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STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR NITRITE ION
(a)?On treating a solid nitrite with dil. H SO? ? ?
? ? and warming , reddish brown?fumes of NO?
? ? gas are evolved.
2 4
2
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR NITRITE ION
Addition of potassium iodide solution to?the
salt solution followed by freshly prepared
starch solution and?acidification with acetic
acid produces blue colour.
(b)
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR NITRITE ION
On adding sulphanilic acid & 1-naphthylamine?
reagent to the water?extract or acidified with
acetic acid, a red azo-dye is?formed.?
(c)
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR NITRITE ION
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR SULPHIDE ION
With warm dilute H SO? ?a sulphide gives
hydrogen sulphide gas which?smells like
rotten eggs.
(a) 2 4
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR SULPHIDE ION
A piece of filter paper dipped in lead acetate
solution turns black on exposure to the gas
due to the formation of?lead sulphide which
is black in colour.
(b)
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR SULPHIDE ION
Solution of saltin water/sodium carbonate
extract, make it?alkaline with ammonium
hydroxide and add sodium nitroprusside
solution. ?Purple or violet colour is obtained.
(c)
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST OF SULPHATE ION
On addition of barium chloride to the
Aqueous solution or sodium carbonate
extract of the salt acidified with?acetic
acid?gives a white precipitate
(a)
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST OF SULPHATE ION
Sulphate ions give white precipitate of lead
sulphate when aqueous?solution or sodium
carbonate extract neutralised with acetic
acid is?treated with lead acetate solution.
(b)
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR CHLORIDE ION
On treatment with warm conc. H ?SO ? the
salt gives a colourless gas with pungent
smell and the gas gives dense white fumes
with ammonia solution,?
(a) 2 4
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR CHLORIDE ION
Salt gives effervescence on heating with
conc. H? SO? ?and MnO? ?and?a light greenish
yellow pungent gas is evolved.
(b)
2 4 2
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR CHLORIDE ION
On addition of silver nitrate?solution to a Salt
solution acidified with dilute HNO???gives a
curdy white precipitate soluble in
ammonium hydroxide?solution.?
(c)
3
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR CHLORIDE ION
Chromyl chloride test(d)
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR BROMIDE ION
On heating the salt with conc. H? SO?
reddish brown fumes of bromine are?
evolved. The fumes get intensified?on
addition of MnO? .?
(a) 2 4
2
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR BROMIDE ION
?The appearance of an orange brown
colouration in the?organic layer on addition
of chloroform & freshly prepared Cl? ?water
dropwise to the salt solution
(b)
2
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR BROMIDE ION
A pale yellow?precipitate is obtained upon
addition of silver nitrate (AgNO? ) solution to
the acidified (dil. HNO? ) sodium carbonate
extract of the salt.?
(c)
3
3
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR IODIDE ION
Deep violet vapours with a?pungent smell
are evolved,?on heating the salt with conc.
H? SO? . These turns starch paper blue and a
violet?sublimate is formed on the sides of
the test tube.
(a)
2 4
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR IODIDE ION
Violet colouration in the?organic layer is
obtained upon addition of CCl? ?and chlorine
water in excess to the salt?solution
(b)
4
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
TEST FOR IODIDE ION
Appearance of a yellow precipitate insoluble
in excess of NH? OH upon addition of AgNO
solution to acidified sodium carbonate
extract of the salt with dil.HNO
(c)
4
3
3
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
SEPARATION OF CATIONS
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
SEPARATION OF?CATIONS
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
GROUP REAGENTS FOR
PRECIPITATING IONS
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
ANALYSIS OF GROUP-I CATIONS
Dissolve the precipitate in hot water and divide
the hot solution into three parts.
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
ANALYSIS OF GROUP¨CII CATIONS
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
ANALYSIS OF GROUP¨CIII CATIONS
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
ANALYSIS OF GROUP¨CIV?CATIONS
STUDYDUNIYA
The Educational Social Network
C H E M I S T R Y - I N O R G A N I C -
Q U A L I T A T I V E A N A L Y S I S
IIT JEE @studyduniya +91 7744994714
ANALYSIS OF GROUP¨CV?CATIONS

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  • 1. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR NITRITE ION (a)?On treating a solid nitrite with dil. H SO? ? ? ? ? and warming , reddish brown?fumes of NO? ? ? gas are evolved. 2 4 2
  • 2. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR NITRITE ION Addition of potassium iodide solution to?the salt solution followed by freshly prepared starch solution and?acidification with acetic acid produces blue colour. (b)
  • 3. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR NITRITE ION On adding sulphanilic acid & 1-naphthylamine? reagent to the water?extract or acidified with acetic acid, a red azo-dye is?formed.? (c)
  • 4. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR NITRITE ION
  • 5. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR SULPHIDE ION With warm dilute H SO? ?a sulphide gives hydrogen sulphide gas which?smells like rotten eggs. (a) 2 4
  • 6. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR SULPHIDE ION A piece of filter paper dipped in lead acetate solution turns black on exposure to the gas due to the formation of?lead sulphide which is black in colour. (b)
  • 7. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR SULPHIDE ION Solution of saltin water/sodium carbonate extract, make it?alkaline with ammonium hydroxide and add sodium nitroprusside solution. ?Purple or violet colour is obtained. (c)
  • 8. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST OF SULPHATE ION On addition of barium chloride to the Aqueous solution or sodium carbonate extract of the salt acidified with?acetic acid?gives a white precipitate (a)
  • 9. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST OF SULPHATE ION Sulphate ions give white precipitate of lead sulphate when aqueous?solution or sodium carbonate extract neutralised with acetic acid is?treated with lead acetate solution. (b)
  • 10. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR CHLORIDE ION On treatment with warm conc. H ?SO ? the salt gives a colourless gas with pungent smell and the gas gives dense white fumes with ammonia solution,? (a) 2 4
  • 11. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR CHLORIDE ION Salt gives effervescence on heating with conc. H? SO? ?and MnO? ?and?a light greenish yellow pungent gas is evolved. (b) 2 4 2
  • 12. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR CHLORIDE ION On addition of silver nitrate?solution to a Salt solution acidified with dilute HNO???gives a curdy white precipitate soluble in ammonium hydroxide?solution.? (c) 3
  • 13. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR CHLORIDE ION Chromyl chloride test(d)
  • 14. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR BROMIDE ION On heating the salt with conc. H? SO? reddish brown fumes of bromine are? evolved. The fumes get intensified?on addition of MnO? .? (a) 2 4 2
  • 15. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR BROMIDE ION ?The appearance of an orange brown colouration in the?organic layer on addition of chloroform & freshly prepared Cl? ?water dropwise to the salt solution (b) 2
  • 16. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR BROMIDE ION A pale yellow?precipitate is obtained upon addition of silver nitrate (AgNO? ) solution to the acidified (dil. HNO? ) sodium carbonate extract of the salt.? (c) 3 3
  • 17. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR IODIDE ION Deep violet vapours with a?pungent smell are evolved,?on heating the salt with conc. H? SO? . These turns starch paper blue and a violet?sublimate is formed on the sides of the test tube. (a) 2 4
  • 18. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR IODIDE ION Violet colouration in the?organic layer is obtained upon addition of CCl? ?and chlorine water in excess to the salt?solution (b) 4
  • 19. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 TEST FOR IODIDE ION Appearance of a yellow precipitate insoluble in excess of NH? OH upon addition of AgNO solution to acidified sodium carbonate extract of the salt with dil.HNO (c) 4 3 3
  • 20. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 SEPARATION OF CATIONS
  • 21. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 SEPARATION OF?CATIONS
  • 22. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 GROUP REAGENTS FOR PRECIPITATING IONS
  • 23. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 ANALYSIS OF GROUP-I CATIONS Dissolve the precipitate in hot water and divide the hot solution into three parts.
  • 24. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 ANALYSIS OF GROUP¨CII CATIONS
  • 25. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 ANALYSIS OF GROUP¨CIII CATIONS
  • 26. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 ANALYSIS OF GROUP¨CIV?CATIONS
  • 27. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - I N O R G A N I C - Q U A L I T A T I V E A N A L Y S I S IIT JEE @studyduniya +91 7744994714 ANALYSIS OF GROUP¨CV?CATIONS