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Chemical Names
and Formulas
Overview
Metals and Non-Metals
Ions and Ionic Charges
Types of Compounds
Systematic Names
-Writing Names and Formulas
Which side is ionic/covalent?
Objectives:
 Identify Ionic and Covalent Compound.
 Describe binary and ternary compound.
 Name and write chemical formula.
* Ionic Compound
* Covalent Compound
Identify Ionic and Covalent Compond
P4O6
LiSO4
CCl4
Al3C4
BaF2
CO2
PbSO4
NH3
LiCl
CdS
Cl2O7
Na2O
P4O6
XeF4
SO3
NaOH
Cr2(SO4)3
K3PO4
Ca(NO3)2
IF5
NCl3
CO2
H2O
AgHCO3
Binary
Ionic Covalent
Ternary
How will you describe a ternary
compound?
Naming Compounds
 General Information
 Binary Ionic Compounds
 Ternary Ionic Compounds/Poly-atomic
Ions
 Naming w/metals that have more than 1
charge (Transition Metals)
 Molecular Compounds
Metals and Nonmetals
 Stairway Of Division on Periodic Table
 C, P, Se, I, Rn and to the right are non-
metals
 B, Si, As, Ge, Sb, Te, Po, At are semi-
metals
 All others are metals
Ions
 Cations
 Positively
Charged
Atoms
 i.e. Na
+
 Anions
 Negatively
Charged
Atoms
 i.e. Cl
-
Naming-Ionic-and-Covalent-Compound-NEW-VERSION.pptx
IONIC CHARGES
 Group I ->
 Group II ->
 Group III ->
 Group IV ->
1+
2+
3+
4+
IONIC CHARGES
 Group V ->
 Group VI ->
 Group VII ->
 Group VIII ->
3-
2-
1-
Noble Gases
Ionic Compounds
 composed of positive and
negative ions.
 usually formed from a metal
and non-metal.
 these elements are not
attached
to one another.
TYPES OF COMPOUNDS
Ionic Compounds cont
 Examples
NaCl
CaBr2
KI
 Definition
 shows the kind and numbers
of atoms in the
smallest representative unit
of the substance.
 i. e.
NaCl
 A formula unit is the lowest
whole number ratio of ions in
an ionic compound.
 i.e. Na2Cl2 -> NaCl
 There is no such thing as a
molecule of NaCl!!!!!!!!!
 If charges cancel, just write the symbols
Na+1 Cl-1 NaCl
 If charges do not cancel, criss-cross:
Ca+2 Cl-1 CaCl2
***Do not move the charge, only the
number
***Do not write the 1
NAMING COMPOUNDS
 Your ability to name
compounds and write
formulas hinges on your
ability to recognize whether a
compound is Ionic or
Covalent.
BINARY IONIC COMPOUNDS
 Binary means 2 elements
 Ionic means a metal and a
non-metal (or cation and
anion)
 Writing Formulas
 charges must balance so
compound charge is
neutral.
BINARY IONIC COMPOUNDS
Writing Formulas from
Names
 1st word = CATION
 2nd word = ANION name
with ide ending.
BINARY IONIC COMPOUNDS
 NaBr
 MgF2
Sodium
Bromide
Magnesium
Fluoride
BINARY IONIC COMPOUNDS
 Potassium
Chloride
 Aluminum
Oxide
 notice
ending of
name is ide!
K+Cl- -> KCl
Al2
3+O3
2- ->
Al2O3
Polyatomic Ions
Definition
tightly bound groups of
atoms that behave as a unit
and carry a charge.
Example
SO3
2-
, NO2
-, ClO2
-
Naming-Ionic-and-Covalent-Compound-NEW-VERSION.pptx
TERNARY IONIC COMPOUNDS
Ternary means 3 different
elements
Usually contain Poly-atomic
Ions
Ionic means cation and
anion
Ca2+CO3
2-
CaCO3
Charges canceled.
Just write the symbols
Calcium
carbonate
TERNARY IONIC
COMPOUNDS: Naming
Calcium
Nitrate
Notice the charges didnt
cancel so they criss
crossed
Ca+2 (NO3)-1
Ca(NO3)2
Naming with Transition Metals
 First word = CATION
 Second word = ANION
The Roman numeral will tell you the
charge of the transition metal
Silver (Ag) is an exception. Its
charge is +1
Elements with more than one oxidation
state.
Naming Transition Metals
Copper (I)
Oxide
Cu+1 O-
2
Cu2O
Writing Formulas with Transition
Metals
FeCl3
Fe+3 Cl-1
FeCl2
Fe+2 Cl-1
Iron (III)
Chloride
Iron (II)
Chloride
*Backwards criss-cross to know the charge/Roman numeral
TYPES OF COMPOUNDS
 Covalent/Molecular Compounds
 composed of molecules in
which elements share
electrons.
 usually composed of 2
nonmetals.
 these elements are attached
MOLECULAR FORMULA
 Definition
 shows the numbers and
kinds of atoms present in a
molecule of a compound.
 i. e.
CO
TYPES OF COMPOUNDS
 Molecular Compounds cont
Examples
CS2
SiO2
BF3
BINARY MOLECULAR
COMPOUNDS
Binary means 2 elements
Molecular means 2 non-
metals
NO ionic charges are
present
Naming Binary
Covalent/Molecular
Compounds
Prefixes are used to show how
many atoms are present in
each molecule.
Covalent Prefixes
 Mono (or no
prefix)  1
 Di  2
 Tri  3
 Tetra  4
 Penta  5
 Hexa  6
 Hepta  7
 Octa  8
 Nona  9
 Deca  10
Writing Binary Molecular
Compounds
CO2
no mono
prefix is used on
first element
Carbon
Dioxide
 Di means 2
oxygens!!
Naming Binary Molecular
Compounds
2 ways its done!
 (prefix + element name)
i.e. N2O
dinitrogen monoxide
Naming Binary Molecular
Compounds
 (prefix + element root + ide)
i.e. PCl3
Phosphorous
Trichloride
All binary compounds end in
ide!!!

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Naming-Ionic-and-Covalent-Compound-NEW-VERSION.pptx