Chains are the measuring instrument used in surveying, formed by 100 links of galvanized steel wire joined by circular rings. There are different types of chains including metric, steel band, Gunter's, engineer's, and revenue chains, which vary in length and link size. Chains are tested for accuracy against tapes or markers and can be adjusted if too long or short by manipulating the links and rings. While chains are a simple surveying method, they are subject to accumulation errors and are time-consuming for large or complex areas.