This document provides an overview and comparison of the business environments in Brazil and Chile in 2014. It finds that while Brazil has a larger economy, Chile has a fundamentally stronger environment with less risk. Both countries have transitioned to stable democracies from dictatorships and have diversified economies, with Brazil relying more on soy and Chile on copper. Chile generally has stronger institutions, less corruption, and a higher competitiveness ranking. For companies interested in these markets, the document recommends acquiring expertise through education, language learning, cultural immersion such as study abroad programs, and networking with contacts in Brazil and Chile.