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A Scientific Research Proposal on
Development of PBAT based Bio Filler Masterbatch
CONTENT
Introduction
End Applications
Cost Analysis
Challenges and Troubleshooting
Timeline and Budget
Manufacturing process of Bio-filler masterbatch
Objectives
Bio filler masterbatch  the mix between
bioplastic and filler masterbatch?
Bio filler masterbatch is the mixture of bio resin, specific fillers (calcium
carbonate powder, talc powder, barium powder,) and additives in different
formulas to completely fulfill end-products requirements.
The introduction of bio resin allows end-products to be biodegradable
after use, thus minimizing the harmful effects on the environment.
How does bio filler masterbatch benefit end-
products?
Cost reduction
Bio filler masterbatch reduces the amount of bioplastic consumed, which is relatively
high-expense.
CaCO3 is a good thermal conductive, it considerably shortens the product cycle and
minimizes the energy consumption, which facilitates the production efficiency.
Properties enhancement
Adding bio filler, end-products are provided with great stiffness, flexural durability, less
shrinkage, good thermal conductivity, whiteness and transparency.
Use of bio filler masterbatch comes at the cost of mechanical degradation is a misconception.
Processing aid additive
 Streamline the blown film process.
 Bio filler masterbatch reduces the blocking between them, thus improving the effectiveness of
the production.
1. Improve the dimensional stability of plastic products
The addition of CaCo3 powder plays a skeleton role in plastic products and has great significant on the
dimensional stability of plastic products.
2. Improve the processing properties of plastics
The addition of CaCo3 powder can change the rheological properties of plastic. Calcium carbonate
powder is usually added in larger quantities to facilitate their mixing with other components and the
processing and moulding of plastics.
3. Improve the heat resistance of plastic products
4. Improve the astigmatism of plastics
Calcium carbonate powder with a whiteness above 90 has obvious whitening effect in plastic products.
5. It can make the product have some special properties
The addition of calcium carbonate powder can improve the electroplating and printing properties of
some products.
Other
benefits
1. Bio filler masterbatch containing calcium carbonate
powder (CaCO3)
CaCO3 bio filler is widely used in several industries, such as
blown film, extrusion, injection molding. And due to its great
biodegradability, it is specifically preferable in manufacturing
single-use products.
2. Bio filler masterbatch containing talc powder
A good thermal resistance, good stiffness and low shrinkage
and is widely used in a wide variety of fields ranging from
blown film to extrusion, thermoforming, and injection
molding.
3. Bio filler masterbatch containing barium sulfate
Specifically preferred in the retail industry (shopping bags, roll
bag), F&B (food packaging films) and agriculture (mulching
Common types of bio filler masterbatches and
their uses
OBJECTIVES
1. Development of PBAT based bio filler masterbatch for to reduce cost and to achieve
desirable properties in the end product.
2. Development of masterbatches varying the composition for different applications
and composition optimization.
3. In-depth analysis of the effect of developed bio filler masterbatch on mechanical
property, thermal property, surface texture, barrier property and other functional
properties of the end product.
4. Evaluation of the effect of developed bio filler masterbatch on biodegradability
and/or compostability of the end product.
5. Establish a feasible industrial production process.
Typical compositions of Bio-filler Masterbatch End Application
PBAT: 20% - 30%
Calcium Carbonate (CaCO3)/Talk: 70% - 80% Packaging Films
PBAT: 20% - 25%
Calcium Carbonate (CaCO3): 60% - 75%
UV Stabilizers: 5% - 15%
Agricultural Films
PLA: 10% - 30%
Talc: 45% - 80%
Impact Modifier: 5% - 15%
Processing Aid: 5% - 10%
Injection-Molded Products
PLA: 10% - 20%
Wood Flour: 65% - 85%
Starch-based Binder: 5% - 15%
Disposable Cutlery
PLA/PBAT: 10% - 20%
Rice Husk Ash (RHA): 60% - 80%
Plant Nutrients: 10% - 20%
Horticultural Pots
PBAT: 20% - 30%
Talc: 55% - 75%
Softening Agent: 5% - 15%
Non-Woven Fabrics
Surface treatment
or particle size
reduction of the
filler (if required).
High speed mixing
of the filler and
carrier resin in
presence of other
additives
The mixture is
processed into
liquid or to a
dough-like state at
high temperature
The blend is cooled
and processed
through a twin
screw extruder
Cut into beads to a
particular size.
Bio-filler Masterbatch Production
Premix process
Twin screw extrusion
Challenges in Bio-filler Masterbatch Production
Challenges Issue Troubleshooting
AGGLOMERATION OF THE
FILLER
 Large number of white spots are bound
to form on the film. Even white hard
particles may form a "cloud.
 Prevent excessive friction during surface
treatment to avoid static electricity generation
by friction.
PROPORTION OF THE
FILLER IN THE
MASTERBATCH
 Imbalance of cost of production and the
desired property.
 The weight percentage of the filler should not
more than 80%.
 R&D to optimize the composition.
PHYSICAL MIXING
 In the twin-screw extruder, the filler
particle separate.
 Uneven material mixing results "cloud"
or white spots on the final product.
 Mixing time and temperature should be
optimum.
CHOICE OF EXTRUDER
 Improper mixing.
 Product with poor surface texture.  Co-rotating twin-screw extruders are superior to
single-screw extruders.
COOLING METHOD  Water cooling of the masterbatch is a
major hidden danger to the blown film.
 Air-cooled die face hot cutting process should
be preferred.
 When the extruder has a large diameter and
the output is higher than 300kg/h, it is
preferable to use a belt cooling method.
Challenges Issue Troubleshooting
BREAKING STRENGTH
 The Melt Flowing Index of filler
masterbatch is extremely lower than the
resin. filler does not melt properly when
processed results in breaking the film.
 Loading of sufficient carrier resin in the
filler masterbatch
BLACK DOT IN FILM  High moisture content in the filler
masterbatch and resin.
 Proper preheating of the components
before processing.
FILM PUNCTURE  Large particle size of the filler.
 Improper mixing.
 Particle size reduction and surface
treatment of the filler
HIGH-SPEED TAPE
BREAKING
 High speed extrusion.
 Different flow rate of the components.  Process optimization
FILM SURFACE IS
BLOOMING  Unsuitable filler masterbatch.  Selection of suitable masterbatch for
different polymer compositions.
BLOCKING THE NET  Masterbatch surface texture.  Selection of good quality filler
Basic challenges in Film production process with Bio-filler
Masterbatch
Cost analysis of the bio-filler masterbatch
Types of Bio-filler
masterbatch
Raw material cost
(RMC) (in INR per kg)
Manufacturing and
operation cost
(in INR per kg)
Total cost
(in INR per kg)
Market selling
price
(in INR per kg)
PBAT-CaCO3 (80%) 62-82 15-25 77-107 120-150
PBAT-Talk (80%) 58-78 15-20 73-98 120-140
PBAT-Barium
sulphate (80%)
74-94 15-25 89-119 140-180
PBAT-Rice husk ash Based on the availability 15-30 - 90-120
PBAT-Wood flour/
other natural filler Based on the availability 15-30 - 90-120
 The manufacturing cost highly depends on the market dynamics, price of PBAT, and the percentage of filler
loading. The bulk manufacturing will reduce the cost of production.
 The RMC will be in the higher side for the bio-filler masterbatch for special applications (like Impact modified bio-
filler masterbatch).
Deliverable and Milestone
Timeline (in months)
0-2 3-4 5-6 7-8 9-10
Literature review
Work plan and experiment design
Procurement of polymers and other required consumables
Composition optimization
Experimental trials
Property analysis and optimization
Technology transfer
PROJECT TIMELINE
Sl. No. Item description Amount (in INR)
1 Chemicals and Consumables 1,00,000.00
2 Manpower
 1- Senior Research Fellow (SRF)
(42,000+18% HRA per month)
 1- Project Assistant
(20,000+18% HRA per month)
7,31,600.00
3 Characterization and Analysis 4,00,000.00
4 Contingency 50,000.00
5 Sub Total 12,81,600.00
6 Over head cost (15%) 1,92,240.00
Total 14,73,840.00
Proposed Budget
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Bio fillers eco friendly products technical & business presentationpptx

  • 1. A Scientific Research Proposal on Development of PBAT based Bio Filler Masterbatch
  • 2. CONTENT Introduction End Applications Cost Analysis Challenges and Troubleshooting Timeline and Budget Manufacturing process of Bio-filler masterbatch Objectives
  • 3. Bio filler masterbatch the mix between bioplastic and filler masterbatch? Bio filler masterbatch is the mixture of bio resin, specific fillers (calcium carbonate powder, talc powder, barium powder,) and additives in different formulas to completely fulfill end-products requirements. The introduction of bio resin allows end-products to be biodegradable after use, thus minimizing the harmful effects on the environment.
  • 4. How does bio filler masterbatch benefit end- products? Cost reduction Bio filler masterbatch reduces the amount of bioplastic consumed, which is relatively high-expense. CaCO3 is a good thermal conductive, it considerably shortens the product cycle and minimizes the energy consumption, which facilitates the production efficiency. Properties enhancement Adding bio filler, end-products are provided with great stiffness, flexural durability, less shrinkage, good thermal conductivity, whiteness and transparency. Use of bio filler masterbatch comes at the cost of mechanical degradation is a misconception. Processing aid additive Streamline the blown film process. Bio filler masterbatch reduces the blocking between them, thus improving the effectiveness of the production.
  • 5. 1. Improve the dimensional stability of plastic products The addition of CaCo3 powder plays a skeleton role in plastic products and has great significant on the dimensional stability of plastic products. 2. Improve the processing properties of plastics The addition of CaCo3 powder can change the rheological properties of plastic. Calcium carbonate powder is usually added in larger quantities to facilitate their mixing with other components and the processing and moulding of plastics. 3. Improve the heat resistance of plastic products 4. Improve the astigmatism of plastics Calcium carbonate powder with a whiteness above 90 has obvious whitening effect in plastic products. 5. It can make the product have some special properties The addition of calcium carbonate powder can improve the electroplating and printing properties of some products. Other benefits
  • 6. 1. Bio filler masterbatch containing calcium carbonate powder (CaCO3) CaCO3 bio filler is widely used in several industries, such as blown film, extrusion, injection molding. And due to its great biodegradability, it is specifically preferable in manufacturing single-use products. 2. Bio filler masterbatch containing talc powder A good thermal resistance, good stiffness and low shrinkage and is widely used in a wide variety of fields ranging from blown film to extrusion, thermoforming, and injection molding. 3. Bio filler masterbatch containing barium sulfate Specifically preferred in the retail industry (shopping bags, roll bag), F&B (food packaging films) and agriculture (mulching Common types of bio filler masterbatches and their uses
  • 7. OBJECTIVES 1. Development of PBAT based bio filler masterbatch for to reduce cost and to achieve desirable properties in the end product. 2. Development of masterbatches varying the composition for different applications and composition optimization. 3. In-depth analysis of the effect of developed bio filler masterbatch on mechanical property, thermal property, surface texture, barrier property and other functional properties of the end product. 4. Evaluation of the effect of developed bio filler masterbatch on biodegradability and/or compostability of the end product. 5. Establish a feasible industrial production process.
  • 8. Typical compositions of Bio-filler Masterbatch End Application PBAT: 20% - 30% Calcium Carbonate (CaCO3)/Talk: 70% - 80% Packaging Films PBAT: 20% - 25% Calcium Carbonate (CaCO3): 60% - 75% UV Stabilizers: 5% - 15% Agricultural Films PLA: 10% - 30% Talc: 45% - 80% Impact Modifier: 5% - 15% Processing Aid: 5% - 10% Injection-Molded Products PLA: 10% - 20% Wood Flour: 65% - 85% Starch-based Binder: 5% - 15% Disposable Cutlery PLA/PBAT: 10% - 20% Rice Husk Ash (RHA): 60% - 80% Plant Nutrients: 10% - 20% Horticultural Pots PBAT: 20% - 30% Talc: 55% - 75% Softening Agent: 5% - 15% Non-Woven Fabrics
  • 9. Surface treatment or particle size reduction of the filler (if required). High speed mixing of the filler and carrier resin in presence of other additives The mixture is processed into liquid or to a dough-like state at high temperature The blend is cooled and processed through a twin screw extruder Cut into beads to a particular size. Bio-filler Masterbatch Production Premix process Twin screw extrusion
  • 10. Challenges in Bio-filler Masterbatch Production Challenges Issue Troubleshooting AGGLOMERATION OF THE FILLER Large number of white spots are bound to form on the film. Even white hard particles may form a "cloud. Prevent excessive friction during surface treatment to avoid static electricity generation by friction. PROPORTION OF THE FILLER IN THE MASTERBATCH Imbalance of cost of production and the desired property. The weight percentage of the filler should not more than 80%. R&D to optimize the composition. PHYSICAL MIXING In the twin-screw extruder, the filler particle separate. Uneven material mixing results "cloud" or white spots on the final product. Mixing time and temperature should be optimum. CHOICE OF EXTRUDER Improper mixing. Product with poor surface texture. Co-rotating twin-screw extruders are superior to single-screw extruders. COOLING METHOD Water cooling of the masterbatch is a major hidden danger to the blown film. Air-cooled die face hot cutting process should be preferred. When the extruder has a large diameter and the output is higher than 300kg/h, it is preferable to use a belt cooling method.
  • 11. Challenges Issue Troubleshooting BREAKING STRENGTH The Melt Flowing Index of filler masterbatch is extremely lower than the resin. filler does not melt properly when processed results in breaking the film. Loading of sufficient carrier resin in the filler masterbatch BLACK DOT IN FILM High moisture content in the filler masterbatch and resin. Proper preheating of the components before processing. FILM PUNCTURE Large particle size of the filler. Improper mixing. Particle size reduction and surface treatment of the filler HIGH-SPEED TAPE BREAKING High speed extrusion. Different flow rate of the components. Process optimization FILM SURFACE IS BLOOMING Unsuitable filler masterbatch. Selection of suitable masterbatch for different polymer compositions. BLOCKING THE NET Masterbatch surface texture. Selection of good quality filler Basic challenges in Film production process with Bio-filler Masterbatch
  • 12. Cost analysis of the bio-filler masterbatch Types of Bio-filler masterbatch Raw material cost (RMC) (in INR per kg) Manufacturing and operation cost (in INR per kg) Total cost (in INR per kg) Market selling price (in INR per kg) PBAT-CaCO3 (80%) 62-82 15-25 77-107 120-150 PBAT-Talk (80%) 58-78 15-20 73-98 120-140 PBAT-Barium sulphate (80%) 74-94 15-25 89-119 140-180 PBAT-Rice husk ash Based on the availability 15-30 - 90-120 PBAT-Wood flour/ other natural filler Based on the availability 15-30 - 90-120 The manufacturing cost highly depends on the market dynamics, price of PBAT, and the percentage of filler loading. The bulk manufacturing will reduce the cost of production. The RMC will be in the higher side for the bio-filler masterbatch for special applications (like Impact modified bio- filler masterbatch).
  • 13. Deliverable and Milestone Timeline (in months) 0-2 3-4 5-6 7-8 9-10 Literature review Work plan and experiment design Procurement of polymers and other required consumables Composition optimization Experimental trials Property analysis and optimization Technology transfer PROJECT TIMELINE
  • 14. Sl. No. Item description Amount (in INR) 1 Chemicals and Consumables 1,00,000.00 2 Manpower 1- Senior Research Fellow (SRF) (42,000+18% HRA per month) 1- Project Assistant (20,000+18% HRA per month) 7,31,600.00 3 Characterization and Analysis 4,00,000.00 4 Contingency 50,000.00 5 Sub Total 12,81,600.00 6 Over head cost (15%) 1,92,240.00 Total 14,73,840.00 Proposed Budget