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Electron Configuration

Filling-Order of Electrons in an Atom
4f
Sublevels
                           4d
                     n=4
                           4p
                           3d
                           4s
            Energy   n=3   3p

                           3s

                           2p
                     n=2
                           2s

                     n=1   1s
4f
 Sublevels
                                                     4d
      s       p           d       f            n=4
          s           p       d
                                                     4p
                  s       p
                      s                              3d
                                                     4s




                                      Energy
                                               n=3   3p

                                                     3s
1s22s22p63s23p64s23d104p65s24d10
                                                     2p
                                               n=2
                                                     2s

                                               n=1   1s
Filling Rules for Electron Orbitals

 Aufbau Principle: Electrons are
 added one at a time to the lowest
 energy orbitals available until all the
 electrons of the atom have been
 accounted for.


 *Aufbau is German for building up
Energy Level Diagram
                         6s     6p               5d                       4f




                          5s    5p               4d
                                                                                           Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                N




                          2s    2p




                           1s

                                                                                       Electron Configuration
                                               NUCLEUS


                         H He Li C N Al Ar F                                   Fe La
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Energy Level Diagram
                         6s     6p               5d                       4f               Hydrogen

                          5s    5p               4d
                                                                                           Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                N




                          2s    2p




                           1s

                                                                                       Electron Configuration
                                               NUCLEUS
                                                                                            H = 1s1
                         H He Li C N Al Ar F                                   Fe La
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Energy Level Diagram
                         6s     6p               5d                       4f                 Helium

                          5s    5p               4d
                                                                                           Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                N




                          2s    2p




                           1s

                                                                                       Electron Configuration
                                               NUCLEUS
                                                                                           He = 1s2
                         H He Li C N Al Ar F                                   Fe La
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Energy Level Diagram
                         6s     6p               5d                       4f                 Lithium

                          5s    5p               4d
                                                                                           Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                N




                          2s    2p




                           1s

                                                                                       Electron Configuration
                                               NUCLEUS
                                                                                           Li = 1s22s1
                         H He Li C N Al Ar F                                   Fe La
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Energy Level Diagram
                         6s     6p               5d                       4f                 Carbon

                          5s    5p               4d
                                                                                           Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                N




                          2s    2p




                           1s

                                                                                       Electron Configuration
                                               NUCLEUS
                                                                                          C = 1s22s22p2
                         H He Li C N Al Ar F                                   Fe La
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Energy Level Diagram
                         6s     6p               5d                       4f                Nitrogen

                          5s    5p               4d
                                                                                           Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                N

                                            Hunds Rule maximum
                                              number of unpaired
                                                  orbitals.
                          2s    2p




                           1s

                                                                                       Electron Configuration
                                               NUCLEUS
                                                                                          N = 1s22s22p3
                         H He Li C N Al Ar F                                   Fe La
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Energy Level Diagram
                         6s     6p               5d                       4f                 Fluorine

                          5s    5p               4d
                                                                                           Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                N




                          2s    2p




                           1s

                                                                                       Electron Configuration
                                               NUCLEUS
                                                                                          F = 1s22s22p5
                         H He Li C N Al Ar F                                   Fe La
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Energy Level Diagram
                         6s     6p               5d                       4f                Aluminum

                          5s    5p               4d
                                                                                            Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                 N




                          2s    2p




                           1s

                                                                                        Electron Configuration
                                               NUCLEUS
                                                                                       Al = 1s22s22p63s23p1
                         H He Li C N Al Ar F                                   Fe La
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Energy Level Diagram
                         6s     6p               5d                       4f                   Argon

                          5s    5p               4d
                                                                                            Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                 N




                          2s    2p




                           1s

                                                                                        Electron Configuration
                                               NUCLEUS
                                                                                       Ar = 1s22s22p63s23p6
                         H He Li C N Al Ar F                                   Fe La
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Energy Level Diagram
                         6s     6p               5d                       4f                  Iron

                          5s    5p               4d
                                                                                           Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                N




                          2s    2p




                           1s

                                                                                       Electron Configuration
                                               NUCLEUS
                                                                                   Fe = 1s22s22p63s23p64s23d6
                         H He Li C N Al Ar F                                   Fe La
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Energy Level Diagram
                         6s     6p               5d                       4f                 Lanthanum

                          5s    5p               4d
                                                                                              Bohr Model


                          4s    4p               3d
Arbitrary Energy Scale




                           3s   3p
                                                                                                   N




                          2s    2p




                           1s

                                                                                          Electron Configuration
                                               NUCLEUS
                                                                                       La = 1s22s22p63s23p64s23d10
                         H He Li C N Al Ar F                                   Fe   La 4p65s24d105p66s25d1
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Write out the complete electron configuration for the following:
         1) An atom of nitrogen

         2) An atom of silver




                      POP
         3) An atom of krypton




                      QUIZ
  Draw a Bohr model an Argon atom .
Answer Key

Write out the complete electron configuration for the following:

         1) An atom of nitrogen 1s22s22p3

         2) An atom of silver      1s22s22p63s23p64s23d104p65s24d9
         3) An atom of krypton     1s22s22p63s23p64s23d104p6




Draw a Bohr model of a Argon atom.


                                 n=
                                                               n
                                           22+
Periodic Table  Filling Order
Electron Configurations and
     the Periodic Table
Orbitals Being Filled
              1                   Groups                            8

          1   1s    2                           3   4   5    6   7 1s

          2    2s                                       2p

          3    3s                                       3p
Periods




          4    4s            3d                         4p


          5    5s            4d                         5p


          6    6s       La   5d                         6p


          7    7s       Ac   6d



                                           4f                           Lanthanide series

                                           5f                           Actinide series
Electron Filling in Periodic Table   s
    s


1                              p


2


3               d


4


5


6       


7       

                        f
s
         s
                                                                                                            H     He
    H                                                                                             p          1        2
1
    1
    Li   Be                                                                       B    C    N         O     F     Ne
2
    3        4                                                                    5    6    7         8      9        10
    Na Mg                                      d                                  Al   Si   P         S     Cl        Ar
3
    11       12                                                                   13   14   15        16    17        18
    K    Ca Sc         Ti    V     Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br                                                Kr
4
    19       20   21   22    23    24    25        26    27    28   29       30   31   32   33        34    35        36
    Rb Sr         Y    Zr Nb Mo Tc Ru Rh Pd Ag Cd                                 In   Sn Sb Te              I    Xe
5
    37       38   39   40    41    42    43        44    45    46   47       48   49   50   51        52    53        54
    Cs Ba              Hf    Ta    W     Re Os           Ir    Pt Au Hg           Tl   Pb Bi      Po At Rn
6                 
    55       56        72    73    74    75        76    77    78   79       80   81   82   83        84    85        86
    Fr   Ra            Rf Db Sg Bh Hs Mt
7                 
    87       88        104   105   106   107       108   109
                                                                         f

                       La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
                  
                       57    58    59    60        61    62    63   64       65   66   67   68        69    70        71
                       Ac Th Pa          U     Np Pu Am Cm Bk Cf                       Es Fm Md No Lr
                  
                       89    90    91    92        93    94    95   96       97   98   99   100       101   102       103
Electron Filling in Periodic Table                                                                                                s
          s
                                                                                                                           H      He
    H                                                                                                           p          1s1        1s2
1
    1s1
    Li    Be                                                                               B      C      N          O      F      Ne
2
    2s1       2s2                                                                          2p1    2p2    2p3        2p4    2p5        2p6
    Na Mg                                         d                                        Al     Si     P          S      Cl         Ar
3
    3s1       3s2                                                                          3p1    3p2    3p3        3p4    3p5        3p6
    K     Ca Sc           Ti    V     Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br                                                             Kr
4
    4s1       4s2   3d1   3d2   3d3   3d5   3d5       3d6   3d7   3d8    3d10       3d10   4p1    4p2    4p3        4p4    4p5        4p6
    Rb Sr           Y     Zr Nb Mo Tc Ru Rh Pd Ag Cd                                       In     Sn Sb Te                  I     Xe
5
    5s1       5s2   4d1   4d2   4d4   4d5   4d6       4d7   4d8   4d10   4d10       4p1    5p1    5p2    5p3        5p4    5p5        5p6
    Cs Ba                 Hf    Ta    W     Re Os           Ir    Pt Au Hg                 Tl     Pb Bi         Po At Rn
6                   
    6s1       6s2         5d2   5d3   5d4   5d5       5d6   5d7   5d9    5d10       5d10   6p1    6p2    6p3        6p4    6p5        6p6
    Fr    Ra              H     H     H     H         H     H
7                   
    7s1       7s2         1s1   1s1   1s1   1s1       1s1   1s1
                                                                                f

                          La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
                    
                          5d1   4f2   4f3   4f4       4f5   4f6   4f7    4f7        4f9    4f10   4f11   4f12       4f13   4f14   4f114
                          Ac Th Pa          U     Np Pu Am Cm Bk Cf                               Es Fm Md No Lr
                    
                          6d1   6d2   5f2   5f3       5f4   5f6   5f7    5f7        5f8    5f10   5f11   5f14       5f13   5f14       5f14

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  • 3. 4f Sublevels 4d s p d f n=4 s p d 4p s p s 3d 4s Energy n=3 3p 3s 1s22s22p63s23p64s23d104p65s24d10 2p n=2 2s n=1 1s
  • 4. Filling Rules for Electron Orbitals Aufbau Principle: Electrons are added one at a time to the lowest energy orbitals available until all the electrons of the atom have been accounted for. *Aufbau is German for building up
  • 5. Energy Level Diagram 6s 6p 5d 4f 5s 5p 4d Bohr Model 4s 4p 3d Arbitrary Energy Scale 3s 3p N 2s 2p 1s Electron Configuration NUCLEUS H He Li C N Al Ar F Fe La CLICK ON ELEMENT TO FILL IN CHARTS
  • 6. Energy Level Diagram 6s 6p 5d 4f Hydrogen 5s 5p 4d Bohr Model 4s 4p 3d Arbitrary Energy Scale 3s 3p N 2s 2p 1s Electron Configuration NUCLEUS H = 1s1 H He Li C N Al Ar F Fe La CLICK ON ELEMENT TO FILL IN CHARTS
  • 7. Energy Level Diagram 6s 6p 5d 4f Helium 5s 5p 4d Bohr Model 4s 4p 3d Arbitrary Energy Scale 3s 3p N 2s 2p 1s Electron Configuration NUCLEUS He = 1s2 H He Li C N Al Ar F Fe La CLICK ON ELEMENT TO FILL IN CHARTS
  • 8. Energy Level Diagram 6s 6p 5d 4f Lithium 5s 5p 4d Bohr Model 4s 4p 3d Arbitrary Energy Scale 3s 3p N 2s 2p 1s Electron Configuration NUCLEUS Li = 1s22s1 H He Li C N Al Ar F Fe La CLICK ON ELEMENT TO FILL IN CHARTS
  • 9. Energy Level Diagram 6s 6p 5d 4f Carbon 5s 5p 4d Bohr Model 4s 4p 3d Arbitrary Energy Scale 3s 3p N 2s 2p 1s Electron Configuration NUCLEUS C = 1s22s22p2 H He Li C N Al Ar F Fe La CLICK ON ELEMENT TO FILL IN CHARTS
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  • 11. Energy Level Diagram 6s 6p 5d 4f Fluorine 5s 5p 4d Bohr Model 4s 4p 3d Arbitrary Energy Scale 3s 3p N 2s 2p 1s Electron Configuration NUCLEUS F = 1s22s22p5 H He Li C N Al Ar F Fe La CLICK ON ELEMENT TO FILL IN CHARTS
  • 12. Energy Level Diagram 6s 6p 5d 4f Aluminum 5s 5p 4d Bohr Model 4s 4p 3d Arbitrary Energy Scale 3s 3p N 2s 2p 1s Electron Configuration NUCLEUS Al = 1s22s22p63s23p1 H He Li C N Al Ar F Fe La CLICK ON ELEMENT TO FILL IN CHARTS
  • 13. Energy Level Diagram 6s 6p 5d 4f Argon 5s 5p 4d Bohr Model 4s 4p 3d Arbitrary Energy Scale 3s 3p N 2s 2p 1s Electron Configuration NUCLEUS Ar = 1s22s22p63s23p6 H He Li C N Al Ar F Fe La CLICK ON ELEMENT TO FILL IN CHARTS
  • 14. Energy Level Diagram 6s 6p 5d 4f Iron 5s 5p 4d Bohr Model 4s 4p 3d Arbitrary Energy Scale 3s 3p N 2s 2p 1s Electron Configuration NUCLEUS Fe = 1s22s22p63s23p64s23d6 H He Li C N Al Ar F Fe La CLICK ON ELEMENT TO FILL IN CHARTS
  • 15. Energy Level Diagram 6s 6p 5d 4f Lanthanum 5s 5p 4d Bohr Model 4s 4p 3d Arbitrary Energy Scale 3s 3p N 2s 2p 1s Electron Configuration NUCLEUS La = 1s22s22p63s23p64s23d10 H He Li C N Al Ar F Fe La 4p65s24d105p66s25d1 CLICK ON ELEMENT TO FILL IN CHARTS
  • 16. Write out the complete electron configuration for the following: 1) An atom of nitrogen 2) An atom of silver POP 3) An atom of krypton QUIZ Draw a Bohr model an Argon atom .
  • 17. Answer Key Write out the complete electron configuration for the following: 1) An atom of nitrogen 1s22s22p3 2) An atom of silver 1s22s22p63s23p64s23d104p65s24d9 3) An atom of krypton 1s22s22p63s23p64s23d104p6 Draw a Bohr model of a Argon atom. n= n 22+
  • 18. Periodic Table Filling Order
  • 19. Electron Configurations and the Periodic Table
  • 20. Orbitals Being Filled 1 Groups 8 1 1s 2 3 4 5 6 7 1s 2 2s 2p 3 3s 3p Periods 4 4s 3d 4p 5 5s 4d 5p 6 6s La 5d 6p 7 7s Ac 6d 4f Lanthanide series 5f Actinide series
  • 21. Electron Filling in Periodic Table s s 1 p 2 3 d 4 5 6 7 f
  • 22. s s H He H p 1 2 1 1 Li Be B C N O F Ne 2 3 4 5 6 7 8 9 10 Na Mg d Al Si P S Cl Ar 3 11 12 13 14 15 16 17 18 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 4 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 5 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn 6 55 56 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Fr Ra Rf Db Sg Bh Hs Mt 7 87 88 104 105 106 107 108 109 f La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
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