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Ionic Liquids in Plastic/Coating Applications - 10 minutes intro to Holland Colours Asia

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Amabilis Jelliarko Palgunadi
Amabilis Jelliarko Palgunadi

Ionic liquids are molten salts composed of large organic cations and anions that remain liquid at low temperatures. They have a structure that can be tailored for specific applications, such as incorporating pigments, dyes, or additives into plastics or coatings. BASF has developed the first commercial process using ionic liquids under the name BASIL and offers a portfolio of ionic liquids called BASIONIC. Ionic liquids show potential as novel plasticizers to modify the mechanical properties of renewable biomaterials like starch and cellulose, as well as dispersants for nanoparticles in coatings and plastics.

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Ionic Liquids – Neoteric Compounds for Plastic and Coating Industries Prepared by Jelliarko Palgunadi HCA Surabaya
Cation Anion Molten salts composed of relatively large organic cations and anions, featuring low melting points. IONIC LIQUIDS (ILs) ARE …..
Key feature IL's structure can be tailored for specific applications i.e., task specific ILs containing pigment, dyes, flame retardants, anti aging, UV absorber, etc., or can be use as novel vehicles for plastic colorants or additives.
Future of Ionic Liquids
BASILTM – The first commercial process employing ILs by BASF BASIONICTM - A broad portfolio of Ionic Liquids by BASF
1. http://link.springer.com/article/10.1007/s00289-011-0490-3 2. http://www.sciencedirect.com/science/article/pii/S0014305703001290 3. http://pubs.acs.org/doi/abs/10.1021/bk-2003-0856.ch037 4. http://www.leicester-ils.co.uk/materials.html Novel Materials — Salt Modified Starch4 Current trend is renewable, bio-based plastics. Starch, cellulose are plausible candidates. However, mechanical properties must be modified. ILs-based plasticizer, i.e. choline chloride can increase flexibility of thermoplastic starch. Functional liquids for polymers Alternative plasticizer for traditional phthalates1-3
Industrial application of ionic liquids as performance additives Secondary dispersant in universal pigment pastes5 5. http://pubs.rsc.org/en/Content/ArticleLanding/2005/GC/b411357h
Opportunities in many different applications: Basionics are effective in liquid coatings and cured coatings used for home and public applications, clean rooms and hospitals as well as in industrial plants. Basionics –highly efficient antistatic additives based on ionic liquid materials from BASF
Novel Materials for Novel Applications Dispersion media for nanoparticles IL have been found as good synthesis and dispersion media for metal nanoparticles6 , carbon allotropes (CNTs, fullerenes, graphene)7. Plausible applications including coatings and nanoparticle incorporation into plastic resins. 6. http://pubs.acs.org/doi/abs/10.1021/ic702071w?journalCode=inocaj 7. www.iolitec.de
Major Challenges 1. Hydrophilicity (hygroscopic nature) 2. Synthesis (price)
From Academia to Industry … and many more.

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Ionic Liquids in Plastic/Coating Applications - 10 minutes intro to Holland Colours Asia

  • 1. Ionic Liquids – Neoteric Compounds for Plastic and Coating Industries Prepared by Jelliarko Palgunadi HCA Surabaya
  • 2. Cation Anion Molten salts composed of relatively large organic cations and anions, featuring low melting points. IONIC LIQUIDS (ILs) ARE …..
  • 3. Key feature IL's structure can be tailored for specific applications i.e., task specific ILs containing pigment, dyes, flame retardants, anti aging, UV absorber, etc., or can be use as novel vehicles for plastic colorants or additives.
  • 4. Future of Ionic Liquids
  • 5. BASILTM – The first commercial process employing ILs by BASF BASIONICTM - A broad portfolio of Ionic Liquids by BASF
  • 6. 1. http://link.springer.com/article/10.1007/s00289-011-0490-3 2. http://www.sciencedirect.com/science/article/pii/S0014305703001290 3. http://pubs.acs.org/doi/abs/10.1021/bk-2003-0856.ch037 4. http://www.leicester-ils.co.uk/materials.html Novel Materials — Salt Modified Starch4 Current trend is renewable, bio-based plastics. Starch, cellulose are plausible candidates. However, mechanical properties must be modified. ILs-based plasticizer, i.e. choline chloride can increase flexibility of thermoplastic starch. Functional liquids for polymers Alternative plasticizer for traditional phthalates1-3
  • 7. Industrial application of ionic liquids as performance additives Secondary dispersant in universal pigment pastes5 5. http://pubs.rsc.org/en/Content/ArticleLanding/2005/GC/b411357h
  • 8. Opportunities in many different applications: Basionics are effective in liquid coatings and cured coatings used for home and public applications, clean rooms and hospitals as well as in industrial plants. Basionics –highly efficient antistatic additives based on ionic liquid materials from BASF
  • 9. Novel Materials for Novel Applications Dispersion media for nanoparticles IL have been found as good synthesis and dispersion media for metal nanoparticles6 , carbon allotropes (CNTs, fullerenes, graphene)7. Plausible applications including coatings and nanoparticle incorporation into plastic resins. 6. http://pubs.acs.org/doi/abs/10.1021/ic702071w?journalCode=inocaj 7. www.iolitec.de
  • 10. Major Challenges 1. Hydrophilicity (hygroscopic nature) 2. Synthesis (price)
  • 11. From Academia to Industry … and many more.