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Bioraffinaderiets möjligheter att skapa
kemikalier och material

Peter Axegård, Innventia

Framtidens förpackningsmaterial
Kista Entré Konferens, 15 november 2011
The Modern Kraft Pulp Mill –
A Biorefinery Platform




    Source: Aker Kvaerner

2011-11-18
                            Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15
2
Organic Substance in a Kraft Pulp Mill, kg


                   Spruce/
                    pine                    Birch                Eucalypt

Pulp fibres          1000                    1000                     1000                    All can be used

Lignin               600                      470                       440                   2/3 can be removed

Xylan                 70                      260                       210                   1/3 can be removed




        Cellulose fibres - main product
        Added value from other components



 2011-11-18
                     Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15
  3
Lignin
Kraft Lignin from LignoBoost Demo Plant
  Carbon        64 – 66 %
  Ash           0.3 - 1 %
  Carbohydrates 0.5-1.5 %




 2011-11-18
               Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15
 5
Activated carbon
  Lignin Applications

  Carbon fibre




                                       Hydrofobzing                                             Asphalt emulsions
                                       agent
Binder in fibreboard




   2011-11-18
                  Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15
   6
Hemicelluloses
Polymeric Xylan from Birch Black Liquor




2011-11-18
             Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15
8
Extrudable Co-polymer from Birch Xylan

      – New materials based on hemicellulose lactic acid co-polymers




2011-11-18
                 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15
9
Other Xylan Applications

                 Fibre additive (higher surface charge)
                 Chemical modification
                 Cellulose fibre composites

                 Gas barriers
                 Hydrogels
                 Emulsifiers

                 Xylitol
                 Xylose
                 Lactic acid




 2011-11-18
                          Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15
 10
Cellulose
Cellulose Products

                                                                              Nanocellulose gel


      Kraft pulp fibres




                      Fibre PLA
                      composite
                                                                                          Transparent
                                                                                          films


2011-11-18
                      Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15
12
Kraft Pulp Cellulose for Cotton Fibre Replacement




2011-11-18
             Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15
13
POLYNOL Project - Overall Concept

 Pulp
 wood                                  Paper /   Liquid             Renewable
                  Kraft                          packaging
                                       board                        packaging
                 pulping                prod.    board
                                                          Polyethylene
Forestry residues, Low-
                                                           & PLA
cost wood, bagasse
                 Alkaline            Ethanol
                                                 Ethanol & Lactic Acid
               fractionation          prod.

                                 CO2                      Transportation fuel
 Chemicals
                        Lignin       Sulphur-Free        Carbon fibres for light
  Recovery               prod.       Lignin              weight vehicles

              Energy
             Recovery
                               Electric Power
Products from the Kraft Pulp Mill Biorefinery



Cellulose          Paper pulp, composites, barriers, special cellulose


Lignin             Fuel, carbon fibres, activated carbon, binder,
                   hydrophobizing agent

Hemicellulose      Fibre additive, barriers, co-polymers, lactic acid

Forestry residues Power, heat, transportation fuels, pellets

Extractives        Tall oil, turpentine, specialty chemicals


 2011-11-18
                    Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15
  15

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Bioraffinaderiets möjligheter att skapa kemikalier och material av Peter Axegård

  • 1. Bioraffinaderiets möjligheter att skapa kemikalier och material Peter Axegård, Innventia Framtidens förpackningsmaterial Kista Entré Konferens, 15 november 2011
  • 2. The Modern Kraft Pulp Mill – A Biorefinery Platform Source: Aker Kvaerner 2011-11-18 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15 2
  • 3. Organic Substance in a Kraft Pulp Mill, kg Spruce/ pine Birch Eucalypt Pulp fibres 1000 1000 1000 All can be used Lignin 600 470 440 2/3 can be removed Xylan 70 260 210 1/3 can be removed  Cellulose fibres - main product  Added value from other components 2011-11-18 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15 3
  • 5. Kraft Lignin from LignoBoost Demo Plant Carbon 64 – 66 % Ash 0.3 - 1 % Carbohydrates 0.5-1.5 % 2011-11-18 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15 5
  • 6. Activated carbon Lignin Applications Carbon fibre Hydrofobzing Asphalt emulsions agent Binder in fibreboard 2011-11-18 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15 6
  • 8. Polymeric Xylan from Birch Black Liquor 2011-11-18 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15 8
  • 9. Extrudable Co-polymer from Birch Xylan – New materials based on hemicellulose lactic acid co-polymers 2011-11-18 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15 9
  • 10. Other Xylan Applications  Fibre additive (higher surface charge)  Chemical modification  Cellulose fibre composites  Gas barriers  Hydrogels  Emulsifiers  Xylitol  Xylose  Lactic acid 2011-11-18 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15 10
  • 12. Cellulose Products Nanocellulose gel Kraft pulp fibres Fibre PLA composite Transparent films 2011-11-18 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15 12
  • 13. Kraft Pulp Cellulose for Cotton Fibre Replacement 2011-11-18 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15 13
  • 14. POLYNOL Project - Overall Concept Pulp wood Paper / Liquid Renewable Kraft packaging board packaging pulping prod. board Polyethylene Forestry residues, Low- & PLA cost wood, bagasse Alkaline Ethanol Ethanol & Lactic Acid fractionation prod. CO2 Transportation fuel Chemicals Lignin Sulphur-Free Carbon fibres for light Recovery prod. Lignin weight vehicles Energy Recovery Electric Power
  • 15. Products from the Kraft Pulp Mill Biorefinery Cellulose Paper pulp, composites, barriers, special cellulose Lignin Fuel, carbon fibres, activated carbon, binder, hydrophobizing agent Hemicellulose Fibre additive, barriers, co-polymers, lactic acid Forestry residues Power, heat, transportation fuels, pellets Extractives Tall oil, turpentine, specialty chemicals 2011-11-18 Axegård, Bioraffinaderiets Möjligheter, Framtidens förpackningsmaterial, Kista, 2011-11-15 15