際際滷

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Progress meeting
24 February 2023
True performance grade trial
65.7
72.0
104.7
79.8 82.4 85.6
0
40
80
120
Vir. Binder RTFO RAB UV-aging USAT-Yinhong USAT-Deiza
Temperature
(属C)
Aging condition
G*/sin隆 = 1 kPa
Mastercurve @64属C complex modulus due to aging
1.E+01
1.E+03
1.E+05
1.E+07
1.E-03 1.E-02 1.E-01 1.E+00 1.E+01 1.E+02 1.E+03
|G*|
(Pa)
Frequency (Hz)
Vir. Binder
RAB
UV-aging
USAT-Yinghong
USAT-Deiza
RTFO
Mastercurve @64属C Phase angle due to aging
45
60
75
90
1.E-03 1.E-02 1.E-01 1.E+00 1.E+01 1.E+02 1.E+03
隆(属)
Frequency (Hz)
Vir. Binder
RAB
UV-aging
USAT-Yinghong
USAT-Deiza
RTFO
Mastercurve @64属C Complex modulus WCO effect
1.E+01
1.E+03
1.E+05
1.E+07
1.E-03 1.E-01 1.E+01 1.E+03
|G*|
(Pa)
Frequency (Hz)
Vir. Binder
RAB
8% Bio-diesel
30% Glyccerol
Mastercurve @64属C Phase angle WCO effect
45
60
75
90
1.E-03 1.E-01 1.E+01 1.E+03
隆
(属)
Frequency (Hz)
Vir. Binder
RAB
8% Bio-diesel
30% Glyccerol
Mastercurve @64属C Complex modulus Bio diesel effect
1.E+01
1.E+03
1.E+05
1.E+07
1.E-03 1.E-01 1.E+01 1.E+03
|G*|
(Pa)
Frequency (Hz)
Vir. Binder
RAB
8% Bio-diesel
6% Bio-diesel
4% Bio-diesel
Mastercurve @64属C Phase angle Bio-diesel effect
45
60
75
90
1.E-03 1.E-01 1.E+01 1.E+03
隆(属)
Frequency (Hz)
Vir. Binder
RAB
8% Bio-diesel
6% Bio-diesel
4% Bio-diesel
Mastercurve @64属C Complex modulus Glycerol effect
1.E+00
1.E+02
1.E+04
1.E+06
1.E-03 1.E-01 1.E+01 1.E+03
|G*|
(Pa)
Frequency (Hz)
Vir. Binder
RAB
20% Glycerol
25% Glycerol
30% Glyccerol
40% Glycerol
Mastercurve @64属C Phase angle Glycerol effect
45
60
75
90
1.E-03 1.E-01 1.E+01 1.E+03
隆
(属)
Frequency (Hz)
Vir. Binder
RAB
20% Glycerol
25% Glycerol
30% Glyccerol
40% Glycerol
67.3
104.7
81.2 78.6
69.1
77.3 74.0 70.8
64.8
0
40
80
120
Temperature
(属C)
Samples
G*/sin隆 = 1 kPa
Proposed experimental plan (1)
RAB
Materials Bio-Rejuvenator (BR)
Find the best WCO upgraded product that can
bring RAB properties comparable to AC-20
Phase 1
WCO upgraded
product selection
AC-20
(Control)
WCO
BD
GL
Rheology test
- Freq. Sweep
- LAS
- MSCR
Chemical test
- GPC
- FTIR
Proposed experimental plan (2)
RAB
Materials
RABL+x%BR
Find the appropriate proportion of BR based on
aging level
Phase 2
BR proportion
investigation
BR
BRL
RABH
Rheology test
- Freq. Sweep
- LAS
- MSCR
Chemical test
- GPC
- FTIR
BRM
RABL
BRH
RABH+y%BR
Blending
proportion
Proposed experimental plan (3)
Materials
Evaluate the resistant of BR due to aging
Phase 3
BR resistant to
re-aging
Rheology test
- Freq. Sweep
- LAS
- MSCR
Chemical test
- GPC
- FTIR
Rejuvenated
RAB
performance
after Re-Aging
RABL+x%BR
RABH+y%BR
Short-term
aging
Long-term
aging

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  • 2. True performance grade trial 65.7 72.0 104.7 79.8 82.4 85.6 0 40 80 120 Vir. Binder RTFO RAB UV-aging USAT-Yinhong USAT-Deiza Temperature (属C) Aging condition G*/sin隆 = 1 kPa
  • 3. Mastercurve @64属C complex modulus due to aging 1.E+01 1.E+03 1.E+05 1.E+07 1.E-03 1.E-02 1.E-01 1.E+00 1.E+01 1.E+02 1.E+03 |G*| (Pa) Frequency (Hz) Vir. Binder RAB UV-aging USAT-Yinghong USAT-Deiza RTFO
  • 4. Mastercurve @64属C Phase angle due to aging 45 60 75 90 1.E-03 1.E-02 1.E-01 1.E+00 1.E+01 1.E+02 1.E+03 隆(属) Frequency (Hz) Vir. Binder RAB UV-aging USAT-Yinghong USAT-Deiza RTFO
  • 5. Mastercurve @64属C Complex modulus WCO effect 1.E+01 1.E+03 1.E+05 1.E+07 1.E-03 1.E-01 1.E+01 1.E+03 |G*| (Pa) Frequency (Hz) Vir. Binder RAB 8% Bio-diesel 30% Glyccerol
  • 6. Mastercurve @64属C Phase angle WCO effect 45 60 75 90 1.E-03 1.E-01 1.E+01 1.E+03 隆 (属) Frequency (Hz) Vir. Binder RAB 8% Bio-diesel 30% Glyccerol
  • 7. Mastercurve @64属C Complex modulus Bio diesel effect 1.E+01 1.E+03 1.E+05 1.E+07 1.E-03 1.E-01 1.E+01 1.E+03 |G*| (Pa) Frequency (Hz) Vir. Binder RAB 8% Bio-diesel 6% Bio-diesel 4% Bio-diesel
  • 8. Mastercurve @64属C Phase angle Bio-diesel effect 45 60 75 90 1.E-03 1.E-01 1.E+01 1.E+03 隆(属) Frequency (Hz) Vir. Binder RAB 8% Bio-diesel 6% Bio-diesel 4% Bio-diesel
  • 9. Mastercurve @64属C Complex modulus Glycerol effect 1.E+00 1.E+02 1.E+04 1.E+06 1.E-03 1.E-01 1.E+01 1.E+03 |G*| (Pa) Frequency (Hz) Vir. Binder RAB 20% Glycerol 25% Glycerol 30% Glyccerol 40% Glycerol
  • 10. Mastercurve @64属C Phase angle Glycerol effect 45 60 75 90 1.E-03 1.E-01 1.E+01 1.E+03 隆 (属) Frequency (Hz) Vir. Binder RAB 20% Glycerol 25% Glycerol 30% Glyccerol 40% Glycerol
  • 11. 67.3 104.7 81.2 78.6 69.1 77.3 74.0 70.8 64.8 0 40 80 120 Temperature (属C) Samples G*/sin隆 = 1 kPa
  • 12. Proposed experimental plan (1) RAB Materials Bio-Rejuvenator (BR) Find the best WCO upgraded product that can bring RAB properties comparable to AC-20 Phase 1 WCO upgraded product selection AC-20 (Control) WCO BD GL Rheology test - Freq. Sweep - LAS - MSCR Chemical test - GPC - FTIR
  • 13. Proposed experimental plan (2) RAB Materials RABL+x%BR Find the appropriate proportion of BR based on aging level Phase 2 BR proportion investigation BR BRL RABH Rheology test - Freq. Sweep - LAS - MSCR Chemical test - GPC - FTIR BRM RABL BRH RABH+y%BR Blending proportion
  • 14. Proposed experimental plan (3) Materials Evaluate the resistant of BR due to aging Phase 3 BR resistant to re-aging Rheology test - Freq. Sweep - LAS - MSCR Chemical test - GPC - FTIR Rejuvenated RAB performance after Re-Aging RABL+x%BR RABH+y%BR Short-term aging Long-term aging