際際滷

際際滷Share a Scribd company logo
2
Most read
3
Most read
4
Most read
PHOSPHORIC ACID BY HCL
Prepared by- Mr. Vishal B. Thakare
(M.Tech, Chemical SVNIT Surat)
Assistant Professor PARUL UNIVERSITY
Vadodara
vishalbt88@gmail.com
PHOSPHORIC ACID
Wet Process by HCL
Raw Material
 Phosphate rock of high P2O5 content(>30%),Hydrochloric acid
 Organic C4 and C5 alcohol solvent (Butanol or amyl alcohol) to
extract H3PO4 from CaCl2 solution.
Reaction
Ca3(PO4)2 + 6HCl + 6H2O 2H3PO4 + 3CaCl2
Side Reactions
CaF2 + 2HCl 2HF + CaCl2
6HF + SiO2 H2SiF6 + 2 H2O
Phosphoric acid by HCl
Phosphate rock is ground top pass a 20 mesh screen and fed into a
dissolver where an acid stream of conc. HCl plus make-up wash
water from the counter-current decantation system is added.
Fumes of CO2, HF and HCl are scrubbed for acid recovery.
The mixture is fed to a series of decantation units with overflow
from the first settler moving to the counter-current solvent extraction
operations. The solids underflow goes to 2-3 washing thickeners.
Extraction of H3PO4 plus some free HCl is done in a battery of
mixer-settlers (a) with CaC12 + CaF2 retained in aqueous phase.
The extract is again passed through several more mixer-settlers (b)
for removal of trace impurities of Ca++ which are co-extracted.
In extractors (c) water extracts H3PO4 and HCl from solvent phase.
The wash solvent from mixer settler (d) is passed to solvent
recovery column and again recycled for extraction.
The aqueous acid raffinate from (c) is separated and concentrated in
a triple effect evaporator to give three different overhead streams.
a) Weak HCl b) Conc. HCl c) Phosphoric acid.
Ad

Recommended

Extraction of Lead
Extraction of Lead
Imtiaz Ali Soomro
Manufacture of caustic soda and chlorine using electrolysis process ...
Manufacture of caustic soda and chlorine using electrolysis process ...
Ankush Gupta
2008 honda civic service repair manual
2008 honda civic service repair manual
ofpsdjksemmds
Microbial Enhance Oil Recovery
Microbial Enhance Oil Recovery
MehreenSharif1
Phosphate based fertilizers
Phosphate based fertilizers
Adeel Hasnain
Nanotoxicology and Nanosafety
Nanotoxicology and Nanosafety
Mobiliuz
Chlor Alkali Industrial Process
Chlor Alkali Industrial Process
Mahmoud Ashraf
Manufacture of manufacturing of single superphosphate and triple superphospah...
Manufacture of manufacturing of single superphosphate and triple superphospah...
MuhammadAyyanKhan
Production of caustic soda and chlorine-ppt
Production of caustic soda and chlorine-ppt
Krishna Peshivadiya
Phosphoric acid Industries
Phosphoric acid Industries
SAFFI Ud Din Ahmad
Phosphoric acid [CHEMICAL PROCESSS INDUSTRIES]
Phosphoric acid [CHEMICAL PROCESSS INDUSTRIES]
KARTHIKSREEVATSAN
B E Project - Manufacturing of Phosphoric Acid
B E Project - Manufacturing of Phosphoric Acid
Aniket Mali
Phosphoric acid by sulphuric acid
Phosphoric acid by sulphuric acid
VISHAL THAKRE
Methanol Synthesis Chemistry
Methanol Synthesis Chemistry
Gerard B. Hawkins
How to use TSP fertilizer manufacturing
How to use TSP fertilizer manufacturing
Proshantaroy5
Sodium Hydroxide
Sodium Hydroxide
VISHAL THAKRE
Catalytic reforming process
Catalytic reforming process
Ihsan Ali
Leaching equipmnts
Leaching equipmnts
Nandy 91
Reflux ratio
Reflux ratio
chemicalengppt
Chlor alkali
Chlor alkali
SakilMollah1
HNO3 MANUFACTURING WITH PROCESS FLOW DIAGRAM
HNO3 MANUFACTURING WITH PROCESS FLOW DIAGRAM
Usama Pervaiz
petroleum refining,crackin and synthetic petrol-ppt
petroleum refining,crackin and synthetic petrol-ppt
Krishna Peshivadiya
Ammonia production from natural gas, haldor topsoe process
Ammonia production from natural gas, haldor topsoe process
Gaurav Soni
CATALYTIC REFORMING
CATALYTIC REFORMING
translateds
Leaching
Leaching
Abhijit Panchmatiya
Ammonia plant GSFC by Vishal Tapiawala
Ammonia plant GSFC by Vishal Tapiawala
Vishal Tapiawala
Leaching process (solid-liquid extraction)
Leaching process (solid-liquid extraction)
Asim Farooq
Ammonium sulphate
Ammonium sulphate
VISHAL THAKRE
FAQ on chemical Reaction Engineering
FAQ on chemical Reaction Engineering
VISHAL THAKRE
FAQ on Process Calculation
FAQ on Process Calculation
VISHAL THAKRE

More Related Content

What's hot (20)

Production of caustic soda and chlorine-ppt
Production of caustic soda and chlorine-ppt
Krishna Peshivadiya
Phosphoric acid Industries
Phosphoric acid Industries
SAFFI Ud Din Ahmad
Phosphoric acid [CHEMICAL PROCESSS INDUSTRIES]
Phosphoric acid [CHEMICAL PROCESSS INDUSTRIES]
KARTHIKSREEVATSAN
B E Project - Manufacturing of Phosphoric Acid
B E Project - Manufacturing of Phosphoric Acid
Aniket Mali
Phosphoric acid by sulphuric acid
Phosphoric acid by sulphuric acid
VISHAL THAKRE
Methanol Synthesis Chemistry
Methanol Synthesis Chemistry
Gerard B. Hawkins
How to use TSP fertilizer manufacturing
How to use TSP fertilizer manufacturing
Proshantaroy5
Sodium Hydroxide
Sodium Hydroxide
VISHAL THAKRE
Catalytic reforming process
Catalytic reforming process
Ihsan Ali
Leaching equipmnts
Leaching equipmnts
Nandy 91
Reflux ratio
Reflux ratio
chemicalengppt
Chlor alkali
Chlor alkali
SakilMollah1
HNO3 MANUFACTURING WITH PROCESS FLOW DIAGRAM
HNO3 MANUFACTURING WITH PROCESS FLOW DIAGRAM
Usama Pervaiz
petroleum refining,crackin and synthetic petrol-ppt
petroleum refining,crackin and synthetic petrol-ppt
Krishna Peshivadiya
Ammonia production from natural gas, haldor topsoe process
Ammonia production from natural gas, haldor topsoe process
Gaurav Soni
CATALYTIC REFORMING
CATALYTIC REFORMING
translateds
Leaching
Leaching
Abhijit Panchmatiya
Ammonia plant GSFC by Vishal Tapiawala
Ammonia plant GSFC by Vishal Tapiawala
Vishal Tapiawala
Leaching process (solid-liquid extraction)
Leaching process (solid-liquid extraction)
Asim Farooq
Ammonium sulphate
Ammonium sulphate
VISHAL THAKRE
Production of caustic soda and chlorine-ppt
Production of caustic soda and chlorine-ppt
Krishna Peshivadiya
Phosphoric acid [CHEMICAL PROCESSS INDUSTRIES]
Phosphoric acid [CHEMICAL PROCESSS INDUSTRIES]
KARTHIKSREEVATSAN
B E Project - Manufacturing of Phosphoric Acid
B E Project - Manufacturing of Phosphoric Acid
Aniket Mali
Phosphoric acid by sulphuric acid
Phosphoric acid by sulphuric acid
VISHAL THAKRE
Methanol Synthesis Chemistry
Methanol Synthesis Chemistry
Gerard B. Hawkins
How to use TSP fertilizer manufacturing
How to use TSP fertilizer manufacturing
Proshantaroy5
Catalytic reforming process
Catalytic reforming process
Ihsan Ali
Leaching equipmnts
Leaching equipmnts
Nandy 91
HNO3 MANUFACTURING WITH PROCESS FLOW DIAGRAM
HNO3 MANUFACTURING WITH PROCESS FLOW DIAGRAM
Usama Pervaiz
petroleum refining,crackin and synthetic petrol-ppt
petroleum refining,crackin and synthetic petrol-ppt
Krishna Peshivadiya
Ammonia production from natural gas, haldor topsoe process
Ammonia production from natural gas, haldor topsoe process
Gaurav Soni
CATALYTIC REFORMING
CATALYTIC REFORMING
translateds
Ammonia plant GSFC by Vishal Tapiawala
Ammonia plant GSFC by Vishal Tapiawala
Vishal Tapiawala
Leaching process (solid-liquid extraction)
Leaching process (solid-liquid extraction)
Asim Farooq
Ammonium sulphate
Ammonium sulphate
VISHAL THAKRE

More from VISHAL THAKRE (18)

FAQ on chemical Reaction Engineering
FAQ on chemical Reaction Engineering
VISHAL THAKRE
FAQ on Process Calculation
FAQ on Process Calculation
VISHAL THAKRE
Pulp making
Pulp making
VISHAL THAKRE
Sulphuric Acid
Sulphuric Acid
VISHAL THAKRE
Sodium bicarbonate
Sodium bicarbonate
VISHAL THAKRE
Paper making
Paper making
VISHAL THAKRE
Nitric acid by oxidation process
Nitric acid by oxidation process
VISHAL THAKRE
Nitric acid by arc process
Nitric acid by arc process
VISHAL THAKRE
Urea
Urea
VISHAL THAKRE
Triple super phosphate
Triple super phosphate
VISHAL THAKRE
Superphosphate
Superphosphate
VISHAL THAKRE
Ammonium phosphate
Ammonium phosphate
VISHAL THAKRE
Ammonia
Ammonia
VISHAL THAKRE
Introduction of polymer
Introduction of polymer
VISHAL THAKRE
Excel error
Excel error
VISHAL THAKRE
Fiber
Fiber
VISHAL THAKRE
Uses of polymer
Uses of polymer
VISHAL THAKRE
FAQ's heat transfer
FAQ's heat transfer
VISHAL THAKRE
FAQ on chemical Reaction Engineering
FAQ on chemical Reaction Engineering
VISHAL THAKRE
FAQ on Process Calculation
FAQ on Process Calculation
VISHAL THAKRE
Sodium bicarbonate
Sodium bicarbonate
VISHAL THAKRE
Nitric acid by oxidation process
Nitric acid by oxidation process
VISHAL THAKRE
Nitric acid by arc process
Nitric acid by arc process
VISHAL THAKRE
Triple super phosphate
Triple super phosphate
VISHAL THAKRE
Ammonium phosphate
Ammonium phosphate
VISHAL THAKRE
Introduction of polymer
Introduction of polymer
VISHAL THAKRE
FAQ's heat transfer
FAQ's heat transfer
VISHAL THAKRE
Ad

Recently uploaded (20)

retina_biometrics ruet rajshahi bangdesh.pptx
retina_biometrics ruet rajshahi bangdesh.pptx
MdRakibulIslam697135
IPL_Logic_Flow.pdf Mainframe IPLMainframe IPL
IPL_Logic_Flow.pdf Mainframe IPLMainframe IPL
KhadijaKhadijaAouadi
60 Years and Beyond eBook 1234567891.pdf
60 Years and Beyond eBook 1234567891.pdf
waseemalazzeh
Industry 4.o the fourth revolutionWeek-2.pptx
Industry 4.o the fourth revolutionWeek-2.pptx
KNaveenKumarECE
NEW Strengthened Senior High School Gen Math.pptx
NEW Strengthened Senior High School Gen Math.pptx
DaryllWhere
Complete University of Calculus :: 2nd edition
Complete University of Calculus :: 2nd edition
Shabista Imam
International Journal of Advanced Information Technology (IJAIT)
International Journal of Advanced Information Technology (IJAIT)
ijait
Cadastral Maps
Cadastral Maps
Google
(Continuous Integration and Continuous Deployment/Delivery) is a fundamental ...
(Continuous Integration and Continuous Deployment/Delivery) is a fundamental ...
ketan09101
Modern multi-proposer consensus implementations
Modern multi-proposer consensus implementations
Fran巽ois Garillot
Fatality due to Falls at Working at Height
Fatality due to Falls at Working at Height
ssuserb8994f
Rapid Prototyping for XR: Lecture 1 Introduction to Prototyping
Rapid Prototyping for XR: Lecture 1 Introduction to Prototyping
Mark Billinghurst
System design handwritten notes guidance
System design handwritten notes guidance
Shabista Imam
LECTURE 7 COMPUTATIONS OF LEVELING DATA APRIL 2025.pptx
LECTURE 7 COMPUTATIONS OF LEVELING DATA APRIL 2025.pptx
rr22001247
Deep Learning for Image Processing on 16 June 2025 MITS.pptx
Deep Learning for Image Processing on 16 June 2025 MITS.pptx
resming1
Learning Types of Machine Learning Supervised Learning Unsupervised UNI...
Learning Types of Machine Learning Supervised Learning Unsupervised UNI...
23Q95A6706
Rapid Prototyping for XR: Lecture 5 - Cross Platform Development
Rapid Prototyping for XR: Lecture 5 - Cross Platform Development
Mark Billinghurst
Machine Learning - Classification Algorithms
Machine Learning - Classification Algorithms
resming1
Rapid Prototyping for XR: Lecture 3 - Video and Paper Prototyping
Rapid Prototyping for XR: Lecture 3 - Video and Paper Prototyping
Mark Billinghurst
Introduction to sensing and Week-1.pptx
Introduction to sensing and Week-1.pptx
KNaveenKumarECE
retina_biometrics ruet rajshahi bangdesh.pptx
retina_biometrics ruet rajshahi bangdesh.pptx
MdRakibulIslam697135
IPL_Logic_Flow.pdf Mainframe IPLMainframe IPL
IPL_Logic_Flow.pdf Mainframe IPLMainframe IPL
KhadijaKhadijaAouadi
60 Years and Beyond eBook 1234567891.pdf
60 Years and Beyond eBook 1234567891.pdf
waseemalazzeh
Industry 4.o the fourth revolutionWeek-2.pptx
Industry 4.o the fourth revolutionWeek-2.pptx
KNaveenKumarECE
NEW Strengthened Senior High School Gen Math.pptx
NEW Strengthened Senior High School Gen Math.pptx
DaryllWhere
Complete University of Calculus :: 2nd edition
Complete University of Calculus :: 2nd edition
Shabista Imam
International Journal of Advanced Information Technology (IJAIT)
International Journal of Advanced Information Technology (IJAIT)
ijait
Cadastral Maps
Cadastral Maps
Google
(Continuous Integration and Continuous Deployment/Delivery) is a fundamental ...
(Continuous Integration and Continuous Deployment/Delivery) is a fundamental ...
ketan09101
Modern multi-proposer consensus implementations
Modern multi-proposer consensus implementations
Fran巽ois Garillot
Fatality due to Falls at Working at Height
Fatality due to Falls at Working at Height
ssuserb8994f
Rapid Prototyping for XR: Lecture 1 Introduction to Prototyping
Rapid Prototyping for XR: Lecture 1 Introduction to Prototyping
Mark Billinghurst
System design handwritten notes guidance
System design handwritten notes guidance
Shabista Imam
LECTURE 7 COMPUTATIONS OF LEVELING DATA APRIL 2025.pptx
LECTURE 7 COMPUTATIONS OF LEVELING DATA APRIL 2025.pptx
rr22001247
Deep Learning for Image Processing on 16 June 2025 MITS.pptx
Deep Learning for Image Processing on 16 June 2025 MITS.pptx
resming1
Learning Types of Machine Learning Supervised Learning Unsupervised UNI...
Learning Types of Machine Learning Supervised Learning Unsupervised UNI...
23Q95A6706
Rapid Prototyping for XR: Lecture 5 - Cross Platform Development
Rapid Prototyping for XR: Lecture 5 - Cross Platform Development
Mark Billinghurst
Machine Learning - Classification Algorithms
Machine Learning - Classification Algorithms
resming1
Rapid Prototyping for XR: Lecture 3 - Video and Paper Prototyping
Rapid Prototyping for XR: Lecture 3 - Video and Paper Prototyping
Mark Billinghurst
Introduction to sensing and Week-1.pptx
Introduction to sensing and Week-1.pptx
KNaveenKumarECE
Ad

Phosphoric acid by HCl

  • 1. PHOSPHORIC ACID BY HCL Prepared by- Mr. Vishal B. Thakare (M.Tech, Chemical SVNIT Surat) Assistant Professor PARUL UNIVERSITY Vadodara vishalbt88@gmail.com
  • 2. PHOSPHORIC ACID Wet Process by HCL Raw Material Phosphate rock of high P2O5 content(>30%),Hydrochloric acid Organic C4 and C5 alcohol solvent (Butanol or amyl alcohol) to extract H3PO4 from CaCl2 solution. Reaction Ca3(PO4)2 + 6HCl + 6H2O 2H3PO4 + 3CaCl2 Side Reactions CaF2 + 2HCl 2HF + CaCl2 6HF + SiO2 H2SiF6 + 2 H2O
  • 4. Phosphate rock is ground top pass a 20 mesh screen and fed into a dissolver where an acid stream of conc. HCl plus make-up wash water from the counter-current decantation system is added. Fumes of CO2, HF and HCl are scrubbed for acid recovery. The mixture is fed to a series of decantation units with overflow from the first settler moving to the counter-current solvent extraction operations. The solids underflow goes to 2-3 washing thickeners. Extraction of H3PO4 plus some free HCl is done in a battery of mixer-settlers (a) with CaC12 + CaF2 retained in aqueous phase. The extract is again passed through several more mixer-settlers (b) for removal of trace impurities of Ca++ which are co-extracted.
  • 5. In extractors (c) water extracts H3PO4 and HCl from solvent phase. The wash solvent from mixer settler (d) is passed to solvent recovery column and again recycled for extraction. The aqueous acid raffinate from (c) is separated and concentrated in a triple effect evaporator to give three different overhead streams. a) Weak HCl b) Conc. HCl c) Phosphoric acid.