Nitric acid
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Nitric acid is a colorless liquid that is highly corrosive. It was first discovered in the 13th century and was known as aqua fortis. Nitric acid can be produced via the sodium nitrate process or by oxidizing ammonia. It is commonly used to make fertilizers and as a cleaning agent. While useful, nitric acid must be handled with care due to its corrosive nature.
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Nitric acid
- 1. NITRIC ACID V PAVAN KUMAR Dept of Chemical Engineering, AP-IIIT, Idupulapaya FEB 3, 2016 V PAVAN KUMAR HNO3
- 2. Contents Introductio HISTORY PROPERTIES METHODES OF PREPARATION APPLICATION SAFETY V PAVAN KUMAR HNO3
- 3. Introduction V PAVAN KUMAR HNO3
- 4. HISTORY Nitric acid 鍖rst descovered by Albert and Ramon Lull in the 13th century Nitrogen compounds are well known in middle ages. In olden days nitricacid called as aqua fortis. Earlier nitric and hydrochloric acids known as aquaregia,which has ability to dissolve gold. From these things our elders came to know that nitricacid have some useful applications in world. V PAVAN KUMAR HNO3
- 5. PROPERTIES PROPERTIES Mol. Wt. : 63.03 MP: -42 oC BP: 86 oC with decomposition Completely miscible with water Forms a constant boiling mixture at 11o oC and 760 mm of Hg, which contains 68 wt.% HNO3. Grades: Concentrated (95%), Fuming ( 86%), Redfuming( 95%with10 15%excessoxidesofnitrogen), nitrating(50 80%HNO3a15 48%H2SO4) V PAVAN KUMAR HNO3
- 6. METHODES OF PREPARATION METHODES OF PREPARATION NaNO3 + H2SO4 process Ammonia oxidation process N2 鍖xation from air (Wisconsin process) Nitrogen 鍖xation by nuclear 鍖ssion fragments V PAVAN KUMAR HNO3
- 7. AMMONIA OXIDATION PROCESS V PAVAN KUMAR HNO3
- 8. BLOCK DIAGRAM V PAVAN KUMAR HNO3
- 9. CHALLENGES NO formation at high temp but NO2 from No at low temperatures Reaction rate is directly proportional to: -Low temp -High pressure (for catalyst ) -NO2 concentration in gaseous phase Reaction kinetics is favored for high temperature and pressure, good catalyst V PAVAN KUMAR HNO3
- 10. APPLICATIONS Precursor to organic nitrogen compounds Nitric acid is used for making fertilizer such as ammonium nitrate. It can be used as cleaning agent V PAVAN KUMAR HNO3
- 11. continue Precursor Nitric acid has been used as oxidizer in liquid fueled rockets. V PAVAN KUMAR HNO3
- 12. safety Nitric acid is higly corossive in nature. will decompose the tissue such as skin,fat. V PAVAN KUMAR HNO3
- 13. THE END THANK YOU V PAVAN KUMAR HNO3