This document provides an overview of photovoltaics and solar energy. It discusses the history of photovoltaics from 1839 when the photovoltaic effect was discovered to recent developments. It describes the difference between the photovoltaic effect and photoelectric effect. It also explains how semiconductors are produced through doping to create P-N junctions and the different types of solar cells including thin film, polycrystalline and monocrystalline cells. The document concludes with a look at future developments in solar energy technology.
2. Overview
History of Photovoltaics
Photovoltaic effect vs. Photoelectric effect
Semiconductor production
P-N junction
Different types of PV cells and the efficiencies
A brief look at the future of solar energy
3. What is Solar Energy
and How is it used?
Radiation from sun
Earth receives ~174 petawatts (1015 watts) at the
upper atmosphere. Only ~ 47% is absorbed.
Solar panels
Photosynthesis
4. History of Photovoltaics
French scientist Edmond Becquerel discovers the
1839
photovoltaic effect
The first solid state photovoltaic cell was built by
1883
Charles Fritts
Albert Einstein published his paper on the
1905
photoelectric effect
The first practical photovoltaic was developed at Bell
1954
Laboratories
1970s Solar energy became commercialized
World record efficiency reached 44% with a
2012
multijunction cell
5. Photovoltaic Effect vs.
Photoelectric Effect
Photovoltaic Effect Photoelectric Effect
The creation of voltage or electrical The emission of electrons from a solid,
current in a material upon exposure to liquid, or gas upon exposure to light.
light.
Electrons are ejected when excess
Electrons absorb energy and become energy is absorbed.
excited.
If the photon energy is too low the
Electrons move to the conduction electrons will not be able to escape
band to become free.
6. Doping
A process first developed by John Robert
Woodyard
Doping intentionally introduces impurities into a
pure semiconductor for the purpose of
modulating its electrical properties
Group IV semiconductors such as Silicon are
used
By doping semiconductors the we are able to
form P-type and N-type semiconductors
7. P-type Semiconductor
Doped with Group III
element such as Boron
Abundance of holes or
electron deficiencies
Electrical conduction due
primarily movement of
holes
8. N-type
Semiconductor
Doped with Group V
elements such as
Phosphorous
Abundance of extra
electrons
Electrical conduction due
primarily to movement of
electrons
10. Thin-film Solar Cells
Around 8% efficiency
Very thin layers of
photovoltaic material.
The thickness is
anywhere between a
few nanometers to tens
of micrometers
Small portion of the solar
cell market
11. Polycrstalline Solar Cells
Around 14-16 %
efficiency
Uses multiple crystal to
harness the suns light.
Generally, these are
cheaper and easier to
install.
12. Monocrystalline Solar
Cells
Around 16-19 %
efficiency
Made from a single
crystal cell
Generally, these are the
most popular and most
efficient cells on the
market.
13. Multijunction Cells
Efficiencies up to 44 %
Not available on the market. Only used experimentally in a lab
setting.
Cells are used in tandem to gain better efficiencies
15. Solar Cell Diagram
Each cell produces 0.5 Volts
Cells are connected in series
of 18 Volts, which
creates a module of 36 cells
A photovoltaic system needs
an array of cells, charge
controller, battery system, an
inverter, and wires to connect
the system
16. Future for Solar Energy
Over the last 20 years, prices have
dropped significantly
Clean renewable energy
Production has increase
exponentially
Dye-sensitized solar cell (DCS)
technology
Many other examples
17. References
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Marti, Antonio, and A. Luque. "Thermodynamics of Solar Energy Conversion. Next Generation
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Physics, 2004. SciFinder. Web. 19 Mar. 2013.
Miessler, Gary L., and Donald A. Tarr. The Crystalline Solid State. Inorganic Chemistry. 4th ed.
Upper Saddle River, NJ: Pearson Prentice Hall, 2011. 238-239. Print.
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CA; 1987
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Zyga, Lisa. Solar Thermal Process Produces Cement with No Carbon Dioxide Emissions. Science
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