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Polymers Based Sensors
Presented By:
Adnan Murad Bhayo
Group Presentation on a topic,
Adnan ppt
 The synthesis of P(S-VP)-AgNPs was accomplished by using a two-phase system consisting of methanol and
toluene. The concentrations of solution of P(S-VP), AgNO3 and NaBH4 were 0.1, 1.0 and 4.0 mM respectively.
 The solutions were mixed in a volume ratio of 1:30:0.1. P(S-VP) solution was added into a stirred aqueous
solution of AgNO3.
 After 15 min, NaBH4 was added into the reaction mixture and stirred for 30 min. Appearance of yellow color was an
indication of the formation of silver nanoparticles (AgNPs)
Synthesis of Nanoparticles
UV-visible spectrum of P(S-VP)-conjugated AgNPs
Ag+ + BH4
 + H2O  Ag0 +B(OH)3
when cartap is present in the solution, it tends to be attracted towards positive charges on the P2VP block
inside core of micelles because of its resonating structure
Cartap Resonating Structure P2VP
Encapsulation of Cartap (Pesticide)
Atomic Force Microscopy (AFM)
Zeta Sizer
Zeta Potential
FTIR
Adnan ppt
Structures of Pesticides
Adnan ppt
Interference
Cartap Detection in Water
Cartap Detection in Blood Plasma
UV-visible spectrum of P(S-VP)-conjugated AgNPs after incubation of P(S-VP)-conjugated AgNPs at 64 属C for
10 minutes (B.P. of methanol)
Temperature Effect
Salt Effect
pH Effect
Adnan ppt

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Adnan ppt

  • 1. Polymers Based Sensors Presented By: Adnan Murad Bhayo Group Presentation on a topic,
  • 3. The synthesis of P(S-VP)-AgNPs was accomplished by using a two-phase system consisting of methanol and toluene. The concentrations of solution of P(S-VP), AgNO3 and NaBH4 were 0.1, 1.0 and 4.0 mM respectively. The solutions were mixed in a volume ratio of 1:30:0.1. P(S-VP) solution was added into a stirred aqueous solution of AgNO3. After 15 min, NaBH4 was added into the reaction mixture and stirred for 30 min. Appearance of yellow color was an indication of the formation of silver nanoparticles (AgNPs) Synthesis of Nanoparticles
  • 4. UV-visible spectrum of P(S-VP)-conjugated AgNPs Ag+ + BH4 + H2O Ag0 +B(OH)3
  • 5. when cartap is present in the solution, it tends to be attracted towards positive charges on the P2VP block inside core of micelles because of its resonating structure Cartap Resonating Structure P2VP Encapsulation of Cartap (Pesticide)
  • 15. Cartap Detection in Blood Plasma
  • 16. UV-visible spectrum of P(S-VP)-conjugated AgNPs after incubation of P(S-VP)-conjugated AgNPs at 64 属C for 10 minutes (B.P. of methanol) Temperature Effect