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GENERAL CHEMISTRY-II (1412)
                                    S.I. # 26


1. The Solubility of an y compound in ____________can be converted to
____________. The ____________can be used to determine the____________of ions
in a solution. The ____________ of ions can be used to calculate ______. The steps
can be __________ and solubility calculated from ___Pg 741

2. Fill in the boxes below:

     (g/L)                       (mol/L)                  ions                Ksp


3. Ksp for AgI is 8.3x10-17 (appendix D) and Kf for Ag(CN)2- is 1x1021 (pg750 table
17.1) calculate the equilibrium constant for the reaction
               AgI(s) + 2CN-(aq)  Ag(CN)2-(aq) + I-(aq)




4. Define reducing agent and oxidizing agent and give their functions.




5. What is a half-reaction?




6. Define anode and cathode in terms of a voltaic cell.




7.     What is the function of a salt bridge?
8. What is emf?



9. The emf of a cell is called ______________. And when it is under standard
conditions it is called _______________. For a half-reaction, _____ is a measure of
the tendency of the reduction to occur. The value of _____ is _______ for a voltaic
cell and can be found by the equation: ___________________________________.
______________ has the most positive value for _____ and is the strongest oxidizing
agent.



10. Indicate whether the following balanced equations involve oxidation-reduction.
If they do, identify the elements that undergo changes in oxidation number.
        A. PBr3(l) + 3 H2O (l)  H3PO3(aq) + 3 HBr (aq)


         B.NaI (aq) + 3 HOCl(aq)  NaIO3 (aq) + 3 HCl (aq)


         C. 3 SO2(g) + 2 HNO3 + H2O(l)  3 H2SO4(aq) + 2 NO(g)


         D. 2 H2SO4(aq) + 2 NaBr(s)  Br2(l) + SO2(g) + Na2SO4(aq) 2 H2O (l)



11. complete and balance the half reactions and indicate whether the half is
reduction or oxidation.
       A. Mo3+  Mo(s)


         B. H2SO3(aq)  SO42-(aq)


         C. NO3-(aq)  NO(g)


         D. Mn2+(aq)  MnO2(s)


         E. Cr(OH)3(s)  CrO42- (aq)

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#26

  • 1. GENERAL CHEMISTRY-II (1412) S.I. # 26 1. The Solubility of an y compound in ____________can be converted to ____________. The ____________can be used to determine the____________of ions in a solution. The ____________ of ions can be used to calculate ______. The steps can be __________ and solubility calculated from ___Pg 741 2. Fill in the boxes below: (g/L) (mol/L) ions Ksp 3. Ksp for AgI is 8.3x10-17 (appendix D) and Kf for Ag(CN)2- is 1x1021 (pg750 table 17.1) calculate the equilibrium constant for the reaction AgI(s) + 2CN-(aq)  Ag(CN)2-(aq) + I-(aq) 4. Define reducing agent and oxidizing agent and give their functions. 5. What is a half-reaction? 6. Define anode and cathode in terms of a voltaic cell. 7. What is the function of a salt bridge?
  • 2. 8. What is emf? 9. The emf of a cell is called ______________. And when it is under standard conditions it is called _______________. For a half-reaction, _____ is a measure of the tendency of the reduction to occur. The value of _____ is _______ for a voltaic cell and can be found by the equation: ___________________________________. ______________ has the most positive value for _____ and is the strongest oxidizing agent. 10. Indicate whether the following balanced equations involve oxidation-reduction. If they do, identify the elements that undergo changes in oxidation number. A. PBr3(l) + 3 H2O (l)  H3PO3(aq) + 3 HBr (aq) B.NaI (aq) + 3 HOCl(aq)  NaIO3 (aq) + 3 HCl (aq) C. 3 SO2(g) + 2 HNO3 + H2O(l)  3 H2SO4(aq) + 2 NO(g) D. 2 H2SO4(aq) + 2 NaBr(s)  Br2(l) + SO2(g) + Na2SO4(aq) 2 H2O (l) 11. complete and balance the half reactions and indicate whether the half is reduction or oxidation. A. Mo3+  Mo(s) B. H2SO3(aq)  SO42-(aq) C. NO3-(aq)  NO(g) D. Mn2+(aq)  MnO2(s) E. Cr(OH)3(s)  CrO42- (aq)