An In-Depth Concept of Solutions For IIT JEE (CHEMISTRY) Exams.
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Solutions for IIT JEE
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Solubility of a substance is its maximum
amount that can be dissolvedin a specified
amount of solvent at a specified temperature.
It dependsupon the nature of solute and
solvent as well as temperature andpressure.
SOLUBILITY
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The law states thatat a constant
temperature, thesolubility of a gas in a
liquidis directly proportional to thepartial
pressure of the gaspresent above the
surface ofliquid or solution.
HENRYS LAW
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For a solution of volatile liquids, the partial
vapour pressure of each component of the
solutionis directly proportional to its mole
fraction present in solution.
RAOULTSLAW
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VAPOUR PRESSURE OF LIQUID-
LIQUIDSOLUTIONS
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For a solution of volatile liquids, the partial
vapour pressure of each component of the
solutionis directly proportional to its mole
fraction present in solution.
IDEAL SOLUTION
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When a solution does not obey Raoults
law over the entire range of concentration,
then it is called non-ideal solution.
The vapour pressureof such a solution is
either higher or lower than that predicted
byRaoults law
NON IDEALSOLUTION
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When the vapour pressure of a solution is
higher than that predicted by Raoult's law,
thesolution exhibits positivedeviation and
if it is lower, it exhibits negative deviation
from Raoultslaw.
DEVIATION FROM RAOULT'S LAW
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The intermolecular attractive forces
between the solute-solvent molecules
are weaker than those between the solute-
solute and solvent-solventmolecules.
POSITIVE DEVIATION
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POSITIVE DEVIATION
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The intermolecular attractive forces
between thesolute-solute and solvent-
solvent molecules are weaker than those
betweenthe solute-solventmolecules.
NEGATIVE DEVIATION
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NEGATIVE DEVIATION
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Azeotropes are binary mixtureshaving the
same composition in liquid and vapour
phase and boil ata constant temperature.
The solutions which show a large positive
deviation fromRaoults law form minimum
boiling azeotrope at a specific
composition.ethanol-water mixture.
AZEOTROPES
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The solutions that show large negative
deviation from Raoults lawform
maximum boiling azeotrope at a specific
composition. Nitric acid and water
AZEOTROPES
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RELATIVELOWERING OF
VAPOURPRESSURE
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ELEVATION OFBOILING POINT
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ELEVATION OFBOILING POINT
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DEPRESSIONOF FREEZINGPOINT
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DEPRESSIONOF FREEZINGPOINT
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The osmotic pressure of a solution is the
excess pressure that must be applied tostop
thepassage of solvent molecules through
asemipermeable membrane into the
solution.
OSMOTICPRESSURE
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Two solutions having same osmotic
pressure at a giventemperature are called
isotonic solutions.
TYPES OF SOLUTIONS
Any solution with a higher osmotic
pressure than other solution, then the
solution is called Hypertonic solution
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A hypotonic solution is any solution that
has a lower osmotic pressure than another
solution
TYPES OF SOLUTIONS
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When a pressure larger than theosmotic
pressure is applied to the solution side.
Then,thepure solvent flows out of the
solution through the semi-permeable
membrane. This phenomenon is called
reverse osmosis
REVERSEOSMOSIS