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Lecture  1 07-Dec-2020 Unit - 1
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore 1
Material Science
Course Introduction
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  1
Syllabus  Material Science
2
Unit I: Phase Diagram
Phase diagram  Basic principles  Simple binary systems  Solid solutions  Eutectic systems- Application - Solid solution  Interstitial and substitution solid
solutions  Hume  Rothery electron compounds  Long range order theory of Bragg and Williams  Super lattices  Interstitial phase  Intermetallic compounds -
Elementary Ideas of corrosion  Oxidation  Creep and fracture
Unit II: Defects
Point defects  Scottky and Frenkel defects  Number of defects as a function of temperature  Diffusion in metals  Diffusion and Ionic conductivity in Ionic
crystals -Dislocations  Edge and screw dislocations  Burgers vector  Plastic deformation  Slip  Motion of dislocations under uniform Shear Stress - Stress
fields around dislocations  Density  Work hardening  Effect of grain size on dislocation motion Effect of solute atoms on dislocation motion.
Unit III: Optical Properties, Dielectric Properties and Ferro Electrics
Color centers  Photo conductivity  Electronic transitions in Photo conductors  Trap, capture, recombination centers  Luminescence - Excitation and emission
Decay mechanisms Thallium activated alkali halides  Sulfide phosphorous - Ferroelectrics  Ferro electricity  General properties  Dipole theory  Ionic
displacements and the behaviour of BaTiO3  Spontaneous polarization of BaTiO3  Thermodynamics of Ferro electric transitions.
Unit IV: Elastic Behaviour, Polymer and Ceramics
An elastic and visco elastic behaviour - Atomic model of elastic behaviour - rubber like elasticity - An elastic deformation - Relaxation process - Model for visco
elastic behaviour - Polymers - Polymerization mechanism - Polymer structures - Deformation of polymers - Behaviour of polymers - Ceramics - Ceramic phases -
Structure - classes - Effect of structure on the behaviour of ceramic phases - composites.
Unit V: Laser Physics
Introduction  Interaction of radiation with matter - Spontaneous and stimulated emission  Conditions for oscillation to occur  Frequency of oscillation of the
system  Einstein co-efficient  Population inversion - Laser pumping Rate equations - Three level laser - Four level Laser  Nd:YAG Laser  He-Ne Laser -
Optical resonator  Types and modes of resonator  Oscillation - Threshold condition  The confocal resonant cavity  Theory  Spot size and beam divergence -
quality factor (Q) of an optical cavity.
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  1
Text & Reference Books
3
Text Books
1. G.K. Narula, K.S. Narula and V.K. Gupta - Material Science, TMH, New Delhi, 1995.
2. A.J. Dekker - Solid State Physics - McMillan Co., 1981.
3. V. Ragavan - Material Science and Engineering, 4th Edition - Prentice Hall of India, New Delhi, 2003.
4. M. Arumugam - Materials Science, 3rd Edition - Anuradha Agencies, 2002.
Books for Reference:
1. Lawrence H. Vlack - Elements of Materials Science and Engineering, 6th Edition -Reprint, Addison-Wesley, 1998.
2. H. Iabch and H. Luth - Solid State Physics: An introduction to Principles of Material Science, 2nd Edition,
Springer, 2001.
3. B.B. Laud - Lasers and Non linear optics, Wiley Eastern Ltd, 1991.
4. Verdayan J.J. - Laser Electronics - Prentice-Hall India, New Delhi, 1993.
5. Allen and Jones - Principles of Gas Lasers - Butterworths, London, 1967.
6. K.R. Nambiar - Laser Principles, Types and Application - New Age International, 2004.
7. K. Thyagarajan and A.K. Ghatak - Laser Theory and Applications - Macmillan India Ltd., 1997.
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  1
Text Books
4
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  7
Syllabus  Unit-1  Phase Diagram
5
 Hume  Rothery electron compounds
 Long range order theory of Bragg and
Williams
 Super lattices
 Interstitial phase
 Intermetallic compounds
 Elementary Ideas of corrosion
 Oxidation
 Creep and fracture
 Phase diagram
 Basic principles
 Simple binary systems
 Solid solutions
 Eutectic systems
 Application
 Solid solution
 Interstitial and substitution solid
solutions
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  1
Lecture Content
6
 Introduction to Material Science
 Classification of Materials
 Properties of Materials
 Phase diagram
 Basic principles
 Simple binary systems
Material
Science
Metals
Polymers
Ceramics
Composites
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  1
Classification of Materials
7
Metals
Ferrous Alloys
Steel
Cast Irons
Aluminum
Alloys
Al-Cu
Al-Mg
Copper Alloys
Brass  Cu-Zn
Bronze  Cu-Sn
Ceramics
Engineering
Ceramics
Barium
Titanate
PZT
Traditional
Ceramics
Stone
Porcelain
Polymers
Thermosets
Metaline
Formaldehyde
Polymides
Thermoplastics
Polypropylene
Polyethylene
Nylon
Elastomers
Nitrle Rubber
Silicone Rubber
Composites
Metal Matrix
Composites
Tungsten-
Carbide cobolt
Polymer Matrix
Composites
Carbon-Fibre
Reinforced Plastics
Ceramic Matrix
Composites
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  1
Properties of Materials
8
Properties
of
Materials
Mechanical
properties
Electrical
properties
Dielectric
properties
Magnetic
properties
Optical
properties
Corrosion
properties
Biological
properties
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  1
Properties of Materials
9
Mechanical properties
A. Elasticity and stiffness (recoverable stress vs. strain)
B. Ductility (non-recoverable stress vs. strain)
C. Strength
D. Hardness
E. Brittleness
F. Toughness
E. Fatigue
F. Creep
Dielectric properties
A. Polarizability
B. Capacitance
C. Ferroelectric properties
D. Piezoelectric properties
E. Pyroelectric properties
Electrical properties
A. Electrical conductivity and resistivity
Magnetic properties
A. Paramagnetic properties
B. Diamagnetic properties
C. Ferromagnetic properties
Optical properties
A. Refractive index
B. Absorption, reflection, and transmission
C. Birefringence (double refraction)
Corrosion properties
Biological properties
A. Toxicity
B. bio-compatibility
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  1
Phase Diagram
10
A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to
show conditions (pressure, temperature, volume, etc.) at which thermodynamically distinct phases (such as solid,
liquid or gaseous states) occur and coexist at equilibrium.
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  1
Types of Phase Diagram  2D & 3D
11
Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture  1
Gibbs Phase Rule
12
F = C  P + N
F - Degrees of freedom (No. of independent variables available to the system)
C - No. of components
P - No. of phases
N - No. of non-compositional variables (e.g.pressure & temperature)
F = C  P + 2
For routine processing of materials, we can consider the pressure to be fixed at 1atm:
F = C  P + 1
Thank You
13

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MS_Unit-1_Lecture-1_Introduction .pdf

  • 1. Lecture 1 07-Dec-2020 Unit - 1 Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore 1 Material Science Course Introduction
  • 2. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 1 Syllabus Material Science 2 Unit I: Phase Diagram Phase diagram Basic principles Simple binary systems Solid solutions Eutectic systems- Application - Solid solution Interstitial and substitution solid solutions Hume Rothery electron compounds Long range order theory of Bragg and Williams Super lattices Interstitial phase Intermetallic compounds - Elementary Ideas of corrosion Oxidation Creep and fracture Unit II: Defects Point defects Scottky and Frenkel defects Number of defects as a function of temperature Diffusion in metals Diffusion and Ionic conductivity in Ionic crystals -Dislocations Edge and screw dislocations Burgers vector Plastic deformation Slip Motion of dislocations under uniform Shear Stress - Stress fields around dislocations Density Work hardening Effect of grain size on dislocation motion Effect of solute atoms on dislocation motion. Unit III: Optical Properties, Dielectric Properties and Ferro Electrics Color centers Photo conductivity Electronic transitions in Photo conductors Trap, capture, recombination centers Luminescence - Excitation and emission Decay mechanisms Thallium activated alkali halides Sulfide phosphorous - Ferroelectrics Ferro electricity General properties Dipole theory Ionic displacements and the behaviour of BaTiO3 Spontaneous polarization of BaTiO3 Thermodynamics of Ferro electric transitions. Unit IV: Elastic Behaviour, Polymer and Ceramics An elastic and visco elastic behaviour - Atomic model of elastic behaviour - rubber like elasticity - An elastic deformation - Relaxation process - Model for visco elastic behaviour - Polymers - Polymerization mechanism - Polymer structures - Deformation of polymers - Behaviour of polymers - Ceramics - Ceramic phases - Structure - classes - Effect of structure on the behaviour of ceramic phases - composites. Unit V: Laser Physics Introduction Interaction of radiation with matter - Spontaneous and stimulated emission Conditions for oscillation to occur Frequency of oscillation of the system Einstein co-efficient Population inversion - Laser pumping Rate equations - Three level laser - Four level Laser Nd:YAG Laser He-Ne Laser - Optical resonator Types and modes of resonator Oscillation - Threshold condition The confocal resonant cavity Theory Spot size and beam divergence - quality factor (Q) of an optical cavity.
  • 3. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 1 Text & Reference Books 3 Text Books 1. G.K. Narula, K.S. Narula and V.K. Gupta - Material Science, TMH, New Delhi, 1995. 2. A.J. Dekker - Solid State Physics - McMillan Co., 1981. 3. V. Ragavan - Material Science and Engineering, 4th Edition - Prentice Hall of India, New Delhi, 2003. 4. M. Arumugam - Materials Science, 3rd Edition - Anuradha Agencies, 2002. Books for Reference: 1. Lawrence H. Vlack - Elements of Materials Science and Engineering, 6th Edition -Reprint, Addison-Wesley, 1998. 2. H. Iabch and H. Luth - Solid State Physics: An introduction to Principles of Material Science, 2nd Edition, Springer, 2001. 3. B.B. Laud - Lasers and Non linear optics, Wiley Eastern Ltd, 1991. 4. Verdayan J.J. - Laser Electronics - Prentice-Hall India, New Delhi, 1993. 5. Allen and Jones - Principles of Gas Lasers - Butterworths, London, 1967. 6. K.R. Nambiar - Laser Principles, Types and Application - New Age International, 2004. 7. K. Thyagarajan and A.K. Ghatak - Laser Theory and Applications - Macmillan India Ltd., 1997.
  • 4. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 1 Text Books 4
  • 5. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 7 Syllabus Unit-1 Phase Diagram 5 Hume Rothery electron compounds Long range order theory of Bragg and Williams Super lattices Interstitial phase Intermetallic compounds Elementary Ideas of corrosion Oxidation Creep and fracture Phase diagram Basic principles Simple binary systems Solid solutions Eutectic systems Application Solid solution Interstitial and substitution solid solutions
  • 6. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 1 Lecture Content 6 Introduction to Material Science Classification of Materials Properties of Materials Phase diagram Basic principles Simple binary systems Material Science Metals Polymers Ceramics Composites
  • 7. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 1 Classification of Materials 7 Metals Ferrous Alloys Steel Cast Irons Aluminum Alloys Al-Cu Al-Mg Copper Alloys Brass Cu-Zn Bronze Cu-Sn Ceramics Engineering Ceramics Barium Titanate PZT Traditional Ceramics Stone Porcelain Polymers Thermosets Metaline Formaldehyde Polymides Thermoplastics Polypropylene Polyethylene Nylon Elastomers Nitrle Rubber Silicone Rubber Composites Metal Matrix Composites Tungsten- Carbide cobolt Polymer Matrix Composites Carbon-Fibre Reinforced Plastics Ceramic Matrix Composites
  • 8. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 1 Properties of Materials 8 Properties of Materials Mechanical properties Electrical properties Dielectric properties Magnetic properties Optical properties Corrosion properties Biological properties
  • 9. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 1 Properties of Materials 9 Mechanical properties A. Elasticity and stiffness (recoverable stress vs. strain) B. Ductility (non-recoverable stress vs. strain) C. Strength D. Hardness E. Brittleness F. Toughness E. Fatigue F. Creep Dielectric properties A. Polarizability B. Capacitance C. Ferroelectric properties D. Piezoelectric properties E. Pyroelectric properties Electrical properties A. Electrical conductivity and resistivity Magnetic properties A. Paramagnetic properties B. Diamagnetic properties C. Ferromagnetic properties Optical properties A. Refractive index B. Absorption, reflection, and transmission C. Birefringence (double refraction) Corrosion properties Biological properties A. Toxicity B. bio-compatibility
  • 10. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 1 Phase Diagram 10 A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, volume, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium.
  • 11. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 1 Types of Phase Diagram 2D & 3D 11
  • 12. Dr. R. Sarjila, Dept. of Physics, Auxilium College, Vellore Lecture 1 Gibbs Phase Rule 12 F = C P + N F - Degrees of freedom (No. of independent variables available to the system) C - No. of components P - No. of phases N - No. of non-compositional variables (e.g.pressure & temperature) F = C P + 2 For routine processing of materials, we can consider the pressure to be fixed at 1atm: F = C P + 1