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(b) Concentration of ions in the solution / electrolytes.




                                                                  Sodium chloride solution,
                                                                  1.0 mol dm-3



                     Carbon
                     electrodes




                        Figure 3 Electrolysis of sodium chloride solution



                            From sodium chloride            Na+, Cl-
                            From water                      H+ , OH-


CATHODE: Na+ , H+                                   ANODE: Cl- , OH-
Both types of cations are attracted to the          Both ions are attracted to the anode, Chloride
cathode, H+ ions are selected for discharged        ions are discharged because the concentration
as they are lower in the ES.                        of Cl- ions are higher than of OH- ions.



2H+ + 2e -- H2 (g)                                 2Cl- -- Cl2 (g) + 2e
Gas bubbles are formed. When a lighted              Bubbles pungent yellowish-green gas is
wooden splinter is place near the mouth of          produced. The gas changed the damp blue
the test tube, a `pop` sound is produced.           litmus paper to red and bleached it. Chlorine
Hydrogen gas is evolved.                            gas is formed.



                 Solution becomes alkaline by presence of sodium hydroxide.
                                         NaOH(aq)
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Concentration of ions in the solution

  • 1. (b) Concentration of ions in the solution / electrolytes. Sodium chloride solution, 1.0 mol dm-3 Carbon electrodes Figure 3 Electrolysis of sodium chloride solution From sodium chloride Na+, Cl- From water H+ , OH- CATHODE: Na+ , H+ ANODE: Cl- , OH- Both types of cations are attracted to the Both ions are attracted to the anode, Chloride cathode, H+ ions are selected for discharged ions are discharged because the concentration as they are lower in the ES. of Cl- ions are higher than of OH- ions. 2H+ + 2e -- H2 (g) 2Cl- -- Cl2 (g) + 2e Gas bubbles are formed. When a lighted Bubbles pungent yellowish-green gas is wooden splinter is place near the mouth of produced. The gas changed the damp blue the test tube, a `pop` sound is produced. litmus paper to red and bleached it. Chlorine Hydrogen gas is evolved. gas is formed. Solution becomes alkaline by presence of sodium hydroxide. NaOH(aq)