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STUDYDUNIYA
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S O L U T I O N S
IIT JEE @studyduniya +91 7744994714
Solubility of a substance is its maximum
amount that can be dissolvedin a specified
amount of solvent at a specified temperature.
It dependsupon the nature of solute and
solvent as well as temperature andpressure.
SOLUBILITY
STUDYDUNIYA
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IIT JEE @studyduniya +91 7744994714
The law states thatat a constant
temperature, thesolubility of a gas in a
liquidis directly proportional to thepartial
pressure of the gaspresent above the
surface ofliquid or solution.
HENRYS LAW
STUDYDUNIYA
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For a solution of volatile liquids, the partial
vapour pressure of each component of the
solutionis directly proportional to its mole
fraction present in solution.
RAOULTSLAW
STUDYDUNIYA
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VAPOUR PRESSURE OF LIQUID-
LIQUIDSOLUTIONS
STUDYDUNIYA
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IIT JEE @studyduniya +91 7744994714
For a solution of volatile liquids, the partial
vapour pressure of each component of the
solutionis directly proportional to its mole
fraction present in solution.
IDEAL SOLUTION
STUDYDUNIYA
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IIT JEE @studyduniya +91 7744994714
When a solution does not obey Raoults
law over the entire range of concentration,
then it is called non-ideal solution.
The vapour pressureof such a solution is
either higher or lower than that predicted
byRaoults law
NON IDEALSOLUTION
STUDYDUNIYA
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When the vapour pressure of a solution is
higher than that predicted by Raoult's law,
thesolution exhibits positivedeviation and
if it is lower, it exhibits negative deviation
from Raoultslaw.
DEVIATION FROM RAOULT'S LAW
STUDYDUNIYA
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The intermolecular attractive forces
between the solute-solvent molecules
are weaker than those between the solute-
solute and solvent-solventmolecules.
POSITIVE DEVIATION
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POSITIVE DEVIATION
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The intermolecular attractive forces
between thesolute-solute and solvent-
solvent molecules are weaker than those
betweenthe solute-solventmolecules.
NEGATIVE DEVIATION
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NEGATIVE DEVIATION
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Azeotropes are binary mixtureshaving the
same composition in liquid and vapour
phase and boil ata constant temperature.
The solutions which show a large positive
deviation fromRaoults law form minimum
boiling azeotrope at a specific
composition.ethanol-water mixture.
AZEOTROPES
STUDYDUNIYA
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IIT JEE @studyduniya +91 7744994714
The solutions that show large negative
deviation from Raoults lawform
maximum boiling azeotrope at a specific
composition. Nitric acid and water
AZEOTROPES
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IIT JEE @studyduniya +91 7744994714
RELATIVELOWERING OF
VAPOURPRESSURE
STUDYDUNIYA
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IIT JEE @studyduniya +91 7744994714
ELEVATION OFBOILING POINT
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ELEVATION OFBOILING POINT
STUDYDUNIYA
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IIT JEE @studyduniya +91 7744994714
DEPRESSIONOF FREEZINGPOINT
STUDYDUNIYA
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DEPRESSIONOF FREEZINGPOINT
STUDYDUNIYA
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S O L U T I O N S
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The osmotic pressure of a solution is the
excess pressure that must be applied tostop
thepassage of solvent molecules through
asemipermeable membrane into the
solution.
OSMOTICPRESSURE
STUDYDUNIYA
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Two solutions having same osmotic
pressure at a giventemperature are called
isotonic solutions.
TYPES OF SOLUTIONS
Any solution with a higher osmotic
pressure than other solution, then the
solution is called Hypertonic solution
STUDYDUNIYA
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A hypotonic solution is any solution that
has a lower osmotic pressure than another
solution
TYPES OF SOLUTIONS
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When a pressure larger than theosmotic
pressure is applied to the solution side.
Then,thepure solvent flows out of the
solution through the semi-permeable
membrane. This phenomenon is called
reverse osmosis
REVERSEOSMOSIS

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Solutions for IIT JEE

  • 1. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 Solubility of a substance is its maximum amount that can be dissolvedin a specified amount of solvent at a specified temperature. It dependsupon the nature of solute and solvent as well as temperature andpressure. SOLUBILITY
  • 2. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 The law states thatat a constant temperature, thesolubility of a gas in a liquidis directly proportional to thepartial pressure of the gaspresent above the surface ofliquid or solution. HENRYS LAW
  • 3. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 For a solution of volatile liquids, the partial vapour pressure of each component of the solutionis directly proportional to its mole fraction present in solution. RAOULTSLAW
  • 4. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 VAPOUR PRESSURE OF LIQUID- LIQUIDSOLUTIONS
  • 5. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 For a solution of volatile liquids, the partial vapour pressure of each component of the solutionis directly proportional to its mole fraction present in solution. IDEAL SOLUTION
  • 6. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 When a solution does not obey Raoults law over the entire range of concentration, then it is called non-ideal solution. The vapour pressureof such a solution is either higher or lower than that predicted byRaoults law NON IDEALSOLUTION
  • 7. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 When the vapour pressure of a solution is higher than that predicted by Raoult's law, thesolution exhibits positivedeviation and if it is lower, it exhibits negative deviation from Raoultslaw. DEVIATION FROM RAOULT'S LAW
  • 8. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 The intermolecular attractive forces between the solute-solvent molecules are weaker than those between the solute- solute and solvent-solventmolecules. POSITIVE DEVIATION
  • 9. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 POSITIVE DEVIATION
  • 10. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 The intermolecular attractive forces between thesolute-solute and solvent- solvent molecules are weaker than those betweenthe solute-solventmolecules. NEGATIVE DEVIATION
  • 11. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 NEGATIVE DEVIATION
  • 12. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 Azeotropes are binary mixtureshaving the same composition in liquid and vapour phase and boil ata constant temperature. The solutions which show a large positive deviation fromRaoults law form minimum boiling azeotrope at a specific composition.ethanol-water mixture. AZEOTROPES
  • 13. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 The solutions that show large negative deviation from Raoults lawform maximum boiling azeotrope at a specific composition. Nitric acid and water AZEOTROPES
  • 14. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 RELATIVELOWERING OF VAPOURPRESSURE
  • 15. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 ELEVATION OFBOILING POINT
  • 16. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 ELEVATION OFBOILING POINT
  • 17. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 DEPRESSIONOF FREEZINGPOINT
  • 18. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 DEPRESSIONOF FREEZINGPOINT
  • 19. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 The osmotic pressure of a solution is the excess pressure that must be applied tostop thepassage of solvent molecules through asemipermeable membrane into the solution. OSMOTICPRESSURE
  • 20. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 Two solutions having same osmotic pressure at a giventemperature are called isotonic solutions. TYPES OF SOLUTIONS Any solution with a higher osmotic pressure than other solution, then the solution is called Hypertonic solution
  • 21. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 A hypotonic solution is any solution that has a lower osmotic pressure than another solution TYPES OF SOLUTIONS
  • 22. STUDYDUNIYA The Educational Social Network C H E M I S T R Y - P H Y S I C A L - S O L U T I O N S IIT JEE @studyduniya +91 7744994714 When a pressure larger than theosmotic pressure is applied to the solution side. Then,thepure solvent flows out of the solution through the semi-permeable membrane. This phenomenon is called reverse osmosis REVERSEOSMOSIS