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jbladon 1
CONDUCTIVE
PALLADIUM SULFIDE
The Crimson? Direct Plate Process
Crimson? Trademark of Dow Chemical
jbladon 2
PREPARATION
1. Palladium-tin colloidal particles have a Pd-
rich core and are charge-stabilized with
negatively charged tin chloride species.
2. Palladium-Tin colloid is adsorbed onto
substrate pretreated with cationic surfactant.
3. Tin rinsed off.
4. Substrate is exposed to alkaline solution of
sodium sulfide, producing PdS.
jbladon 3
? Crimson? Direct Plate Process
? Used to electroplate thru-holes in
printed circuit boards
? Adsorbed PdS nanoparticles on epoxy
substrate permits immediate copper
electroplating.
APPLICATION
Crimson? Trademark of Dow Chemical
jbladon 4
? XAS, XPS and Extended X-ray Absorption Fine
Structure (EXAFS) research is published:
? A Palladium Sulfide Catalyst for Electrolytic Plating.
Bladon, John J. et al, Electrochem. Soc. (1996),
143(4), 1206-13
ESTABLISHING COMPOSITION
AND STRUCTURE
MEASURING PARTICLE SIZE
USING
ATOMIC FORCE MICROSCOPY
jbladon 5
PREPARATION OF SAMPLE
? Atomically flat pyrolytic graphite is
processed through Crimson? Direct
Plate.
? Exposure time is adjusted to avoid
multilayer adsorption of colloid.
? Sample is rinsed and air dried.
jbladon 6
jbladon 7
Surface view of PdS
nanoparticles
jbladon 8
Diameter of PdS
nanoparticles
is about 5 nm
jbladon 9
Isometric view of PdS
nanoparticles
PATENTS ON CRIMSON?
DIRECT PLATE PROCESS
? Electroplating Process. Bladon, John J., (Shipley Co). April 24, 1990;
US 4,919,768.
? Method for electroplating nonconductors. Bladon, John J.; Robinson,
John N.; Rousseau, Michael. (Shipley Co). April 28, 1990; US
4,952,286.
? Electroplating process. Bladon, John J., (Shipley Co). April 16, 1991;
US 5,007,990.
? Printed Circuit Board. Bladon, John J., (Shipley Co). May 21 1991;
US 5,017,742.
? Electroplating Process and Composition. Bladon, John J., (Shipley
Co). May 4, 1993; US 5,207,888.
? Spray Parameters for Horizontal Processing. Bladon, John J.;
Colangelo, Carl; Robinson, John; Rousseau, Michael. (Rohm and
Haas). Filed August 9, 1993; US 5,374,346.
? Electroplating Process and Composition. Bladon, John J., (Shipley
Co). January 4, 1994; US 5,276,290.
jbladon 10

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Crimson Direct Plate

  • 1. jbladon 1 CONDUCTIVE PALLADIUM SULFIDE The Crimson? Direct Plate Process Crimson? Trademark of Dow Chemical
  • 2. jbladon 2 PREPARATION 1. Palladium-tin colloidal particles have a Pd- rich core and are charge-stabilized with negatively charged tin chloride species. 2. Palladium-Tin colloid is adsorbed onto substrate pretreated with cationic surfactant. 3. Tin rinsed off. 4. Substrate is exposed to alkaline solution of sodium sulfide, producing PdS.
  • 3. jbladon 3 ? Crimson? Direct Plate Process ? Used to electroplate thru-holes in printed circuit boards ? Adsorbed PdS nanoparticles on epoxy substrate permits immediate copper electroplating. APPLICATION Crimson? Trademark of Dow Chemical
  • 4. jbladon 4 ? XAS, XPS and Extended X-ray Absorption Fine Structure (EXAFS) research is published: ? A Palladium Sulfide Catalyst for Electrolytic Plating. Bladon, John J. et al, Electrochem. Soc. (1996), 143(4), 1206-13 ESTABLISHING COMPOSITION AND STRUCTURE
  • 5. MEASURING PARTICLE SIZE USING ATOMIC FORCE MICROSCOPY jbladon 5
  • 6. PREPARATION OF SAMPLE ? Atomically flat pyrolytic graphite is processed through Crimson? Direct Plate. ? Exposure time is adjusted to avoid multilayer adsorption of colloid. ? Sample is rinsed and air dried. jbladon 6
  • 7. jbladon 7 Surface view of PdS nanoparticles
  • 8. jbladon 8 Diameter of PdS nanoparticles is about 5 nm
  • 9. jbladon 9 Isometric view of PdS nanoparticles
  • 10. PATENTS ON CRIMSON? DIRECT PLATE PROCESS ? Electroplating Process. Bladon, John J., (Shipley Co). April 24, 1990; US 4,919,768. ? Method for electroplating nonconductors. Bladon, John J.; Robinson, John N.; Rousseau, Michael. (Shipley Co). April 28, 1990; US 4,952,286. ? Electroplating process. Bladon, John J., (Shipley Co). April 16, 1991; US 5,007,990. ? Printed Circuit Board. Bladon, John J., (Shipley Co). May 21 1991; US 5,017,742. ? Electroplating Process and Composition. Bladon, John J., (Shipley Co). May 4, 1993; US 5,207,888. ? Spray Parameters for Horizontal Processing. Bladon, John J.; Colangelo, Carl; Robinson, John; Rousseau, Michael. (Rohm and Haas). Filed August 9, 1993; US 5,374,346. ? Electroplating Process and Composition. Bladon, John J., (Shipley Co). January 4, 1994; US 5,276,290. jbladon 10

Editor's Notes