Mark, Polymer Data Handbook
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This document summarizes information about poly(1,3-trans-竜-carboxyphenoxypropane anhydride), including its structure, major applications, thermal behavior, synthesis methods, and various physical properties. Tables provide data on polymer composition and properties like density, glass transition temperature, and solubility. The polymer is a dark purple powder that is soluble in concentrated sulfuric and methane sulfonic acids. It has a glass transition temperature between 213-238 K depending on its acetonitrile content.
![995
Poly(1,3-trans-竜-carboxyphenoxypropane anhydride)
Jagath K. Premachandra, Chamdima Kumudinie,
and Junzo Masamoto
Acronym, Trade Names Bore conullut ulput nit, sed magna feugiamcorer am venissi
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Structure[CH2CH=CHCH2]m[CH2CH]n
|
C=N
Major Applications Bore conullut ulput nit, sed magna feugiamcorer am venissi exer足cinim
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Source(4) Cellulose (%)
Cotton 94
Hemp 77
Flax 75
Straw 4050
Gelatin Testing Methods
Identification Gelatin gives the normal positive trichloroacetic acid, biret, ninhydrin.
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Thermal behavior(1)
Cis isomer 1. Cis to trans isomerization at 145属C
2. Molecular rearrangement at 325属C
3. Thermal decomposition at 420属C
Shorthand notation for siloxane polymer units
Formula: (CH3)3SiO0.5 (CH3)2SiO (CH3)SiO1.5 SiO2
MDTQ formula: M (monofunctional) D (difunctional T (trifunction) Q (tetrafunctional)
CH3 CH3 CH3 O
| | | |
H3CSiO OSiO OSiO OSiO
| | | |
CH3 CH3 O O](https://image.slidesharecdn.com/oupmarkpolymerdatahandbook-150614162803-lva1-app6892/85/Mark-Polymer-Data-Handbook-1-320.jpg)
![Poly(1,3-trans-竜-carboxyphenoxypropane anhydride)
997996
Poly(1,3-trans-竜-carboxyphenoxypropane anhydride)
P2O5 (wt. %) [P2O5] 1 2 3 4 5 6 7 8 9 10 11 12 13 14 High-Poly
89.4 1.066 1.88
89.4 1.066 1.88 1.52
89.4 1.066 1.88 1.52 0.77
89.4 1.066 1.88 1.52 0.77 0.61
89.4 1.066 1.88 1.52 0.77 0.61 0.62
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8
89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8
Property Units Conditions Value Reference
Density g cm3 26-27% ACN 0.92 (1)
Glass transition temperature Tg K ~20% ACN 213 (2)
~30% ACN 231
~34% ACN 238
Service temperature (max) K 9% N
Solubility Parameter (MPa)1/2 25% ACN, 25C, calc. 18.93 (4)
Theta temperature 慮 K 26% ACN, cyclohexane/MEK (64/36) 293.2 (5)
40% ACN, cyclohexame/MEK (52.5/47.5) 295.2
*Table footnote agna atue delent velissed ercidunt la ad et luptat ut iuscinc ilisi.
Synthesis(14)
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Other physical properties(4)
Property Polymer Conditions
Color [Si(Pc)O]n Dark purple powder
Solubility [Si(Pc)O]n Concentrated H2SO4 and HSO3CH3:
0.013 g in 25 ml concentrated H2SO4 at room temperature
0.020 g in 25 ml concentrated H2SO4 at 80C
Densities
Density (G CM 3)
Polymer y Calculated Found Reference
[Si(Pc)O]n 1.458 1.432 (4,6)
Sonic velocity Infrared diachroic
X-ray angle (degree)
Thickness Density Birefringence
(ms1) ratio (at 730 cm1) a-axis b-axis
(亮m) (g cm3) ( 103) MD* TD* MD/TD* MD-TD* ND-MD* MD-TD* ND-MD*
54 0.9182 9.79 953 1,128 1.15 4550 4560 0 0
26 8.23 870 1,003 0.88 45 4560 0 0
23 0.9175 3.07 852 998 1.13 70 6070 0 0
Table 2. This page uses 30 pts r/b above Densities head abd 24 pts between other blocks.
This text ignores far right TSH so 24 pts b/b is to 2nd row.
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Typical properties of filled amino resin molding compounds(3)
Urea Melamine
Property Units Alpha-cellulose Alpha-cellulose Asbestos Glass fiber
Physical
Specific gravity _ 1.471.52 1.471.52 1.72.0 1.82.0
Water absorption % 0.48 0.10.6 0.080.14 0.090.21
Mechanical
Tensile strength MPa (103) 3848 (5.57) 4890 (713) 3845 (56.5) 3570 (510)
Elongation % 0.51.0 0.60.9 0.30.45
Tensile strength MPa (103) 3848 (5.57) 4890 (713) 3845 (56.5) 3570 (510)
Thermal
Tensile strength MPa (103) 3848 (5.57) 4890 (713) 3845 (56.5) 3570 (510)
Elongation % 0.51.0 0.60.9 0.30.45
Tensile strength MPa (103) 3848 (5.57) 4890 (713) 3845 (56.5) 3570 (510)](https://image.slidesharecdn.com/oupmarkpolymerdatahandbook-150614162803-lva1-app6892/85/Mark-Polymer-Data-Handbook-2-320.jpg)
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Mark, Polymer Data Handbook
- 1. 995 Poly(1,3-trans-竜-carboxyphenoxypropane anhydride) Jagath K. Premachandra, Chamdima Kumudinie, and Junzo Masamoto Acronym, Trade Names Bore conullut ulput nit, sed magna feugiamcorer am venissi exercinim velisci bla core el ute corper alis aliquis alis nim augiatue. Structure[CH2CH=CHCH2]m[CH2CH]n | C=N Major Applications Bore conullut ulput nit, sed magna feugiamcorer am venissi exer足cinim velisci bla core el ute corper alis aliquis alis nim augiatue do exero dui blandreet laorero et wis nos nisi essequat, sectet atue tisim ilis nit atueratem quismod. Source(4) Cellulose (%) Cotton 94 Hemp 77 Flax 75 Straw 4050 Gelatin Testing Methods Identification Gelatin gives the normal positive trichloroacetic acid, biret, ninhydrin. Utatum veliquat am aci tet ilisi blandreetue consecte deli足quisi ting er ipis dio et niscil delis augait nos acil iure vendrem do odolenit veliquam, voloreetum vel utpat auguera esecte tat velit adiat landre feuipit landigna. Loboreet adio eugiam iureet lut ipsusti onullamet vero consequisit lor inis nisl dipit wis num exero ent la conse con et, consendiam, consequat nulland ipsusciduis augiam. Thermal behavior(1) Cis isomer 1. Cis to trans isomerization at 145属C 2. Molecular rearrangement at 325属C 3. Thermal decomposition at 420属C Shorthand notation for siloxane polymer units Formula: (CH3)3SiO0.5 (CH3)2SiO (CH3)SiO1.5 SiO2 MDTQ formula: M (monofunctional) D (difunctional T (trifunction) Q (tetrafunctional) CH3 CH3 CH3 O | | | | H3CSiO OSiO OSiO OSiO | | | | CH3 CH3 O O
- 2. Poly(1,3-trans-竜-carboxyphenoxypropane anhydride) 997996 Poly(1,3-trans-竜-carboxyphenoxypropane anhydride) P2O5 (wt. %) [P2O5] 1 2 3 4 5 6 7 8 9 10 11 12 13 14 High-Poly 89.4 1.066 1.88 89.4 1.066 1.88 1.52 89.4 1.066 1.88 1.52 0.77 89.4 1.066 1.88 1.52 0.77 0.61 89.4 1.066 1.88 1.52 0.77 0.61 0.62 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8 89.4 1.066 1.88 1.52 0.77 0.61 0.62 0.68 0.54 0.71 0.86 1.03 0.98 1.16 1.23 1.37 86.8 Property Units Conditions Value Reference Density g cm3 26-27% ACN 0.92 (1) Glass transition temperature Tg K ~20% ACN 213 (2) ~30% ACN 231 ~34% ACN 238 Service temperature (max) K 9% N Solubility Parameter (MPa)1/2 25% ACN, 25C, calc. 18.93 (4) Theta temperature 慮 K 26% ACN, cyclohexane/MEK (64/36) 293.2 (5) 40% ACN, cyclohexame/MEK (52.5/47.5) 295.2 *Table footnote agna atue delent velissed ercidunt la ad et luptat ut iuscinc ilisi. Synthesis(14) (a)Del eugiat lore dolor sed tat. Ud tatem dolore te dolobore commod essi. (b)Borperat, susci blandit landreetum incidunt nulla feugue vel il exero corercip enissequat. (c)Bore conullut ulput nit, sed magna feugiamcorer am venissi exercinim velisci bla core el ute corper alis aliquis alis nim augiatue do exero dui blandreet laorero et nisi essequat, sectet atue tisim ilis nit atueratem quismod te feuis del dolor adit, quamcon ulputpat, conullan hent veliqui ssendiat. Henim ad min ullan vent nullan hendiam commodit doluptat lobor se diat. Irilit ing euisl ulputpat, con utat. Duismod magnissim et lam zzriuscidunt nonum zzriusc ipsummod et lortis adip ex ex eum do od te dolesse ndignim iril doluptat, core commolor ip eratet, venim quismod olorerat laor iuscidui eraessent doleniscil. Other physical properties(4) Property Polymer Conditions Color [Si(Pc)O]n Dark purple powder Solubility [Si(Pc)O]n Concentrated H2SO4 and HSO3CH3: 0.013 g in 25 ml concentrated H2SO4 at room temperature 0.020 g in 25 ml concentrated H2SO4 at 80C Densities Density (G CM 3) Polymer y Calculated Found Reference [Si(Pc)O]n 1.458 1.432 (4,6) Sonic velocity Infrared diachroic X-ray angle (degree) Thickness Density Birefringence (ms1) ratio (at 730 cm1) a-axis b-axis (亮m) (g cm3) ( 103) MD* TD* MD/TD* MD-TD* ND-MD* MD-TD* ND-MD* 54 0.9182 9.79 953 1,128 1.15 4550 4560 0 0 26 8.23 870 1,003 0.88 45 4560 0 0 23 0.9175 3.07 852 998 1.13 70 6070 0 0 Table 2. This page uses 30 pts r/b above Densities head abd 24 pts between other blocks. This text ignores far right TSH so 24 pts b/b is to 2nd row. (a)Henim ad min ullan vent nullan hendiam. (b) commodit doluptat lobor se diat. (c)Et lortis adip ex ex eum do od te dolesse ndignim iril doluptat, core commolor ip eratet, venim quismod olorerat laor iuscidui eraessent doleniscil esto eumsandre. Typical properties of filled amino resin molding compounds(3) Urea Melamine Property Units Alpha-cellulose Alpha-cellulose Asbestos Glass fiber Physical Specific gravity _ 1.471.52 1.471.52 1.72.0 1.82.0 Water absorption % 0.48 0.10.6 0.080.14 0.090.21 Mechanical Tensile strength MPa (103) 3848 (5.57) 4890 (713) 3845 (56.5) 3570 (510) Elongation % 0.51.0 0.60.9 0.30.45 Tensile strength MPa (103) 3848 (5.57) 4890 (713) 3845 (56.5) 3570 (510) Thermal Tensile strength MPa (103) 3848 (5.57) 4890 (713) 3845 (56.5) 3570 (510) Elongation % 0.51.0 0.60.9 0.30.45 Tensile strength MPa (103) 3848 (5.57) 4890 (713) 3845 (56.5) 3570 (510)
- 3. Poly(1,3-trans-竜-carboxyphenoxypropane anhydride) 999998 Poly(1,3-trans-竜-carboxyphenoxypropane anhydride) Table 2b. Del eugiat lore dolor sed tat. Ud tatem dolore te dolobore commod essi. Borperat, susci blandit landreetum incidunt nulla feugue. fE 0.06 0.15 0.31 0.37 0.42 0.49 0.70 0.77 0.90 1.00 pK* 6.08 5.70 4.90 4.70 4.55 4.50 4.40 4.35 4.35 4.35 pK 6.61 5.92 5.03 4.80 4.48 4.40 4.35 4.40 4.55 4.70 fE 0.06 0.15 0.31 0.37 0.42 0.49 0.70 0.77 0.90 1.00 pK* 6.08 5.70 4.90 4.70 4.55 4.50 4.40 4.35 4.35 4.35 pK 6.61 5.92 5.03 4.80 4.48 4.40 4.35 4.40 4.55 4.70 fE 0.06 0.15 0.31 0.37 0.42 0.49 0.70 0.77 0.90 1.00 pK* 6.08 5.70 4.90 4.70 4.55 4.50 4.40 4.35 4.35 4.35 pK 6.61 5.92 5.03 4.80 4.48 4.40 4.35 4.40 4.55 4.70 Table 2c. Nonsenim vel exer autat. Reet, vel eu feum diat, velissi tiniamc onsectem zzrilla ndrerostin henisi. Ilit ut utet wisit, quat. Ut aliquamet, sum elesendiamet dionsecte modolortio ercing ea alisl ut lam venibh erosting eliquam Conditions Time (days) Value (% mass loss day1) Time (days) Value (% mass loss day1) Insulin loadings at 40% in copolymer at pH = 2.09; S.D. 賊 3; error 10% 0.0 0.0 5.1 96.4 0.07 9.0 7.1 98.8 0.1 25.4 9.0 98.9 0.3 49.0 12.0 99.5 3.0 85.5 25.0 100.0 4.0 89.4 Ditto (aat 10% loading) 0.0 0.0 5.1 96.4 0.07 9.0 7.1 98.8 0.1 25.4 9.0 98.9 0.3 49.0 12.0 99.5 3.0 85.5 25.0 100.0 Table 3. usciliquam ent num qui tem estrud dolenisissi ex endio consequis. Chemical shift (ppm) Chemical shift (ppm) Chemical shift (ppm) Chemical shift (ppm) Sequence Sequence Seqiemce Carbon Butene assignmnet* Hexene assignment* Octene assignment* 4-MP-1 assignment* 35.0 BBB 38.13 EHE 32.22 EOE 34.6 alpha-C 34.5 EBEB + BEBE 35.85 EHH + HHE 30.47 OEEE + EEEO 25.8 2-C 39.56 BBBE + EBBB 40.86 EHE + EHH + HHE + HHH EOE + EOO + OOE + OOO 10.81 BBB 27.09 HHEE + EEHH 24.39 EHEHH + HHEHE Figure 1. PAMAM dendrimers as a function of shape, core, branch cell and terminal groups, where: Nb=branch cell multiplicity, Nc=core multiplicity and G=generation. Ut aliquamet, sum elesendiamet dionsecte modolortio ercing ea alisl ut lam venibh erosting eliquam in utem veriurerat ipsusci liquis. Exeriliscil ing eliquissis augueri usciliquam ent num qui tem estrud dolenisissi ex endio consequis augiamc onsequat nostrud minciduisi. Other uses Nonsenim vel exer autat. Reet, vel eu feum diat, velissi tiniamc onsectem zzrilla ndrerostin henisi. Ilit ut utet wisit, quat. Ut aliquamet, sum elesendiamet dionsecte modolortio ercing ea alis. Exeriliscil ing eliquissis augueri usciliquam ent num qui tem estrud dolenisissi ex endio consequis augiamc onsequat nostrud minciduisi. Suppliers EMS Chemie AG, Domat, Switzerland Elf Atochem S.A., Paris, France UBE Industries, Tokyo, Japan Creanova GmbH., Division of Degussa-H端ls AG., Marl, Germany References 1. Nonsenim vel exer autat. Reet, vel eu feum diat, velissi tiniamc onsectem zzrilla ndrerostin henisi. Ilit ut utet wisit, quat. 2. Ut aliquamet, sum elesendiamet dionsecte modolortio ercing ea alisl ut lam venibh erosting eliquam in utem veriurerat ipsusci liquis. 3. Exeriliscil ing eliquissis augueri usciliquam ent num qui tem estrud dolenisissi ex endio consequis augiamc onsequat nostrud minciduisi. Acknowledgment The author wishes to acknowledge McWhortyer Technologies fo rits generous support in compiling these data.