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STUDYDUNIYA
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C H E M I S T R Y - I N O R G A N I C -
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variousconstituents (atoms, ions, etc.)
together in different chemical species is
called a chemical bond.
CHEMICAL BOND
STUDYDUNIYA
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ofvalence electrons from one atom to
anotheror by sharing of valenceelectrons
in order to have an octet in theirvalence
shells. This is known as octet rule
OCTET RULE
STUDYDUNIYA
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they are said to be joined by a single
covalent bond.
If two atoms share two pairs of electrons,
the covalent bond between them is
called a double bond.
LEWIS-LANGMUIR THEORY
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LEWIS-LANGMUIR THEORY
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The ease of formation of the positive and
negative ions from the respective neutral
atoms.
The arrangement of the positive and
negative ions in the solid, i.e. the lattice
of the crystalline compound.
IONIC OR ELECTROVALENT BOND
Formation of ionic compounds would
primarily depend upon:
STUDYDUNIYA
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Polarity of bond arises when a pair of
electrons is unequally shared between
two atoms.
As a result of polarisation, the molecule
possesses the dipole moment
POLARITY OF BONDS
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DIPOLE MOMENT
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The shape of a molecule depends upon
the number of valence shell electron pairs
around the central atom.
Pairs of electrons in the valence shell
repel one another
These pairs of electrons tend to occupy
such positions in space that minimise
repulsion and thus maximise distance
between them.
VSEPR THEORY
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The valence shell is taken as a sphere
withthe electron pairs localising on the
spherical surface at maximum distance
from one another.
A multiple bond is treated as if it is a
single electron pair.
Where two or more resonance structures
can represent a molecule, the VSEPR
model is applicable to any such structure
VSEPR THEORY
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SHAPES OF MOLECULES
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SHAPES OF MOLECULES
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SHAPES OF MOLECULES
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SHAPES OF MOLECULES
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ORBITAL OVERLAP
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ORBITAL OVERLAP
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ORBITAL OVERLAP
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Sigma bond
TYPES OF OVERLAPPING
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Pi bond
TYPES OF OVERLAPPING
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(a)sp hybridisation:
HYBRIDISATION
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(a)sp hybridisation:
HYBRIDISATION
2
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(a)sp hybridisation:
HYBRIDISATION
3
STUDYDUNIYA
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(a)sp hybridisation:
HYBRIDISATION
3
STUDYDUNIYA
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HYBRIDISATION
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(a)spdhybridisation:
HYBRIDISATION
3
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MOLECULAR ORBITAL THEORY
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The increasing order of energies of various
molecular orbitals for O2 and F2 is given
below
MOLECULAR ORBITAL THEORY
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For molecules such as B2, C2, N2 etc. the
increasing order of energies of various
molecular orbitals is
MOLECULAR ORBITAL THEORY
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(1) Intermolecular hydrogen bond : It is
  formed between two different molecules 
  of the same or different compounds.
(2) Intramolecular hydrogen bond : It is
  formed when hydrogen atom is in        
  between the two highly electronegative (F,
  O, N) atoms present within the same      
  molecule.
HYDROGEN BONDING

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Chemical bonding and molecular structure

  • 1. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion SurveyThe attractive force which holds variousconstituents (atoms, ions, etc.) together in different chemical species is called a chemical bond. CHEMICAL BOND
  • 2. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion SurveyAtoms can combine either by transfer ofvalence electrons from one atom to anotheror by sharing of valenceelectrons in order to have an octet in theirvalence shells. This is known as octet rule OCTET RULE
  • 3. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Surveywhen two atoms share one electron pair they are said to be joined by a single covalent bond. If two atoms share two pairs of electrons, the covalent bond between them is called a double bond. LEWIS-LANGMUIR THEORY
  • 4. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey LEWIS-LANGMUIR THEORY
  • 5. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey The ease of formation of the positive and negative ions from the respective neutral atoms. The arrangement of the positive and negative ions in the solid, i.e. the lattice of the crystalline compound. IONIC OR ELECTROVALENT BOND Formation of ionic compounds would primarily depend upon:
  • 6. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey Polarity of bond arises when a pair of electrons is unequally shared between two atoms. As a result of polarisation, the molecule possesses the dipole moment POLARITY OF BONDS
  • 7. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey DIPOLE MOMENT
  • 8. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey The shape of a molecule depends upon the number of valence shell electron pairs around the central atom. Pairs of electrons in the valence shell repel one another These pairs of electrons tend to occupy such positions in space that minimise repulsion and thus maximise distance between them. VSEPR THEORY
  • 9. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey The valence shell is taken as a sphere withthe electron pairs localising on the spherical surface at maximum distance from one another. A multiple bond is treated as if it is a single electron pair. Where two or more resonance structures can represent a molecule, the VSEPR model is applicable to any such structure VSEPR THEORY
  • 10. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey SHAPES OF MOLECULES
  • 11. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey SHAPES OF MOLECULES
  • 12. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey SHAPES OF MOLECULES
  • 13. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey SHAPES OF MOLECULES
  • 14. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey ORBITAL OVERLAP
  • 15. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey ORBITAL OVERLAP
  • 16. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey ORBITAL OVERLAP
  • 17. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey Sigma bond TYPES OF OVERLAPPING
  • 18. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 Employee Opinion Survey Pi bond TYPES OF OVERLAPPING
  • 19. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 (a)sp hybridisation: HYBRIDISATION
  • 20. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 (a)sp hybridisation: HYBRIDISATION 2
  • 21. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 (a)sp hybridisation: HYBRIDISATION 3
  • 22. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 (a)sp hybridisation: HYBRIDISATION 3
  • 23. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 HYBRIDISATION
  • 24. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 (a)spdhybridisation: HYBRIDISATION 3
  • 25. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 MOLECULAR ORBITAL THEORY
  • 26. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 The increasing order of energies of various molecular orbitals for O2 and F2 is given below MOLECULAR ORBITAL THEORY
  • 27. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 For molecules such as B2, C2, N2 etc. the increasing order of energies of various molecular orbitals is MOLECULAR ORBITAL THEORY
  • 28. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - C H E M I C A L B O N D I N G IIT JEE @studyduniya +91 7744994714 (1) Intermolecular hydrogen bond : It is formed between two different molecules of the same or different compounds. (2) Intramolecular hydrogen bond : It is formed when hydrogen atom is in between the two highly electronegative (F, O, N) atoms present within the same molecule. HYDROGEN BONDING