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Mrs. Prajakta B. Kothawade
Assistant Professor,
PES Modern College of Pharmacy, for ladies, Moshi, Pune
Carbohydrates are Polyhydroxy aldehydes or ketones, or
substances that yield such compounds on hydrolysis.
General formula : (CH2O)n
 Monosaccharides  carbohydrates that cannot be hydrolyzed
to simpler carbohydrates; eg. Glucose or fructose.
 Oligosaccharides  carbohydrates that can be hydrolyzed into
a few monosaccharide units; eg. Sucrose or lactose
 Polysaccharides  carbohydrates that are polymeric sugars; eg
Starch or cellulose
 Monosaccharides Contains 3-9 carbon atom sugars.
Carbohydrates.ppt
Carbohydrates.ppt
Ketone Aldehyde
4 Tetrose Tetrulose
5 Pentose Pentulose
6 Hexose Hexulose
7 Heptose Heptulose
8 Octose Octulose
Number
of
carbons
 Oligosaccharides contains 2-10 monosaccharide units
joined by glycosidic bonds.
-OH group of one monosaccharide joined to -OH group
of another monosaccharide .
 Links may be a or b
 Link around glycosidic bond is fixed but anomeric forms
on the other C-1 are still in equilibrium.
Carbohydrates.ppt
Polysaccharides are complex carbohydrates made up
More than 10 linked monosaccharide units.
 Nomenclature:
Homopolysaccharide-a polysaccharide is made up of one type of
monosaccharide unit.
Heteropolysaccharide-a polysaccharide is made up of more than one type of
monosaccharide unit.
 Starch and glycogen are storage molecules
 Chitin and cellulose are structural molecules
 Cell surface polysaccharides are recognition molecules
Carbohydrates.ppt
Some types of polysaccharides
1.Starch
 Starch is a storage compound in plants, and made of
glucose units
 It is a homopolysaccharide made up of two components:
amylose and amylopectin.
 Most starch is 10-30% amylose and 70-90%
amylopectin
 Amylose  a straight chain structure formed by 1,4 glycosidic
bonds between 留-D-glucose molecules.
H O
OH
H
OH
H
OH
CH2OH
H
O H
H
OH
H
OH
CH2OH
H
O
H
H H O
O
H
OH
H
OH
CH2OH
H
H H O
H
OH
H
OH
CH2OH
H
OH
H
H O
O
H
OH
H
OH
CH2OH
H
O
H
1
6
5
4
3
1
2
amylose
Structure of Amylose Fraction of Starch
 The amylose chain forms a
helix.
 This causes the blue colour
change on reaction with
iodine.
 Amylose is poorly soluble in
water, but forms micellar
suspensions
Amylose
Amylopectin-a glucose polymer with mainly 留 -(14)
linkages, but it also has branches formed by 留 -(16)
linkages. Branches are generally longer than shown above.
H O
OH
H
OH
H
OH
CH2OH
H
O H
H
OH
H
OH
CH2OH
H
O
H
H H O
O
H
OH
H
OH
CH2
H
H H O
H
OH
H
OH
CH2OH
H
OH
H
H O
O
H
OH
H
OH
CH2OH
H
O
H
O
1 4
6
H O
H
OH
H
OH
CH2OH
H
H H O
H
OH
H
OH
CH2OH
H
H
O
1
OH
3
4
5
2
amylopectin
Structure of Amylopectin Fraction of Starch
 Amylopectin causes a red-
violet colour change on
reaction with iodine.
 This change is usually
masked by the much
darker reaction of
amylose to iodine.
Amylopectin
Amylopectin
Starch therefore consists of amylose helices entangled on
branches of amylopectin.
2 Glycogen
 Storage polysaccharide in animals
 Glycogen constitutes up to 10% of liver mass and 1-2% of muscle
mass
 Glycogen is stored energy for the organism
 Similar in structure to amylopectin, only difference from starch:
number of branches
 Alpha(1,6) branches every 8-12 residues
 Like amylopectin, glycogen gives a red-violet color with iodine
glycogen
3 Cellulose
 The 硫-glucose molecules are joined by condensation, i.e. the
removal of water, forming 硫-(1,4) glycosidic linkages.
 The glucose units are linked into straight chains each 100-1000
units long.
Carbohydrates.ppt
Cellulose
4 pectin
Cell wall
polysaccharide
Carbohydrates.ppt
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Carbohydrates.ppt

  • 1. Mrs. Prajakta B. Kothawade Assistant Professor, PES Modern College of Pharmacy, for ladies, Moshi, Pune
  • 2. Carbohydrates are Polyhydroxy aldehydes or ketones, or substances that yield such compounds on hydrolysis. General formula : (CH2O)n
  • 3. Monosaccharides carbohydrates that cannot be hydrolyzed to simpler carbohydrates; eg. Glucose or fructose. Oligosaccharides carbohydrates that can be hydrolyzed into a few monosaccharide units; eg. Sucrose or lactose Polysaccharides carbohydrates that are polymeric sugars; eg Starch or cellulose
  • 4. Monosaccharides Contains 3-9 carbon atom sugars.
  • 7. Ketone Aldehyde 4 Tetrose Tetrulose 5 Pentose Pentulose 6 Hexose Hexulose 7 Heptose Heptulose 8 Octose Octulose Number of carbons
  • 8. Oligosaccharides contains 2-10 monosaccharide units joined by glycosidic bonds. -OH group of one monosaccharide joined to -OH group of another monosaccharide . Links may be a or b Link around glycosidic bond is fixed but anomeric forms on the other C-1 are still in equilibrium.
  • 10. Polysaccharides are complex carbohydrates made up More than 10 linked monosaccharide units. Nomenclature: Homopolysaccharide-a polysaccharide is made up of one type of monosaccharide unit. Heteropolysaccharide-a polysaccharide is made up of more than one type of monosaccharide unit. Starch and glycogen are storage molecules Chitin and cellulose are structural molecules Cell surface polysaccharides are recognition molecules
  • 12. Some types of polysaccharides 1.Starch Starch is a storage compound in plants, and made of glucose units It is a homopolysaccharide made up of two components: amylose and amylopectin. Most starch is 10-30% amylose and 70-90% amylopectin
  • 13. Amylose a straight chain structure formed by 1,4 glycosidic bonds between 留-D-glucose molecules. H O OH H OH H OH CH2OH H O H H OH H OH CH2OH H O H H H O O H OH H OH CH2OH H H H O H OH H OH CH2OH H OH H H O O H OH H OH CH2OH H O H 1 6 5 4 3 1 2 amylose Structure of Amylose Fraction of Starch
  • 14. The amylose chain forms a helix. This causes the blue colour change on reaction with iodine. Amylose is poorly soluble in water, but forms micellar suspensions Amylose
  • 15. Amylopectin-a glucose polymer with mainly 留 -(14) linkages, but it also has branches formed by 留 -(16) linkages. Branches are generally longer than shown above. H O OH H OH H OH CH2OH H O H H OH H OH CH2OH H O H H H O O H OH H OH CH2 H H H O H OH H OH CH2OH H OH H H O O H OH H OH CH2OH H O H O 1 4 6 H O H OH H OH CH2OH H H H O H OH H OH CH2OH H H O 1 OH 3 4 5 2 amylopectin Structure of Amylopectin Fraction of Starch
  • 16. Amylopectin causes a red- violet colour change on reaction with iodine. This change is usually masked by the much darker reaction of amylose to iodine. Amylopectin Amylopectin
  • 17. Starch therefore consists of amylose helices entangled on branches of amylopectin.
  • 18. 2 Glycogen Storage polysaccharide in animals Glycogen constitutes up to 10% of liver mass and 1-2% of muscle mass Glycogen is stored energy for the organism Similar in structure to amylopectin, only difference from starch: number of branches Alpha(1,6) branches every 8-12 residues Like amylopectin, glycogen gives a red-violet color with iodine
  • 20. 3 Cellulose The 硫-glucose molecules are joined by condensation, i.e. the removal of water, forming 硫-(1,4) glycosidic linkages. The glucose units are linked into straight chains each 100-1000 units long.