastic ruler. The true measurement is 27.00 mm. They report the following results: Pam Deviation Max Deviation 28.246 mm 28.9 mm 28.244 23.0 28.246 30.8 28.248 21.1 Avg:____________ Avg:___________ a) Calculate each students average deviation? percent deviation? Which students results were most precise?
12 b) Calculate each students percent error? Which student was most accurate? Practice: Indicate whether each statement below refers to precision (p) or accuracy (a) _____a) This term refers to how close your measurement (or average measurement) is to the true value. ______b) This term refers to how close your measurements are to one another. _____c) The results of your percentage error calculation gives you an idea of the _________ of your measurement(s). _____d) The results of your average deviation calculation gives you an idea of the _________ of your measurement(s). 2. a) Calculate the mean and average deviation for the series of density measurements on samples of zinc below. Please make proper use of significant figures in your calculations Trial # Density (g/cm3 ) Abs Deviation From The Mean 1 7.76 __________ 2 7.82 __________ 3 7.65 __________ Average _____________ 賊 __________ b) The true value for the density of zinc is 7.30 g/cm3 . What was the percent error of the measurements above? III. Properties of Matter A. Chemical Properties The ability of a substance to undergo chemical reactions to form new substances. B. Physical Properties A quality of a substance that can be observed or measured without changing the substances chemical composition. Just as you identify your friends by their physical properties; height, weight, eye color, hair color Chemical substances are also identified by their physical properties. Different chemical substances clearly differ in properties that allow us to classify and identify substances of the world. These physical properties may depend on the amount of substance present (extensive) or may not depend on the amount of substance present (intensive). Intensive properties are useful in identifying unknown substances. Practice:
13 Three primary sources can be used to identify physical and chemical properties of known elements and compounds are Handbook of Chemistry and Physics The Merck Index Material Safety Data Sheet (MSDS) Review/Practice 1) (Using the table on page 12) List (a) physical property(ies) that can be used to distinguish Ethanol and Water. 2) (Using the table on page 12) List (a) a physical property(ies) that can be used to distinguish sodium chloride and sulfur. Common physical properties of matter: Property Intensive or Extensive Physical Property Mass ______________________________ Volume ______________________________ Color ______________________________ State of Matter ______________________________ *Melting Point ______________________________ *Boiling Point ______________________________ *Density ______________________________ Solubility ______________________________ Electrical Conductivity ______________________________ Malleability ______________________________ Ductility ______________________________ Viscosity ______________________________ * These intensive properties can be used to identify pure substances like elements and compounds because every element and compound has a unique values.
14 Important Physical Property -- Density Density is the ratio of the mass of an object to its volume. This property is useful in identifying an unknown substance. The density of a substance relates the mass and volume of a substance. If you know any two of the three quantities you can solve for the third. Mass D = _______ Volume Sample Calculations: The Handbook of Chemistry and Physics lists the density of mercury as 13.534 g/cm3 (at 20 o C). a) What is the mass of 24 cm3 (or 24 milliliters, mL) of mercury? b) What is the volume of 65.5 g of mercury? c) An unknown metal has a mass of 2.361 g and is 2.35 cm x 0.134 cm x 1.05 cm. What is the identity of the element (dNi = 8.91 g/cm3 ; dTi = 4.50g/cm3 ; dZn = 7.14 g/cm3 ; dSn = 7.23g/cm3 ) d) The Handbook of Chemistry and Physics reports that the density of Zinc (Zn) is 7.50 g/cm3 . i) What is the mass of 10.0 cm3 of Zn? ii) What would be the volume of 50.0 g of Zinc? iii) What is the density of Zinc in g / L (using unit conversion method)
15 Temperature Dependence of Physical Properties The numerical values of the physical properties of matter are often affected by temperature. Density is an important example of this. Temperature (o C) Density of Water (g/cm3 ) 0 (ice) 0.917 0 (liquid water) 0.99984 2 0.99994 3.98 0.999973 (Max Density) 4 0.99997 10 0.9970 Solid water (ice) is less dense than liquid water so it floats. Because the density of materials changes with temperature, it is important to report temperature when doing density studies. Different substances will separate from one another based on their different densities. Three liquids along with two solids are placed into a cylinder. If they arranged themselves from top to bottom according to their densities what would the cylinder look like? Oak Wood 0.71 g/mL Solid Gold 19.3 g/mL Water 1.00 g/mL Gasoline 0.67 g/mL Mercury (liquid) 13.6 g/mL Calculating Density of Substances in Laboratory Regular Shaped Object: 2.0 cm Mass = 10.00 g 2.0 cm Density:______________ Volume = _______________ 5.0 cm Mini Challenge Activity: A piece of aluminum foil that is ________ cm by _________ cm has a mass of ___________ g. The true density of the aluminum is 2.70 g / cm3 . How thick is the foil?
16 Irregular Shaped Object A sample or unknown irregularly shaped metal is placed into a graduated cylinder containing water. The mass of the sample is 37.5 g, and the water levels before and after adding the sample to the cylinders is shown below. What is the density and what type of metal is the unknown? Volume:_____________ 20.8 mL 7.2mL dMg = 1.74 g/cm3 % Error: ____________________ dFe = 7.87 g/cm3 dAg = 10.5 g/cm3 dAl = 2.70 g/cm3 dCu = 8.96 g.cm3 Graphical Methods a) X: ____________g a) Y: ____________g Z: ____________g b) X: ____________mL Y: ____________mL Z: ____________mL X Y c) d) What is the density (slope) of each Z substance? X = ___________ g/cm3 Y = ___________ g/cm3 Z = ___________ g/cm3
17 IV. Temperature and Heat of Matter A. Temperature and its Units Temperature is the property of matter that determines whether heat energy can be transferred from one body to another and the direction of that transfer. Temperature is also a measure of the motion (kinetic energy) of the particles that make up a sample of matter. Heat is what moves from matter at a higher temperature to matter that is at a lower temperature. Heat will continue to flow until both samples of matter are at the same temperature. Aluminum Pellet Air (250 C) 500 C In the U.S. everyday temperatures are reported using the Fahrenheit (o F) scale, but the Celsius scale is used in most other countries. The scientific community has adopted the Kelvin scale (SI Unit). In our class we will be using either the Celsius or Kelvin scales. K = o C + 273 **Absolute Zero F.P. Water B.P. Water 32o F 212o F -273o C 0o C 100o C 0 K 273 K 373 K Solid Water Liquid Water Gaseous Water **At 0 K, absolute zero, all particles in a sample of matter loses ALL KINETIC ENERGY. The particles do not move!!!! Review/Practice: A sample of water is at 200 K. What is its temperature in o C? What state is the water in? Surgical instruments may be sterilized by heating to 170o C for 1.5 hours. Convert 170o C to kelvins? B. Heat(q) and its Units Heat is a form of energy that can be transferred from one body to another because of temperature difference. A transfer will occur from the body at higher temperature to a body that is at a lower temperature until both bodies are at the same temperature. The joule is the SI unit of heat.
18 IV. Matter Can Undergo Physical and Chemical Changes A. Physical Changes Changes in physical properties are called physical changes. In a physical change the identity of a sample doesnt change even though its shape, size, or physical state (solid liquid, or gas) has changed. Chemical bonds are not broken, that is atoms are not rearranged) during physical changes. Physical changes usually involve the addition or removal of heat from a substance (element, compound, or mixture). Examples: Melting, Boiling, Subliming, Freezing, Dissolving, Cutting a piece of copper wire Heat Added MP BP Solid Liquid Gas FP CP Heat Removed B. Chemical Changes When one or more chemical substances (reactants) are changed to one or more DIFFERENT chemical substances (products) a chemical change, or chemical reaction has occurred. At a particulate level a chemical change produces a new arrangement of atoms without a gain or los in the number of atoms of each kind. The particles (atoms, molecules, or ions) present after the reaction, however, are different from those present before the reaction. Chemical change is represented by using a chemical formula called a chemical equation. Indications that a chemical change has occurred include: 1. Energy (Heat or light) is released or absorbed. 2. Change in color or odor 3. Production of gas or solid (precipitate) from a liquid 4. Chemical change is often irreversible. Review/Practice Questions: 1) Classify the following changes as chemical or physical: __Water boils __A firefly emits light __A metal chair rusts __Salt dissolves in water __Milk spoils __bending of wire __Cutting of grass __Burning coal __Dry ice subliming 2) Classify the following properties as chemical or physical: ____ a) a blue-gray color ____ b) brittle ____ c) insoluble in water ____ d) melts at 14100 C ____ e) reacts vigorously with fluorine ____ f) gasoline burns
19 3) Classify the following changes as chemical or physical: ______ Cu + I2 CuI2 ______ CO2 (s) CO2 (g) ______ Ice Melts ______ An alka-seltzer tablet is added to water and dissolved (bubbles form) ______ Table salt (NaCl) is dissolved in water 4) C. Law of Conservation of matter In any physical or chemical change , mass is neither created or destroyed; it is conserved. In other words the total mass of reactants is equal to the total mass of products. Reactants Products Hydrogen + Oxygen Water 4.8 g 38.4 g _________g Consider the following explosive chemical reaction and determine the mass of water produced (Oklahoma City Bomb) 2 NH4NO3 (s) 2 N2 (g) + O2 (g) + 4 H2O (g) 40.0 g 14 g 8 g _______g When powdered iron (Fe) is left exposed to air, it rusts (forms Fe2O3). Explain why the rust weighs more than the original iron. Does this go against the law of conservation of mass?
20 D. Energy and Physical and Chemical Changes of Matter Chemical and physical changes are ALWAYS accompanied by energy changes. Energy is always either released (exothermic reaction; feels warm; heat exits) or absorbed (endothermic reaction; feels cold; heat enters) during chemical and physical changes. Exothermic Chemical Reaction: Hydrogen + Oxygen Water + Heat Endothermic Chemical Reaction: limestone + Heat lime + carbon dioxide (calcium carbonate) (calcium oxide) Photosynthesis (very important!!!) Carbon Dioxide + Water + Light Energy Glucose + Oxygen Exothermic Physical Reaction Liquid water Ice + Heat Endothermic Physical Reaction Ice + Heat Liquid water ReviewPractice: Classify the following as Chemical or Physical changes and then as Exothermic or Endothermic Process Chemical or Physical Endothermic or Exothermic 1. Solid silicon melts _______________ _____________________ 2. Solid KBr is dissolved in water and the solution feels warm _______________ _____________________ 3. Natural gas (CH4) is burned in a furnace _______________ _____________________ 4. Water is boiled in a tea kettle _______________ _____________________ 5. Gaseous water condenses into liquid water in a radiator _______________ _____________________ 6. Fe + S + Heat FeS _______________ _____________________ 7. I2 (g) I2 (s) + Heat _______________ _____________________
21 V. Classifying Matter A. Classifying Matter Based on State (Solid, Liquid, or Gas): The kinetic molecular theory (model) of matter helps to interpret the properties of solids, liquids, and gases. Low Temps High Temps Solid Liquid Gas Particle Arrangement Regular Random Random Shape Rigid Takes Shape of Container Takes Shape of Container Volume Fixed Fixed Expands to fill container (volume affected by press & temp) Motion Vibration Fluid Lots of motion The higher the temperature the faster particles move. The particles energy of motion (kinetic energy, KE) acts to overcome the forces of attraction between particles. Review/Practice: Complete the table below: Substance Pure Element, Pure Compound, State of matter at Room Temperature or Mixture (solid, Liquid or gas) Gold ________________________ _____________________________ Air ________________________ _____________________________ Mercury ________________________ _____________________________ Helium ________________________ _____________________________ Oxygen ________________________ _____________________________ Wine ________________________ _____________________________ Rubbing Alcohol ________________________ _____________________________ (C3H7OH) Dry Ice (CO2) ________________________ _____________________________
22 Phase Changes of Matter Heating Curve of Matter: Cooling Curve of Matter: Melting: The motion of the particles in a solid (KE) are great enough to overcome attraction between particles in solid state, they spread out into a more random liquid arrangement of particles. All pure compounds, pure elements, and mixtures have unique MP and BP. Boiling: The motion of the particles in a liquid (KE) are great enough to overcome attraction between particles in liquid state, they spread out into a extremely random gas arrangement of particles. All pure compounds, pure elements, and mixtures have unique MP and BP. ReviewPractice Reading Heating or Cooling Curve Cooling Curve for Element X A The following questions relate to the Graph to the left B C 1) Is this a heating or cooling for a substance? D 2) What is the substances Freezing Pt: _____o C 3) What is the substances Boiling Pt: _____o C 4) Identify the state of matter of X at F Point A:_________ Point E:_________ E G Point B:_________ Point F:________ Point C:_________ Point G:_______ Point D:_________ 5) What change of state is occurring from points b to c:_______________________ 6) What change of state is occurring from points b to c:_______________________ 7) What process is occurring at the circled region on the curve? _________________
23 B. Classifying Matter Based on Composition Filter Centrifuge Decant Chromatography Distillation Evaporation (20+ million) 117 elements Elements united into fixed ratios Cannot be subdivided by chemical or Physical processes Table salt (NaCl) Water (H2O) Sodium (Na) Silicon (Si) Sand (SiO2) Sugar (C12H22O11) Chlorine (Cl) Oxygen (O2) Fools Gold (FeS2) Hydrogen (H2) Iron (Fe) Element: A substance that CANNOT be changed into a simpler substance (see periodic table) Compound: A substance that CAN be changed into a simpler substance Mixture: A physical blend of two or more substances (elements or compounds) that are not chemically combined ReviewPractice: 1. Classify the mixture as homogenous or heterogeneous then identify the best means of separating the mixture into pure substances (Chromatograpghy, Filtration, or Distilation) Mixture Homogeneous or Heterogeneous Separation Technique Sand (SiO2) and water _______________________ _________________ Salt and water (Boiling Points) _______________________ _________________ Food Coloring _______________________ _________________
24 2. Separating Mixtures. Match the mixtures on the left with the separation method for separating the mixture on the right: _____ Chromatography a) Used to separate homogeneous mixture based on BP differences _____ Filtration of pure substances making up a mixture _____ Distillation b) Used to separate homogeneous mixture based on differences in the _____ Evaporation pure substances in a mixtures ability to adhere to a solid substrate. _____ Centrifuge c) Used to separate heterogeneous mixture based on differences in the _____ Decant size or density of the pure substances making up the mixture Separating Heterogenoeous Mixtures (filtration, centrifuge, decant) Example: Sand & Water (SiO2 and H2O) Decanting Filtering Centrifuge
25 Separating Homogeneous Mixtures (solutions) of Matter Chromatography A process of separating a homogeneous solution (like ink) of closely related compounds by allowing the components of a solution to adsorb (stick) to a solid substrate (paper or glass fiber) while a mobile phase (alcohol, water, etc) allows the components of the mixture to migrate up the solid substrate. Because the components stick with differing degrees of tenacity the components of the mixture separate into colored layers. The compounds found closest to the bottom of the chromatograph have not moved up the solid substrate quickly because they have stuck to the solid with a greater tenacity. The components of the mixture will each be assigned an Rf value = distance pure compound migrated / distance solvent migrated. End A A B B C Solvent Flow Start Unknown Known Ink 1) How many pure compounds make up the unknown ink? _______ 2) How many pure compounds make up the known ink? _______ 3) a) Do either of the inks have an pure compounds in common? _______ b) How do you know? 4) Calculate the Retention Factor, Rf value for compound A 5) a) Which pure compound (A, B, or C) greatest adhesion to the chromatography paper? _______ b) Which pure compound (A, B, or C) least adhesion to the chromatography paper? _______ c) What pure compound (A, B, or C) is found in the unknown but not in the known ink? _______ d) What is the Rf factor for pure compound C? _______
26 Distillation A process of separating a homogeneous solution of closely related compounds based on their large differences in boiling points. A process by which a homogeneous mixture can be separated into its components. In the process a mixture is heated and the component with the lowest boiling point is driven from the mixture as a vapor or gas. This vapor then condenses on the inside of a condensing tube and the purified liquid with the lowest boiling point drips out the far end of the condensing tube. The component of the mixture with the much higher boiling point remains as a liquid in the round bottom flask. Evaporation
27 Practice: 1. Classify the mixture as homogenous or heterogeneous then identify the best means of separating the mixture into pure substances (Chromatograpghy, Filtration, or Distilation) Mixture Homogeneous or Heterogeneous Separation Technique Sand (SiO2) and water _______________________ _________________ Salt and water (Boiling Points) _______________________ _________________ Food Coloring _______________________ _________________ 2. Separating Mixtures. Match the mixtures on the left with the separation method for separating the mixture on the right: _____ Chromatography a) Used to separate homogeneous mixture based on BP differences _____ Filtration of pure substances making up a mixture _____ Distillation b) Used to separate homogeneous mixture based on differences in the _____ Evaporation pure substances in a mixtures ability to adhere to a solid substrate. _____ Centrifuge c) Used to separate heterogeneous mixture based on differences in the _____ Decant size or density of the pure substances making up the mixture Lab Practical: Devise a way, using physical methods of separating mixtures previously discussed in the notes, to separate and quantify the mass of each pure component in a 10.0 g mixture of iron (Fe), sand (SiO2) , and salt (NaCl), into its pure components (you may also use water, H2O).
28 VI. The Scientific Method and Visualizing Data A. The SCIENTIFIC METHOD B. VISUALIZING DATA One of the most important skills to master in science is to determine how changing one variable in an experiment affects another. The variable the experimenter changes or manipulates is the independent variable. The variable that changes in response to the independent variable is called the dependent variable. The value of the dependent variable depends on the independent variable. When graphing data the independent variable is plotted on the x-axis and the dependent variable is plotted on the y-axis. When Graphing Data follow the following steps: 1. Identify the independent and dependent variables in your experiment. The independent variable is plotted on the x-axis and the dependent variable is plotted on the y-axis. 2. Determine the range of the independent variable to be plotted. 3. Decide whether the origin (0,0) is a valid data point. 4. Spread the data out as much as possible. Let each division on the graph paper stand for a convenient unit. 5. Number and label (including what is being plotted and units) the horizontal axis. 6. Repeat steps 2-5 for the dependent variable. 7. Plot the data points on the graph. 8. Draw the best fit straight line or smooth curve that passes through as many data point as possible. Do not use a series of straight lines that connect the dots. 9. Give a graph a title that clearly tells what the graph represents. 10. Give the equation for the line of best fit a R2 using Excel or your calculators regression functions.
29 Dependent Variable vs Independent Variable Linear Relationship Non-Linear Relationship Direct Proportion Parabolic (quadratic) Hyperbolic (inverse) Y = mx + b y = ax2 + bx + c y = a / x or xy = a Practice 1: A sample of gas is placed in a sealed syringe. The sample has a constant mass and is kept at a constant temperature. The pressure on the gas is increased over a series of intervals by the scientist and the volume is then measured. Pressure (atm) Volume (cm3 ) Dependent Variable ___________ 1.01 22.4 Independent Variable ___________ 1.49 14.9 1.99 11.2 Describe the Resulting Curve 2.51 8.95 3.01 7.46 a) Plot the data given in the table and draw curve that best fits all points. b) What is the relationship between Volume and Pressure of a gas? c) What is the equation relating Volume and Pressure of a gas?
30 Practice 2: A ball is dropped from a 50.0 m building and the scientist measures the distance the ball has fallen each second for 5 seconds. Time (s) Distance (m) Dependent Variable ___________ 1 5 2 20 Independent Variable ___________ 3 44 4 80 a) Plot the data given in the table and draw curve that 5 122 best fits all points. b) Describe the Resulting Curve:_________________ c) What is the relationship between Time and Distance of the ball? d) What is the equation relating Time and Distance of the ball?
31 Practice 3: Pete and Sally wanted to investigate how the mass of sulfur is related to its volume. They took various masses of sulfur and measured their volumes. The following data was obtained: Mass (g) Volume (cm3 ) Dependent Variable ___________ 23.5 11.4 60.8 29.2 Independent Variable ___________ 115 55.5 168 81.1 a) Plot the data given in the table and draw curve that best fits all points. b) Describe the Resulting Curve:_________________ c) What is the relationship between mass and volume the sulfur sample? _______________ d) What is the equation relating mass and volume the sulfur sample? _______________ e) Does the slope of the graph represent the sulfurs density? Explain f) What is the density of the sulfur sample? g) The true density of pure sulfur is 2.07 g/cm3 . What is the percent error of Pete and Sallys density determination?

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Ap chemistry notes chapter 1

  • 1. 1 AP Chemistry Notes Chapter 1 Chemistry Notes Chapter 1, 2, 3, & 4 Chemistry is the study of the composition of matter- the stuff things are made of- and the changes matter undergoes. Matter is ultimately composed of chemical elements (atoms) and their compounds. Most matter can exist in one or more states: solid, liquid, and gas. Areas of Study in Chemistry: Organic Chemistry Study of substances containing carbon. Inorganic Chemistry* Study of substances NOT containing carbon. Analytical Chemistry* Study of the composition of substances. Physical Chemistry* Study of the theories and experiments that describe the behavior of substances. Biochemistry Study of the chemistry of living things. I. Matter and Measurement A. Matter: Elements, Compounds, or Mixtures (20+ million) 117 elements Elements united into fixed ratios Cannot be subdivided by chemical or Physical processes Table salt (NaCl) Water (H2O) Sodium (Na) Silicon (Si) Sand (SiO2) Sugar (C12H22O11) Chlorine (Cl) Oxygen (O2) Fools Gold (FeS2) Hydrogen (H2) Iron (Fe) *When elements become part of a compound, their original properties such as color, hardness, melting point are replaced by the characteristic properties of the new compound. Consider table salt (sodium chloride)
  • 2. 2 B. Elements and Atoms 117 elements are known of these only 90 are found in nature; the remainder being created by scientists in a laboratory using techniques of modern physics. Many elements names often have names and symbols relating to their Latin or Greek origin Element Symbol Latin or Greek Iron Fe Ferrum Lead Pb Plumbum Tin Sn Stannum Mercury Hg Mercurum (Hydragyrum Greek) CopperCu Cuprum Silver Ag Argentum Potassium K Kalium Sodium Na Natrium Note: Elements can have a one or two letter symbol. Only the first letter of an elements symbol is capitalized. Elements are listed in the Periodic Table. An atom is the smallest particle of an element that retains the properties (color, hardness, melting point) of that element. Element: A substance that CANNOT be changed into a simpler substance (see periodic table) Compound: A substance that CAN be changed into a simpler substance Mixture: A physical blend of two or more substances (elements or compounds) that are not chemically combined ReviewPractice Identify the following as an element, mixture, compound then identify each as a homogeneous or heterogeneous. Element, Mixture, Compound If Mixture Homogeneous or Heterogeneous 1. Oxygen _____________________ ________________ 2. Air _____________________ ________________ 3. blood _____________________ ________________ 4. brass ( a blend of copper and zinc) _____________________ ________________ 5. Food coloring _____________________ ________________ 6. Soda _____________________ ________________ 7. Silver _____________________ ________________ 8. Salt Water _____________________ ________________ 9. Oil and Water _____________________ ________________ 10. Candle Wax (C20H42) _____________________ ________________ 11. Ice _____________________ ________________ 12. Carbon monoxide (CO) _____________________ ________________ 13. Sugar (C12H22O11) _____________________ ________________
  • 3. 3 II. The Measures of Science -Observations of Matter Doing chemistry requires observing elements and compounds undergoing chemical and physical changes. A. Qualitative Measurements Observations that involve no measurements or units. B. Quantitative Measurements Observations that involve measurements or numbers w/ units. Classify each observation as qualitative or quantitative: Blue-Grey color _____________________ Melts at 1410o C _____________________ Brittle _____________________ 1. SI System- International System of Units The scientific community has chosen a modified version of the metric system as the standard system Measured Property Name of Unit Abbreviation Mass kilogram kg Length meter m Time second s Temperature kelvin K Amount of substance mole mol Electric Current ampere A Prefixes are used to change SI units by powers of 10. To use the SI units effectively, you should know the meanings of the prefixes. Prefix Symbol Multiplier Exponential Example Femto f 1/1 000 000 000 000 000 1 x 10-15 femtosecond (fs) Pico p 1/1 000 000 000 000 1 x 10-12 picometer (pm) Nano n 1/1 000 000 000 1 x 10-9 nanometer (nm) Micro 1/1 000 000 1 x 10-6 microgram (g) Milli m 1/1 000 1 x 10-3 milligram (mg) Centi c 1/100 1 x 10-2 centimeter (cm) Deci d 1/10 1 x 10-1 deciliter (dL) Kilo k 1000 1 x 103 kilometer (km) Mega M 1 000 000 1 x 106 megagram (Mg) Giga G 1 000 000 000 1 x 109 gigameter (Gm) Tera T 1 000 000 000 000 1 x 1012 terameter (Tm) When choosing the best unit and prefix for a measurement you need to choose the correct unit and then the prefix that will give you a measurement that is not extremely large or small. Radius of an atom 1 x 10-12 m so 1 pm Diameter of a virus 1 x 10-6 m so 1 m Circumference of Earth 1 x 107 m so 10 Mm
  • 4. 4 2. Significant Digits in Measurements The valid digits (all certain plus one uncertain/estimated) in a measurement are called significant digits. Rules for determining the number of significant figures in a measurement: 1. Non zero numbers are always significant. 2.84 km ______ sig figs 1.8 x 106 mL ______ sig figs 2. All final zeros after a decimal point are significant. 0.760 s ______ sig figs 75.00 kg ______ sig figs 3. Leading zeros used solely as placeholders are not significant. 0.00345 ______ sig figs 0.023 ______ sig figs 4. Zeros between two other significant digits are always significant. 2804 m ______ sig figs 0.003086 ______ sig figs 5. Zeros located at the end of a number and to the left of a decimal point are significant. 20. 0 C ______ sig figs 3000. K ______ sig figs 20 o C ______ sig figs 3000 K ______ sig figs
  • 5. 5 Practice: Complete the table below Measurement Number of Sig. Figs Measurement Number of Sig. Figs 2804 m _______________ 30.9 V _______________ 2.84 km _______________ 0.001 010 0 s _______________ 0.0029 m _______________ 0.106 W _______________ 4.6 x 105 m _______________ 0.160 A _______________ 4.06 x 10-5 _______________ 5.20 N _______________ 4.060 x 10-5 _______________ 30.9 V _______________ 250 600 m _______________ 5.2234 x 1012 mol _______________ 250 600. m _______________ 4.2 x 106 g _______________ 3. Scientific (Exponential) Notation Many measurements are very large or very small numbers. Written in this form, the values of the quantities take up to much space, are difficult to read, and are awkward to use in calculations. To work with such numbers, write them in scientific (exponential) notation by expressing decimal places as powers of ten. _________ X 10 ___ If this value is negative your number in long form will be <1 Number between 1 and 9.9999 If this value is positive your number in long form will be >1 The average distance from the sun to Mars is 227 800 000 000 m. To write this number is correct scientific notation the decimal is moved to the left 11 places. In scientific notation this distance would be 2.278 x 1011 m. The mass of a single electron is about 0.000 000 000 000 000 000 000 000 000 000 911 kg. To write this number is correct scientific notation the decimal is moved to the right 31 places. In scientific notation this mass would be 9.11 x 10-31 m. Review/Practice: 1. Correct the measurements so that they are in PROPER scientific notation THEN use a prefix rather than scientific notation: Incorrect Scientific Notation Correct Scientific Notation Using Prefix 128. x 103 m _____________________ _________________ 0.009320 x 105 K _____________________ _________________ 2345 x 10-2 g _____________________ _________________ 0.562 x 10-5 s _____________________ _________________
  • 6. 6 2. Complete the Table Long Form Number of Sig figs Scientific Notation 0.0001267 m 4 1.267 x 10-4 m 10022.5 kg ____ __________________ 0.034500 s ____ __________________ ____________ A ____ 2.43 x 105 A ____________ mol ____ 1.23450 x 10-3 mol 200 kg ____ __________________ 200. kg ____ __________________ 200.0 kg ____ __________________ _____________ s ____ 1,243 x 103 s _____________ A ____ 5.6 x 104 A 3. Using the five rules of significant figures, use of scientific notation, and use of prefixes complete the following table: Long Form #Sig Figures Scientific Notation Unit w/ Prefix a) 0.004080 g ________________ _______________ ________________ b) 0.0180 m ________________ _______________ ________________ c) 3450000 s ________________ _______________ ________________ d) 0.0000012 m ________________ _______________ ________________ e) ____________ ________________ _______________ 3.3 dm f) ____________ ________________ 1. 67 x 102 g ________________ g) ____________ ________________ 2.33 x 10-3 s ________________ h) ____________ ________________ ________________ 2.35 袖s 4. Place the following measurements in order from smallest to largest 1.0 km, 1.0 Tm, 1.0 cm, 1.0 m, 1.0 nm, 1.0 袖m _______________________________________________ 4. Significant Figures When Measuring with Laboratory Equipment When recording measurements taken during an experiment, you must always record them with the correct number of significant figures (all certain plus one uncertain/estimated digit) Measuring Volume: Using the graduated cylinders below report the correct volume of liquid
  • 7. 7 Measuring Length: Using the rulers below report the length of your pencil _________cm _________ cm _________ cm Measuring Temperature: Using the thermometers below report the correct temperature _______o C _______o C _________o C Measuring Mass: Electronic balances always report all significant digits. This means that the last digit reported by an electronic balance is uncertain/estimated but it is still significant 208.569 g
  • 8. 8 Review Practice: Read the following instruments. Express your measurement using the correct number of significant figures _________cm _________cm ______mL _______mL ________o C _________o C 5. Arithmetic with Significant Figures As mentioned previously, when recording the results of an experiment, you must always record them with the correct number of significant figures. Frequently you will need to add, subtract, multiply, or divide the measurements. When you perform these arithmetic operations, it is important to remember that the result can never be more precise than the least precise measurement. YOUR CALCULATOR DOES NOT DO THIS FOR YOU!!! Rule #1: Addition and Subtraction: To add or subtract measurements, first perform the operation, then round off the answer to correspond with the least precise measurement 24.686 m 2.456 s 2.341 m - 0.03 s + 3.2 m ________ _________ Rule #2: Multiplication and Division A different rule governs multiplication and division. After performing a calculation, note the measurement with the least number of significant figures and round your final answer to this number of significant figures. 3.22 cm x 2.1 cm = 36.5 m / 3.414 s = Review/Practice 1. Round each measurement to three significant figures. a) 98.473 L ___________ b) 12.17 o C _________ c) 57.048 m ____________ d) 4323.34 s ___________ e) 4327 s _________ f) 0.0007635211 L ____________ (Use Sci. Notation)
  • 9. 9 2. Complete the table Report answers to the correct number of significant figures and include correct units with each answer): Long Form Scientific Notation 1. 6.201 cm + 7.4 cm + 0.68 cm + 12. cm = ___________ ____________ 2. 1.6 km + 0.0162 km + 1.2 km = ___________ ____________ 3. 10.8 g - 8.264 g = ___________ ____________ 4. 475 m - 0.4168 m = ___________ ____________ 5. 131 cm x 2.3 cm = ___________ ____________ 6. 5.761 N x 6.20 m = ___________ ____________ 7. 13.78 g / 11 mL = ___________ ____________ 8. 3.1416 cm / 12.4 s = ___________ ____________ 9. (1.68) ( 23.56 - 2.3) = 1.248 x 103 ___________ ____________ 10. (6.2 x 1018 m ) ( 4.7 x 10-10 m) = ___________ ____________ 11. (6.5 x 105 kg) / (3.4 x 103 m3 ) = ___________ ____________ 3. The following operations were completed on a calculator. The answer the calculator provided is provided for you. Please round the provided answer to the correct number of significant figures with the correct units. Rounded to Calculator Answer Correct num. of SFs a) 3.46 cm + 104.5 cm + 0.346 cm = _________________ _________________ b) 2.384 g - 1.5 g = _________________ _________________ c) 9.40 mm x 2.6 mm = _________________ _________________ d) 1.50 g / 2 cm3 = _________________ _________________ e) 21.50 g/(4.06cm x 1.8 cm x 0.905cm) = _________________ _________________ 6. Unit Conversions (dimensional analysis) Many time the measurements you collect in laboratory are not the units you desire. This will require you to convert a measurement to another unit using dimensional analysis. Measurement in original unit x [ new unit] = Measurement in new units original unit Conversion factor (s) a. Converting Units Within the Metric System Example 1: Convert 456 to kg 456 g 1 kg = 1000g
  • 10. 10 Example 2: Convert 2.1 m to cm 2.1 m ___ cm = m Example 3: Convert 76.2 pm to mm 76.2 pm ____________m _____________mm = pm m b. Converting Ratios Example 1: Convert 65 mi /hr to m/s 65 mi _____km _________m _________hr ________min = m/s hr mi km min s Example 2: Convert 42.3 g/mL to mg/L 45.3 g _____mg _________mL = mg/L mL g L c. Converting Volumes and Areas Example 1: Convert 6.2 m2 to mm2 Example 2: Convert 6.34 x 10-8 cm3 to m3 C. Accuracy and Precision of Laboratory Measurements In laboratory we will often do several quantitative measurements of on a sample of matter (i.e. density, melting point, boiling point .)
  • 11. 11 The PRECISION of a set of measurements is how well several measurements of the same quantity agree. The precision of a set of measurements is often expressed by the average deviation and/or percent deviation. That is we calculate the difference between each experimental result and the average result. The differences, each expressed as a positive quantity, are averaged, and the experiments results are reported as the average value () the average deviation. % deviation = avg deviation x 100% avg. of experimentally determined values If percent deviation is less than 20% you are accurate ACCURACY is the agreement of a measurement with the accepted value of a quantity. Measurements can be precise but not accurate. The accuracy of a set of measurements is often expressed by the percent error. If percent error is less than 20% you are accurate % error = avg of experimentally determined values - accepted value x 100% accepted value If percent error is less than 20% you are accurate Example: Pam makes four measurements of the diameter of a coin using a micrometer. Max measures the same coin using a simple plastic ruler. The true measurement is 27.00 mm. They report the following results: Pam Deviation Max Deviation 28.246 mm 28.9 mm 28.244 23.0 28.246 30.8 28.248 21.1 Avg:____________ Avg:___________ a) Calculate each students average deviation? percent deviation? Which students results were most precise?
  • 12. 12 b) Calculate each students percent error? Which student was most accurate? Practice: Indicate whether each statement below refers to precision (p) or accuracy (a) _____a) This term refers to how close your measurement (or average measurement) is to the true value. ______b) This term refers to how close your measurements are to one another. _____c) The results of your percentage error calculation gives you an idea of the _________ of your measurement(s). _____d) The results of your average deviation calculation gives you an idea of the _________ of your measurement(s). 2. a) Calculate the mean and average deviation for the series of density measurements on samples of zinc below. Please make proper use of significant figures in your calculations Trial # Density (g/cm3 ) Abs Deviation From The Mean 1 7.76 __________ 2 7.82 __________ 3 7.65 __________ Average _____________ 賊 __________ b) The true value for the density of zinc is 7.30 g/cm3 . What was the percent error of the measurements above? III. Properties of Matter A. Chemical Properties The ability of a substance to undergo chemical reactions to form new substances. B. Physical Properties A quality of a substance that can be observed or measured without changing the substances chemical composition. Just as you identify your friends by their physical properties; height, weight, eye color, hair color Chemical substances are also identified by their physical properties. Different chemical substances clearly differ in properties that allow us to classify and identify substances of the world. These physical properties may depend on the amount of substance present (extensive) or may not depend on the amount of substance present (intensive). Intensive properties are useful in identifying unknown substances. Practice:
  • 13. 13 Three primary sources can be used to identify physical and chemical properties of known elements and compounds are Handbook of Chemistry and Physics The Merck Index Material Safety Data Sheet (MSDS) Review/Practice 1) (Using the table on page 12) List (a) physical property(ies) that can be used to distinguish Ethanol and Water. 2) (Using the table on page 12) List (a) a physical property(ies) that can be used to distinguish sodium chloride and sulfur. Common physical properties of matter: Property Intensive or Extensive Physical Property Mass ______________________________ Volume ______________________________ Color ______________________________ State of Matter ______________________________ *Melting Point ______________________________ *Boiling Point ______________________________ *Density ______________________________ Solubility ______________________________ Electrical Conductivity ______________________________ Malleability ______________________________ Ductility ______________________________ Viscosity ______________________________ * These intensive properties can be used to identify pure substances like elements and compounds because every element and compound has a unique values.
  • 14. 14 Important Physical Property -- Density Density is the ratio of the mass of an object to its volume. This property is useful in identifying an unknown substance. The density of a substance relates the mass and volume of a substance. If you know any two of the three quantities you can solve for the third. Mass D = _______ Volume Sample Calculations: The Handbook of Chemistry and Physics lists the density of mercury as 13.534 g/cm3 (at 20 o C). a) What is the mass of 24 cm3 (or 24 milliliters, mL) of mercury? b) What is the volume of 65.5 g of mercury? c) An unknown metal has a mass of 2.361 g and is 2.35 cm x 0.134 cm x 1.05 cm. What is the identity of the element (dNi = 8.91 g/cm3 ; dTi = 4.50g/cm3 ; dZn = 7.14 g/cm3 ; dSn = 7.23g/cm3 ) d) The Handbook of Chemistry and Physics reports that the density of Zinc (Zn) is 7.50 g/cm3 . i) What is the mass of 10.0 cm3 of Zn? ii) What would be the volume of 50.0 g of Zinc? iii) What is the density of Zinc in g / L (using unit conversion method)
  • 15. 15 Temperature Dependence of Physical Properties The numerical values of the physical properties of matter are often affected by temperature. Density is an important example of this. Temperature (o C) Density of Water (g/cm3 ) 0 (ice) 0.917 0 (liquid water) 0.99984 2 0.99994 3.98 0.999973 (Max Density) 4 0.99997 10 0.9970 Solid water (ice) is less dense than liquid water so it floats. Because the density of materials changes with temperature, it is important to report temperature when doing density studies. Different substances will separate from one another based on their different densities. Three liquids along with two solids are placed into a cylinder. If they arranged themselves from top to bottom according to their densities what would the cylinder look like? Oak Wood 0.71 g/mL Solid Gold 19.3 g/mL Water 1.00 g/mL Gasoline 0.67 g/mL Mercury (liquid) 13.6 g/mL Calculating Density of Substances in Laboratory Regular Shaped Object: 2.0 cm Mass = 10.00 g 2.0 cm Density:______________ Volume = _______________ 5.0 cm Mini Challenge Activity: A piece of aluminum foil that is ________ cm by _________ cm has a mass of ___________ g. The true density of the aluminum is 2.70 g / cm3 . How thick is the foil?
  • 16. 16 Irregular Shaped Object A sample or unknown irregularly shaped metal is placed into a graduated cylinder containing water. The mass of the sample is 37.5 g, and the water levels before and after adding the sample to the cylinders is shown below. What is the density and what type of metal is the unknown? Volume:_____________ 20.8 mL 7.2mL dMg = 1.74 g/cm3 % Error: ____________________ dFe = 7.87 g/cm3 dAg = 10.5 g/cm3 dAl = 2.70 g/cm3 dCu = 8.96 g.cm3 Graphical Methods a) X: ____________g a) Y: ____________g Z: ____________g b) X: ____________mL Y: ____________mL Z: ____________mL X Y c) d) What is the density (slope) of each Z substance? X = ___________ g/cm3 Y = ___________ g/cm3 Z = ___________ g/cm3
  • 17. 17 IV. Temperature and Heat of Matter A. Temperature and its Units Temperature is the property of matter that determines whether heat energy can be transferred from one body to another and the direction of that transfer. Temperature is also a measure of the motion (kinetic energy) of the particles that make up a sample of matter. Heat is what moves from matter at a higher temperature to matter that is at a lower temperature. Heat will continue to flow until both samples of matter are at the same temperature. Aluminum Pellet Air (250 C) 500 C In the U.S. everyday temperatures are reported using the Fahrenheit (o F) scale, but the Celsius scale is used in most other countries. The scientific community has adopted the Kelvin scale (SI Unit). In our class we will be using either the Celsius or Kelvin scales. K = o C + 273 **Absolute Zero F.P. Water B.P. Water 32o F 212o F -273o C 0o C 100o C 0 K 273 K 373 K Solid Water Liquid Water Gaseous Water **At 0 K, absolute zero, all particles in a sample of matter loses ALL KINETIC ENERGY. The particles do not move!!!! Review/Practice: A sample of water is at 200 K. What is its temperature in o C? What state is the water in? Surgical instruments may be sterilized by heating to 170o C for 1.5 hours. Convert 170o C to kelvins? B. Heat(q) and its Units Heat is a form of energy that can be transferred from one body to another because of temperature difference. A transfer will occur from the body at higher temperature to a body that is at a lower temperature until both bodies are at the same temperature. The joule is the SI unit of heat.
  • 18. 18 IV. Matter Can Undergo Physical and Chemical Changes A. Physical Changes Changes in physical properties are called physical changes. In a physical change the identity of a sample doesnt change even though its shape, size, or physical state (solid liquid, or gas) has changed. Chemical bonds are not broken, that is atoms are not rearranged) during physical changes. Physical changes usually involve the addition or removal of heat from a substance (element, compound, or mixture). Examples: Melting, Boiling, Subliming, Freezing, Dissolving, Cutting a piece of copper wire Heat Added MP BP Solid Liquid Gas FP CP Heat Removed B. Chemical Changes When one or more chemical substances (reactants) are changed to one or more DIFFERENT chemical substances (products) a chemical change, or chemical reaction has occurred. At a particulate level a chemical change produces a new arrangement of atoms without a gain or los in the number of atoms of each kind. The particles (atoms, molecules, or ions) present after the reaction, however, are different from those present before the reaction. Chemical change is represented by using a chemical formula called a chemical equation. Indications that a chemical change has occurred include: 1. Energy (Heat or light) is released or absorbed. 2. Change in color or odor 3. Production of gas or solid (precipitate) from a liquid 4. Chemical change is often irreversible. Review/Practice Questions: 1) Classify the following changes as chemical or physical: __Water boils __A firefly emits light __A metal chair rusts __Salt dissolves in water __Milk spoils __bending of wire __Cutting of grass __Burning coal __Dry ice subliming 2) Classify the following properties as chemical or physical: ____ a) a blue-gray color ____ b) brittle ____ c) insoluble in water ____ d) melts at 14100 C ____ e) reacts vigorously with fluorine ____ f) gasoline burns
  • 19. 19 3) Classify the following changes as chemical or physical: ______ Cu + I2 CuI2 ______ CO2 (s) CO2 (g) ______ Ice Melts ______ An alka-seltzer tablet is added to water and dissolved (bubbles form) ______ Table salt (NaCl) is dissolved in water 4) C. Law of Conservation of matter In any physical or chemical change , mass is neither created or destroyed; it is conserved. In other words the total mass of reactants is equal to the total mass of products. Reactants Products Hydrogen + Oxygen Water 4.8 g 38.4 g _________g Consider the following explosive chemical reaction and determine the mass of water produced (Oklahoma City Bomb) 2 NH4NO3 (s) 2 N2 (g) + O2 (g) + 4 H2O (g) 40.0 g 14 g 8 g _______g When powdered iron (Fe) is left exposed to air, it rusts (forms Fe2O3). Explain why the rust weighs more than the original iron. Does this go against the law of conservation of mass?
  • 20. 20 D. Energy and Physical and Chemical Changes of Matter Chemical and physical changes are ALWAYS accompanied by energy changes. Energy is always either released (exothermic reaction; feels warm; heat exits) or absorbed (endothermic reaction; feels cold; heat enters) during chemical and physical changes. Exothermic Chemical Reaction: Hydrogen + Oxygen Water + Heat Endothermic Chemical Reaction: limestone + Heat lime + carbon dioxide (calcium carbonate) (calcium oxide) Photosynthesis (very important!!!) Carbon Dioxide + Water + Light Energy Glucose + Oxygen Exothermic Physical Reaction Liquid water Ice + Heat Endothermic Physical Reaction Ice + Heat Liquid water ReviewPractice: Classify the following as Chemical or Physical changes and then as Exothermic or Endothermic Process Chemical or Physical Endothermic or Exothermic 1. Solid silicon melts _______________ _____________________ 2. Solid KBr is dissolved in water and the solution feels warm _______________ _____________________ 3. Natural gas (CH4) is burned in a furnace _______________ _____________________ 4. Water is boiled in a tea kettle _______________ _____________________ 5. Gaseous water condenses into liquid water in a radiator _______________ _____________________ 6. Fe + S + Heat FeS _______________ _____________________ 7. I2 (g) I2 (s) + Heat _______________ _____________________
  • 21. 21 V. Classifying Matter A. Classifying Matter Based on State (Solid, Liquid, or Gas): The kinetic molecular theory (model) of matter helps to interpret the properties of solids, liquids, and gases. Low Temps High Temps Solid Liquid Gas Particle Arrangement Regular Random Random Shape Rigid Takes Shape of Container Takes Shape of Container Volume Fixed Fixed Expands to fill container (volume affected by press & temp) Motion Vibration Fluid Lots of motion The higher the temperature the faster particles move. The particles energy of motion (kinetic energy, KE) acts to overcome the forces of attraction between particles. Review/Practice: Complete the table below: Substance Pure Element, Pure Compound, State of matter at Room Temperature or Mixture (solid, Liquid or gas) Gold ________________________ _____________________________ Air ________________________ _____________________________ Mercury ________________________ _____________________________ Helium ________________________ _____________________________ Oxygen ________________________ _____________________________ Wine ________________________ _____________________________ Rubbing Alcohol ________________________ _____________________________ (C3H7OH) Dry Ice (CO2) ________________________ _____________________________
  • 22. 22 Phase Changes of Matter Heating Curve of Matter: Cooling Curve of Matter: Melting: The motion of the particles in a solid (KE) are great enough to overcome attraction between particles in solid state, they spread out into a more random liquid arrangement of particles. All pure compounds, pure elements, and mixtures have unique MP and BP. Boiling: The motion of the particles in a liquid (KE) are great enough to overcome attraction between particles in liquid state, they spread out into a extremely random gas arrangement of particles. All pure compounds, pure elements, and mixtures have unique MP and BP. ReviewPractice Reading Heating or Cooling Curve Cooling Curve for Element X A The following questions relate to the Graph to the left B C 1) Is this a heating or cooling for a substance? D 2) What is the substances Freezing Pt: _____o C 3) What is the substances Boiling Pt: _____o C 4) Identify the state of matter of X at F Point A:_________ Point E:_________ E G Point B:_________ Point F:________ Point C:_________ Point G:_______ Point D:_________ 5) What change of state is occurring from points b to c:_______________________ 6) What change of state is occurring from points b to c:_______________________ 7) What process is occurring at the circled region on the curve? _________________
  • 23. 23 B. Classifying Matter Based on Composition Filter Centrifuge Decant Chromatography Distillation Evaporation (20+ million) 117 elements Elements united into fixed ratios Cannot be subdivided by chemical or Physical processes Table salt (NaCl) Water (H2O) Sodium (Na) Silicon (Si) Sand (SiO2) Sugar (C12H22O11) Chlorine (Cl) Oxygen (O2) Fools Gold (FeS2) Hydrogen (H2) Iron (Fe) Element: A substance that CANNOT be changed into a simpler substance (see periodic table) Compound: A substance that CAN be changed into a simpler substance Mixture: A physical blend of two or more substances (elements or compounds) that are not chemically combined ReviewPractice: 1. Classify the mixture as homogenous or heterogeneous then identify the best means of separating the mixture into pure substances (Chromatograpghy, Filtration, or Distilation) Mixture Homogeneous or Heterogeneous Separation Technique Sand (SiO2) and water _______________________ _________________ Salt and water (Boiling Points) _______________________ _________________ Food Coloring _______________________ _________________
  • 24. 24 2. Separating Mixtures. Match the mixtures on the left with the separation method for separating the mixture on the right: _____ Chromatography a) Used to separate homogeneous mixture based on BP differences _____ Filtration of pure substances making up a mixture _____ Distillation b) Used to separate homogeneous mixture based on differences in the _____ Evaporation pure substances in a mixtures ability to adhere to a solid substrate. _____ Centrifuge c) Used to separate heterogeneous mixture based on differences in the _____ Decant size or density of the pure substances making up the mixture Separating Heterogenoeous Mixtures (filtration, centrifuge, decant) Example: Sand & Water (SiO2 and H2O) Decanting Filtering Centrifuge
  • 25. 25 Separating Homogeneous Mixtures (solutions) of Matter Chromatography A process of separating a homogeneous solution (like ink) of closely related compounds by allowing the components of a solution to adsorb (stick) to a solid substrate (paper or glass fiber) while a mobile phase (alcohol, water, etc) allows the components of the mixture to migrate up the solid substrate. Because the components stick with differing degrees of tenacity the components of the mixture separate into colored layers. The compounds found closest to the bottom of the chromatograph have not moved up the solid substrate quickly because they have stuck to the solid with a greater tenacity. The components of the mixture will each be assigned an Rf value = distance pure compound migrated / distance solvent migrated. End A A B B C Solvent Flow Start Unknown Known Ink 1) How many pure compounds make up the unknown ink? _______ 2) How many pure compounds make up the known ink? _______ 3) a) Do either of the inks have an pure compounds in common? _______ b) How do you know? 4) Calculate the Retention Factor, Rf value for compound A 5) a) Which pure compound (A, B, or C) greatest adhesion to the chromatography paper? _______ b) Which pure compound (A, B, or C) least adhesion to the chromatography paper? _______ c) What pure compound (A, B, or C) is found in the unknown but not in the known ink? _______ d) What is the Rf factor for pure compound C? _______
  • 26. 26 Distillation A process of separating a homogeneous solution of closely related compounds based on their large differences in boiling points. A process by which a homogeneous mixture can be separated into its components. In the process a mixture is heated and the component with the lowest boiling point is driven from the mixture as a vapor or gas. This vapor then condenses on the inside of a condensing tube and the purified liquid with the lowest boiling point drips out the far end of the condensing tube. The component of the mixture with the much higher boiling point remains as a liquid in the round bottom flask. Evaporation
  • 27. 27 Practice: 1. Classify the mixture as homogenous or heterogeneous then identify the best means of separating the mixture into pure substances (Chromatograpghy, Filtration, or Distilation) Mixture Homogeneous or Heterogeneous Separation Technique Sand (SiO2) and water _______________________ _________________ Salt and water (Boiling Points) _______________________ _________________ Food Coloring _______________________ _________________ 2. Separating Mixtures. Match the mixtures on the left with the separation method for separating the mixture on the right: _____ Chromatography a) Used to separate homogeneous mixture based on BP differences _____ Filtration of pure substances making up a mixture _____ Distillation b) Used to separate homogeneous mixture based on differences in the _____ Evaporation pure substances in a mixtures ability to adhere to a solid substrate. _____ Centrifuge c) Used to separate heterogeneous mixture based on differences in the _____ Decant size or density of the pure substances making up the mixture Lab Practical: Devise a way, using physical methods of separating mixtures previously discussed in the notes, to separate and quantify the mass of each pure component in a 10.0 g mixture of iron (Fe), sand (SiO2) , and salt (NaCl), into its pure components (you may also use water, H2O).
  • 28. 28 VI. The Scientific Method and Visualizing Data A. The SCIENTIFIC METHOD B. VISUALIZING DATA One of the most important skills to master in science is to determine how changing one variable in an experiment affects another. The variable the experimenter changes or manipulates is the independent variable. The variable that changes in response to the independent variable is called the dependent variable. The value of the dependent variable depends on the independent variable. When graphing data the independent variable is plotted on the x-axis and the dependent variable is plotted on the y-axis. When Graphing Data follow the following steps: 1. Identify the independent and dependent variables in your experiment. The independent variable is plotted on the x-axis and the dependent variable is plotted on the y-axis. 2. Determine the range of the independent variable to be plotted. 3. Decide whether the origin (0,0) is a valid data point. 4. Spread the data out as much as possible. Let each division on the graph paper stand for a convenient unit. 5. Number and label (including what is being plotted and units) the horizontal axis. 6. Repeat steps 2-5 for the dependent variable. 7. Plot the data points on the graph. 8. Draw the best fit straight line or smooth curve that passes through as many data point as possible. Do not use a series of straight lines that connect the dots. 9. Give a graph a title that clearly tells what the graph represents. 10. Give the equation for the line of best fit a R2 using Excel or your calculators regression functions.
  • 29. 29 Dependent Variable vs Independent Variable Linear Relationship Non-Linear Relationship Direct Proportion Parabolic (quadratic) Hyperbolic (inverse) Y = mx + b y = ax2 + bx + c y = a / x or xy = a Practice 1: A sample of gas is placed in a sealed syringe. The sample has a constant mass and is kept at a constant temperature. The pressure on the gas is increased over a series of intervals by the scientist and the volume is then measured. Pressure (atm) Volume (cm3 ) Dependent Variable ___________ 1.01 22.4 Independent Variable ___________ 1.49 14.9 1.99 11.2 Describe the Resulting Curve 2.51 8.95 3.01 7.46 a) Plot the data given in the table and draw curve that best fits all points. b) What is the relationship between Volume and Pressure of a gas? c) What is the equation relating Volume and Pressure of a gas?
  • 30. 30 Practice 2: A ball is dropped from a 50.0 m building and the scientist measures the distance the ball has fallen each second for 5 seconds. Time (s) Distance (m) Dependent Variable ___________ 1 5 2 20 Independent Variable ___________ 3 44 4 80 a) Plot the data given in the table and draw curve that 5 122 best fits all points. b) Describe the Resulting Curve:_________________ c) What is the relationship between Time and Distance of the ball? d) What is the equation relating Time and Distance of the ball?
  • 31. 31 Practice 3: Pete and Sally wanted to investigate how the mass of sulfur is related to its volume. They took various masses of sulfur and measured their volumes. The following data was obtained: Mass (g) Volume (cm3 ) Dependent Variable ___________ 23.5 11.4 60.8 29.2 Independent Variable ___________ 115 55.5 168 81.1 a) Plot the data given in the table and draw curve that best fits all points. b) Describe the Resulting Curve:_________________ c) What is the relationship between mass and volume the sulfur sample? _______________ d) What is the equation relating mass and volume the sulfur sample? _______________ e) Does the slope of the graph represent the sulfurs density? Explain f) What is the density of the sulfur sample? g) The true density of pure sulfur is 2.07 g/cm3 . What is the percent error of Pete and Sallys density determination?
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